Results 131 to 140 of about 2,300,404 (261)
Guanidine-Based Ligands in Bioinorganic Chemistry: Coordination Modes and Applications in Anticancer Metallodrugs. [PDF]
Del Campo-Balguerías A +3 more
europepmc +1 more source
Steric Effects in Isopropyl‐Substituted (β‐Diketiminato)Iron Complexes
An isopropyl‐substituted β‐diketiminate ligand is shown to integrate aspects of its methyl and tert‐butyl counterparts in the preparation of iron complexes. As in the methyl system, it is synthesized in a single step but, like the tert‐butyl analog, it provides sufficient steric shielding to support otherwise unstable compounds.
Isaac J. Akpan +2 more
wiley +1 more source
Introduction to the spotlight collection on bioinorganic chemistry. [PDF]
Dey A, Lim MH, DeBeer S.
europepmc +1 more source
Luminescent metal–organic framework@nanoparticle composites show dual emission of both components EuBDC and zirconyl‐containing nanoparticles, being reversible, excitation energy‐dependent and solvatochromic switches. The chromaticity changes are fast, as no chemical transformation is involved and required as source of the dual emission.
Tobias Wehner +3 more
wiley +1 more source
Copper(II/III) Redox Couple Enables C─H Methylation via a Radical Mechanism Analogous to SAM Enzymes
Biological C–H methylation proceeds through radical pathways mediated by one‐electron redox cofactors, yet no synthetic model has reproduced this reactivity. Here, we report the first isolable Cu(II/III)–methyl complexes that mediate C–H methylation through hydrogen atom transfer and methyl radical rebound.
Emily N. Doss +2 more
wiley +2 more sources
Bioinorganic Chemistry and Applications
doaj +1 more source
Schiff Bases and Metal Complexes as Multifunctional Platforms: Bridging Bioinorganic Chemistry, Catalysis, Sensing, and Energy Applications. [PDF]
Barreras-Contreras LA +7 more
europepmc +1 more source
Using a multidentate ligand with two distinct coordination sites and a bridging coordination site, a series of novel linear pentanuclear complexes with alternately arranged 3d and 4f ions via a one‐pot reaction were synthesized. Cryomagnetic studies revealed the presence of intramolecular ferromagnetic interactions and their magnetic entropy changes ...
Takuya Shiga +3 more
wiley +1 more source

