Mechanistic Understanding of Protein–MOF Integration Through Surfactant‐Driven Interfacial Design
Advanced Science, EarlyView.This study reveals how surfactant‐driven interfacial design governs the assembly and stability of protein@MOF composites. Using lipid‐based nonionic surfactants, we modulate protein–MOF interactions to improve encapsulation efficiency, MOF crystallization, and catalytic performance.
Ehsan Rashidniyaghi +4 more
wiley +1 more source
Rewiring Pyroptosis to Potentiate Cancer Immunotherapy via a Gasdermin D Agonist Bypassing Caspase‐3
Advanced Science, EarlyView.This work introduces a small‐molecule agonist, DIBDO, that bypasses Casp‐3 to directly trigger GSDMD‐mediated pyroptosis in tumors. Activated by glutathione, DIBDO generates singlet oxygen and molecular iodine, blocking Casp‐3 pathways and inducing immunogenic cell death.
Dan Zhao +6 more
wiley +1 more source
Advanced Science, EarlyView.This article aims to elucidate the biological mechanisms of bone repair and the evolution of material design, highlighting key cellular and molecular processes. It further proposes strategies and prospects for programmable bio‐interactive materials, which enable precisely guided bone tissue regeneration by dynamically regulating cell behavior and the ...
Qingrui Fan +6 more
wiley +1 more source
Open Access chemistry journal -- Bioinorganic Chemistry & Applications
, 2005 Bioinorganic Chemistry & Applications is an Open Access journal published by Hindawi Publishing.
Peter Suber
core +1 more source
[Review] Computational Inorganic and Bioinorganic Chemistry
, 2010 This article reviews the book "Computational Inorganic and Bioinorganic Chemistry," edited by Edward I. Solomon, Robert A. Scott, and R.
Cundari, Thomas R., 1964-
core +1 more source
Activation of Metal Complexes With Ultrasound Waves for Targeted Anticancer Therapy
Angewandte Chemie International Edition, EarlyView.Ultrasound enables non‐invasive activation of metal‐based therapeutics deep within tumors. Acoustic cavitation can drive sonodynamic reactive oxygen species generation or mechanochemical metal–ligand bond dissociation, enabling controlled release of bioactive payloads.
Félix Grosjean +3 more
wiley +1 more source
The Bioinorganic Chemistry of the First Row d-Block Metal Ions—An Introduction
The role played by the metal ions of the first row of the block in biology is discussed using illustrative examples, and covering current thinking in the field.
Helder M. Marques
core +1 more source
Dioxygen Reduction at a Cu(I) Complex Supported by a Macrocyclic N3O Ligand System
Chemistry – A European Journal, EarlyView.A non‐reactive [CuI(14‐TMC)]+ complex is transformed to an efficient catalyst [CuI(14‐TMCO)]+ (TMCO = 4,8,12‐trimethyl‐1‐oxa‐4,8,12‐triazacyclotetradecane) for 4e−/4H+ reduction of O2 by N → O substitution. ABSTRACT CuI(14 TMCO) (1), involving a N3O‐macrocycle, reacts with O2 at cryogenic temperatures to yield an end‐on peroxodicopper(II) species.
Maximilian Schütze +3 more
wiley +1 more source
Reactivity difference between protolytic forms of some macrocyclic chromium(III) complexes in ligand substitution and electron transfer processes [PDF]
, 2010 The review provides insight into the mechanism of ligand substitution and electron transfer (from chromium( III) to iron(III)) by comparison of the reactivity of some tetraazamacrocyclic chromium(III) complexes in the conjugate acid-base forms.
Impert, O. +20 more
core +1 more source
Bioinorganic Platforms for Sensing, Biomimicry, and Energy Catalysis
, 2021 Bioinorganic chemistry is a broad field with multiple branches. In this Highlight Review, the newest excitements in the branch of Bioinorganic Platforms are reviewed.
Tse, ECM, NGO, FM
core +1 more source