Results 31 to 40 of about 2,300,404 (261)

Turning Bonding Into Function: The Emerging Role of the Bioactive Selenium─Metal Motif in Toxicology and Medicinal Chemistry

Chemistry – A European Journal, EarlyView.
Balancing Act: Se─M bond serving as the fulcrum of the balance scale to compare the different weight of toxicity and therapeutic effects in biological environment. ABSTRACT The synthesis and characterization of organo‐selenium compounds have attracted considerable interest for decades, driven by the search for efficient catalysts and bioinspired ...
Matteo Filippi, Alessandro Rubbi, Pablo A. Nogara, Giovanni Ribaudo, Vito Lippolis, João B. T. Rocha, Laura Orian   +6 more
wiley   +1 more source

Multidimensional Engineering Enabling Rate‐Matched C−N Coupling for Efficient Organonitrogen Electrosynthesis

EcoEnergy, EarlyView.
This review introduces rate matching as a unifying design principle for efficient electrochemical C−N coupling and highlights multidimensional engineering of catalysts, interfaces, and reactors to synchronize the generation of carbon‐ and nitrogen‐containing intermediates, balance their surface coverages, maximize C−N bond formation, and enable ...
Kaixing Cai, Chunyang Pu, Jun Yang, Guangqin Li, Jiahui Xian   +4 more
wiley   +1 more source

Ambient Electrosynthesis of Pure 15 wt% H2O2 Without Salt Using an Ultrathin Metal–Organic Framework Nanosheet Featuring Dicopper(I) Active Sites

EcoEnergy, EarlyView.
An ultrathin metal–organic framework nanosheet with exposed dicopper(I) active sites enables ambient electrosynthesis of pure, salt‐free 15 wt% H2O2, achieving ∼95% Faradaic efficiency, 350 mA cm−2 current density, and over 50 h of stable operation in a solid‐electrolyte system.
Ze‐Wei Chai, Pei‐Qin Liao
wiley   +1 more source

Bioinorganic Chemistry : Some New Facets

, 2021
The book includes several topics as per Universities curriculum of M.Sc. and M.Phil. course work in Chemistry. This covers different Physiological aspects of Bioinorganic Chemistry in terms of 4 Chapters with in-depth and up-to-date coverage.
Ram Charitra Maurya
core  

Hydrostatic and Anisotropic Pressure Responses in Tetragonal Zirconia Nanoparticles

European Journal of Inorganic Chemistry, EarlyView.
Tetragonal zirconia nanoparticles exhibit remarkable sensitivity to a nonhydrostatic pressure component while remaining largely unaffected by hydrostatic pressure. Their tetragonal‐to‐monoclinic phase transition enables the detection of nonhydrostatic pressure components in the MPa range, providing a new strategy for evaluating nonhydrostatic pressure ...
Yuki Konno, Natsuki Asano, Ai Amatatsu, Kenta Imoto, Shin‐ichi Ohkoshi, Hiroko Tokoro   +5 more
wiley   +1 more source

Bioinorganic chemistry and drug design: here comes zinc again [PDF]

, 1998
The structures and reactions of metal ions in proteins are of tremendous interest in bioinorganic chemistry, as is the potential for metals in creating novel medicines. New results combine these aspects in describing an unexpected mode for metal-mediated
Thorp, H.Holden
core   +1 more source

Quantum Bio-Inorganic Chemistry (QBIC) Society Special Collection

, 2022
This Editorial by Guest Editors L. Rulíšek, M. Gruden, M. Orio and QBIC Society President R. J. Deeth summarizes the Chemistry Europe Special Collection on quantum bioinorganic chemistry, published in collaboration with the Quantum Bioinorganic Chemistry
Maylis Orio, Robert J. Deeth, Rulíšek, Lubomír, Orio, Maylis, Lubomír Rulíšek, Maja Gruden, Gruden, Maja, Deeth, Robert J., Deeth, Robert   +8 more
core   +1 more source

Rare Earth 3‐Hydroxyphenylacetate Complexes: Synthesis, Structural Characterization, and Surprising Improved Anticorrosion Performance on Mild Steel

European Journal of Inorganic Chemistry, EarlyView.
The rare earth (RE) aqua complexes using 3‐hydroxyphenylacetate ligand were prepared using the corresponding RE salt and the sodium salt of the ligand by a salt metathesis reaction. Two different structural motifs of the complexes, {[La(3hpa)3(H2O)] × 2H2O}n, and [RE(3hpa)3(H2O)]n (RE = Ce (2), Nd (3), Gd (4), Dy (5), Y (6), Er (7), Yb (8)) were ...
Naveena Y. Salpadoru Thuppahige, Amy Burke‐Kennedy, Zhifang Guo, Glen B. Deacon, Anthony E. Somers, Peter C. Junk   +5 more
wiley   +1 more source

1,3‐Bis(tetrylene)s: Emerging Platforms for Functional Main‐Group Molecules

European Journal of Inorganic Chemistry, EarlyView.
Bridge design governs the stability and reactivity of 1,3‐bis(tetrylene)s. This review surveys pnictogen‐, chalcogen‐, and tetrel‐bridged systems and shows how geometric preorganization and electronic communication can enable cooperative bond activation and access to unusual heavy‐element π frameworks. Main‐group chemistry has undergone a resurgence as
Daichi Uchida, Yoshiyuki Mizuhata
wiley   +1 more source

Ligand Redox Noninnocence in Bis(phosphinimine) Diarylamido Pincer Complexes of Nickel

European Journal of Inorganic Chemistry, EarlyView.
The oxidative noninnocence of a bis(phosphinimine) ligand featuring a diarylamido backbone was investigated for several nickel complexes. Radical/charge delocalization across the aromatic backbone plays an important role in the stabilization of the diarylaminyl and putative diarylnitrenium complexes.
Xiujing Xing, Ryan P. Murphy, David P. Hales, Qiuran Wang, Ariana Z. Spentzos, Laura M. Thierer, Michael R. Gau, Patrick J. Carroll, Neil C. Tomson   +8 more
wiley   +1 more source