Results 121 to 130 of about 193,836 (387)

Comparison crystal structure conformations of two structurally related biphenyl analogues: 4,4′-bis[3-(pyrrolidin-1-yl)prop-1-yn-1-yl]-1,1′-biphenyl and 4,4′-bis{3-[(S)-2-methylpyrrolidin-1-yl]prop-1-yn-1-yl}-1,1′-biphenyl

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
The title compounds, C26H28N2, (I), and C28H32N2, (II), were designed based on the structure of the potent α9α10 nicotinic acetylcholine receptor antagonist ZZ161C {1,1′-[[1,1′-biphenyl]-4,4′-diylbis(prop-2-yne-3,1-diyl)]bis(3,4-dimethylpyridin-1-ium ...
Anqi Wan   +4 more
doaj   +1 more source

Luminescent Chiral Molecular Glasses by Melt‐Quenching Enantiopure BINAP

open access: yesAdvanced Science, EarlyView.
Melt‐quenching of enantiopure BINAP yields transparent chiral molecular glasses that retain axial chirality and display blue‐shifted luminescence together with strongly enhanced circularly polarized emission with dissymmetry factors |glum| of ≈10−2.
Nuttaporn Krittametaporn   +8 more
wiley   +1 more source

Electrocatalytic Nitrate Reduction to Hydroxylamine: Breaking the Activity‐Selectivity Trade‐Off by Designer Bifunctional Metal‐Organic Frameworks

open access: yesAngewandte Chemie, EarlyView.
A bifunctional metal‐organic framework (MOF) catalyst with dual active sites is developed for enabling NH2OH electrosynthesis via NitRR with both high selectivity and activity. ABSTRACT Electrocatalytic nitrate reduction reaction (NitRR) offers a promising route for hydroxylamine (NH2OH) synthesis under ambient conditions.
Yingying Zou   +9 more
wiley   +2 more sources

Identification of biphenyls - contaminants responsible for off-flavour in soft drinks

open access: yesCzech Journal of Food Sciences, 2018
Off-flavour in soft drinks is one of the main threats to manufacturers, which can result in expensive recalls, and discredit the brand. Off-flavours can occur for a variety of reasons (e.g . chemical contamination of raw material).
Iveta ŠÍSTKOVÁ   +3 more
doaj   +1 more source

Highly potent first examples of dual aromatase-steroid sulfatase inhibitors based on a biphenyl template.

open access: yesJournal of Medicinal Chemistry, 2010
Single agents against multiple drug targets are of increasing interest. Hormone-dependent breast cancer (HDBC) may be more effectively treated by dual inhibition of aromatase and steroid sulfatase (STS).
L. Woo   +9 more
semanticscholar   +1 more source

A Generalized Approach for Distal C–H Arylation of Organic Building Blocks: Unveiling the Role of Counter Anion

open access: yesAdvanced Science, EarlyView.
We report a general strategy for meta‐selective C–H arylation using aryl iodides and a Pd(II)/Pd(IV) catalytic system guided by a removable directing group. DFT and experimental studies reveal that counter anion tuning (acetate to trifluoroacetate) significantly enhances selectivity.
Jagrit Grover   +6 more
wiley   +1 more source

Atroposelective Suzuki–Miyaura Coupling to Form 2‐Amino‐2′‐Hydroxybiphenyls Enabled by sRuPhos

open access: yesAngewandte Chemie, EarlyView.
We report a new chiral phosphine ligand, sRuPhos, which permits the highly enantioselective Suzuki–Miyaura coupling of ortho‐aniline and ortho‐phenol building blocks. This results in 2‐amino‐2′‐hydroxybiphenyls with very high enantiomeric excesses, products that will have application in pharmaceutical synthesis and ligand design for catalysis ...
Hamzah Sharif   +3 more
wiley   +2 more sources

Qualitative change in structural dynamics of some glass-forming systems

open access: yes, 2015
Analysis of temperature dependence of structural relaxation time in supercooled liquids revealed a qualitatively distinct feature - a sharp, cusp-like maxumum in the second derivative of its logarithm. It suggests that the super-Arrhenius behavior of the
Novikov, V. N., Sokolov, A. P.
core   +1 more source

Thermoresponsive Property Controlled by End-Functionalization of Poly(N-isopropylacrylamide) with Phenyl, Biphenyl, and Triphenyl Groups [PDF]

open access: bronze, 2006
Qian Duan   +6 more
openalex   +1 more source

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