Results 71 to 80 of about 2,368,810 (278)

Multifunctional Matrix‐Activated Electrodes Enabling Efficient Proton Transport and Durable Low‐Pt Operation for High‐Temperature Proton Exchange Membrane Fuel Cells

open access: yesAdvanced Energy Materials, EarlyView.
This work introduces a CeHP‐enabled multifunctional matrix‐activated electrode (MME) for high‐temperature PEM fuel cells, forming an electrochemically and mechanically functional matrix within the catalyst layer. The design increases peak power density by 38% and reduces voltage decay by 62% at 240 °C, while using only 40% of the Pt loading of a ...
Gyeongseok Gwak   +12 more
wiley   +1 more source

Diamondiyne: A 3D Carbon Allotrope With Mixed sp–sp3 Hybridization

open access: yesAngewandte Chemie, EarlyView.
A new carbon allotrope with mixed sp–sp3 hybridization has been synthesized through delicately controlled kinetics at a liquid–liquid interface. The resulting material, termed diamondiyne, exhibits an expanded diamond‐type network in the form of small crystallites in a continuous all‐carbon film.
Yizhou Yang   +12 more
wiley   +2 more sources

Does Participating in Agricultural Global Value Chains Promote Agricultural Growth?

open access: yesAgribusiness, EarlyView.
ABSTRACT This study examines the relationship between GVC participation and agricultural value‐added growth in 43 countries over the period 1995–2022. In contrast to prior literature, we disaggregate the agricultural sector into four sub‐sectors namely crop cultivation, animal production, forestry and fishing.
Taner Turan   +2 more
wiley   +1 more source

Energy Transfer‐Mediated Magnetoluminescence of an Octahedral MnII Complex Ligated With Bis(Diphenylphosphino)Methane Dioxide

open access: yesAngewandte Chemie, EarlyView.
Energy‐transfer‐mediated magnetoluminescence of paramagnetic transition metal complexes: dope solids of an octahedral MnII complex into the corresponding ZnII complex exhibited a pronounced magnetic field response of emission spectra under the application of magnetic fields.
Asato Mizuno   +5 more
wiley   +2 more sources

Small Intestinal Bacterial Overgrowth Following Gastrointestinal Cancer Surgery: Current Evidence and Future Perspectives

open access: yesAnnals of Gastroenterological Surgery, EarlyView.
ABSTRACT Small intestinal bacterial overgrowth (SIBO) has recently gained increasing attention as a potential cause of postoperative gastrointestinal symptoms following gastrointestinal cancer surgery. Surgical procedures can disrupt normal gastrointestinal physiology through anatomical reconstruction, impaired motility, reduced gastric acid secretion,
Toru Aoyama   +2 more
wiley   +1 more source

Structure and Function of a Multi‐Megadalton Virus‐Like Proteolytic Dodecahedron

open access: yesAngewandte Chemie, EarlyView.
Zuzalysin, a virulence metallopeptidase of the periodontal pathogen Porphyromonas gingivalis, is secreted as a latent, flexible ≈95‐kDa monomer. Calcium triggers cysteine‐switch activation and hierarchical assembly into pentamers, bipentamers, tripentamers, and a ≈5.6‐MDa, ≈355‐Å dodecahedron. Structures at 1.8–3.6 Å reveal a virus‐sized catalytic cage
Mariusz Madej   +20 more
wiley   +2 more sources

Joule self‐heating enabled oxygen transport and coupled methane reactions in a La0.6Sr0.4Co0.2Fe0.8O3‐δ hollow fiber membrane reactor

open access: yesAIChE Journal, EarlyView.
Abstract Mixed‐conducting ceramic hollow fiber membranes are a versatile platform for oxygen separation, value‐added chemical production, and oxy‐combustion. Because oxygen permeation is thermally activated, these systems typically rely on bulky, energy‐intensive furnaces that suffer from low efficiency and large thermal inertia.
Gang Wang   +2 more
wiley   +1 more source

Site‐Specific Molecular Engineering Redirects Radical Pathways for Selective Photocatalytic Coupling of Methane to C2+ Hydrocarbons

open access: yesAngewandte Chemie, EarlyView.
Site‐specific self‐assembly of alkyl thiols on Au/TiO2 enables precise modulation of interfacial electron distribution and the local microenvironment through covalent Au‐thiolate interactions. This site‐specific molecular engineering synergistically promotes surface kinetics and charge separation, suppressing ·O2−‐driven overoxidation and thereby ...
Yaru Shao   +11 more
wiley   +2 more sources

How small changes to methylated piperidinium cations impact the synthesis of zeolite SSZ‐39

open access: yesAIChE Journal, EarlyView.
Abstract Here we report a synthesis study of SSZ‐39 with four different organic structure directing agents (OSDA). The goal was to determine how subtle changes to the OSDA architecture impact crystallization kinetics, material composition, and other properties.
Onyinyechukwu Ukagha, Daniel F. Shantz
wiley   +1 more source

1,2‐Bis(boronate) Arenes by Borylation Directed Borylation

open access: yesAngewandte Chemie, EarlyView.
Boron electrophiles derived from tetrabromo‐pyrazaboles and AlCl3 affect the regioselective vicinal double C–H borylation of a range of arenes and polycyclic aromatic hydrocarbons (PAHs). A subsequent pinacol installation step then affords the vicinal bis‐boronate ester‐substituted arene/PAH.
Anna V. Schellbach   +4 more
wiley   +2 more sources

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