Results 131 to 140 of about 193,836 (387)

Observation of Edge‐Confined Acoustic Hyperbolic Polaritons in van der Waals Materials

open access: yesAdvanced Science, EarlyView.
This work demonstrates a new type of light wave—edge‐confined acoustic hyperbolic polaritons—in hexagonal boron nitride on gold. These waves travel along crystal edges with nanoscale confinement and strongly interact with molecular vibrations, enabling highly sensitive detection of tiny molecular layers.
Tianning Zhang   +4 more
wiley   +1 more source

Radical Electroprecipitation from a Water|Oil|Electrode Interface Prolongs “Electro”Chemiluminescence of the Tris(2,2′‐bipyridyl)Ruthenium(II) and Benzoyl Peroxide System by 103

open access: yesAngewandte Chemie, EarlyView.
Multiphase systems, including ones with liquid‐liquid phase boundaries, are the home to many curious chemistries including reaction acceleration and spontaneous formation of reactive species. Here we show the liquid‐liquid interface causes electrochemiluminescence and afterglow chemiluminescence lifetime to be enhanced by 220,000% in‐time, far beyond ...
Daniel M. Carrel   +3 more
wiley   +2 more sources

Biphenyl-4-yl 2,2,2-trichloroethyl sulfate

open access: yesActa Crystallographica Section E, 2010
The molecular structure of the title compound, C14H11Cl3O4S, displays a biphenyl dihedral angle of 4.9 (2)° between the benzene rings, which is significantly smaller than the calculated dihedral angle of 41.2° of biphenyl ...
Xueshu Li   +4 more
doaj   +1 more source

Record‐High Performance Hyperfluorescent OLEDs Achieved via Electronic Structure Control of Chlorine‐Diversified MR‐TADF Emitters

open access: yesAdvanced Science, EarlyView.
A late‐stage diversification strategy for the benchmark MR‐TADF emitter ω‐DABNA enables precise electronic structure control via chlorine‐activated functionalization. The resulting derivatives achieve tunable emission from 523 to 533 nm with record‐high EQE1000 up to 34.0% and excellent color purity (CIEy = 0.70–0.73), establishing a versatile platform
Taehwan Lee   +7 more
wiley   +1 more source

Reimagining o‐Carborane‐Based Fluorophores: Charge‐Transfer from Boron Substituents Triggers Aggregation‐ and Crystallization‐Induced Emission

open access: yesAngewandte Chemie, EarlyView.
This work reports, for the first time, aggregation‐ or crystallization‐induced emission in boron‐substituted carboranes, which was driven by photoinduced charge‐transfer from fluorophore attached via boron vertices. The emission properties can be tuned by varying the substituents, expanding design strategies for luminescent materials.
Balázs Szathmári   +9 more
wiley   +2 more sources

Carbons produced from known organic compounds 2. Anthracene-biphenyl and phenanthrene- biphenyl systems [PDF]

open access: yes
Carbonization of binary mixtures of anthracene biphenyl and penanthrene ...
Walker, P. L., Jr., Weintraub, A.
core   +1 more source

Circularly Polarized Long‐Persistent and Photostimulated Luminescence Enabled through Förster Resonance Energy Transfer and Upconversion Strategies

open access: yesAdvanced Science, EarlyView.
Using chiral emitters with circularly polarized luminescence (CPL) characteristics integrated into organic long‐persistent luminescence (OLPL) system demonstrates circularly polarized long‐persistent luminescence (CP‐LPL). Importantly, the Förster resonance energy transfer (FRET)‐based design reveals circularly polarized photostimulated luminescence ...
Ruttapol Malatong   +8 more
wiley   +1 more source

Experimental Isolation of Single Impact, Cumulative Energy, Aging, and Liquid‐Assisted Grinding Effects in Mechanochemical Reactions

open access: yesAngewandte Chemie, EarlyView.
An experimental framework is introduced to isolate single‐impact and cumulative energy within a mechanochemical system. The guided, stepwise approach highlights the fundamental roles of impact events, post‐impact reactivity, and liquid‐assisted grinding additives in all‐solid mechanochemical reactions.
Johanna Templ, Lars Borchardt
wiley   +2 more sources

From Materials to Systems: Challenges and Solutions for Fast‐Charge/Discharge Na‐Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
This review systematically analyzes the key characteristics limiting the fast‐charge/discharge capability of Na‐ion batteries (SIBs) from a multi‐scale perspective encompassing electrode materials, the electrode‐electrolyte interface, and the system. Furthermore, it presents practical solution strategies for the fundamental issues arising at each scale,
Bonyoung Ku   +5 more
wiley   +1 more source

Enantiospecific Optical Sensing of Terpenes by an Aggregated Atropisomeric Platinum(II) Complex

open access: yesAngewandte Chemie, EarlyView.
Aggregated metal complexes act as an artificial nose and permit reversible optical sensing of small volatile molecules like R/S‐limonene based on enantiospecific recognition. Abstract Terpenes are unfunctionalized small volatile organic compounds (VOCs) that are naturally abundant, relevant to climate change, and impose potential health risks.
Annika Huber   +3 more
wiley   +2 more sources

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