Results 181 to 190 of about 47,366 (291)

Visible‐light‐promoted catalyst‐free benzylic C‐H oxidation using molecular oxygen as a green oxidant

open access: yesSmart Molecules, EarlyView.
A green and simple photo‐oxygenation of benzylic C‐H bond with molecular oxygen was developed for the preparation of a series of carbonyl compounds. The straightforward C‐H carbonylation strategy features catalyst‐ and additive‐free reaction conditions, only oxygen as a green oxidant, broad scope and scalable, and the simple‐operation nature.
Jianing Li   +6 more
wiley   +1 more source

Unraveling the effect of topological structures of B/N‐doped conjugated macrocycles on spectral properties: A computational study

open access: yesSmart Molecules, EarlyView.
Herein, we constructed a series of fully B‐doped, fully N‐doped and hybrid B/N‐doped conjugated macrocycles considering three key topological factors. At a fixed ring size, the spectra initially redshift then blueshift with varying B/N ratio, while ring size exhibits negligible impact on spectra.
Wen‐Yu Guo   +4 more
wiley   +1 more source

Ligand‐Controlled Tunable Distal C(sp2)–H Functionalization of Aryl and Benzyl Phosphonates

open access: yesTransformative Chemistry, EarlyView.
The switchable borylation of aryl and benzyl phosphonates with good to excellent regioselectivity was demonstrated. Through orthogonal transformation of Horner–Wadsworth–Emmons olefination and Suzuki–Miyaura cross coupling, a variety of styrene derivatives were obtained with precise site control.
Han Ang   +6 more
wiley   +1 more source

Designing Tailored Molecular Cavities Using Calix[5]arenes as Building Blocks

open access: yesThe Chemical Record, EarlyView.
This account focuses on the shape and dimensions of cavities formed by precisely designed molecular frameworks. It highlights our efforts to construct synthetically tailored cavities based on calix[5]arenes. This study examines the shapes and dimensions of cavities defined by well‐designed molecular structures.
Takehiro Hirao, Takeharu Haino
wiley   +1 more source

Dimethyl‐, Diethyl‐, and Propylene Carbonates: An Emerging Class of Green Solvents for Organic Synthesis

open access: yesThe Chemical Record, EarlyView.
This review highlights recent advances in the use of organic carbonates, dimethyl carbonate (DMC), diethyl carbonate (DEC), and propylene carbonate (PC), as solvents in organic synthesis. Based on over seventy studies from the past 6 years, it shows their application in different organic reaction types, emphasizing their role in safer and more ...
Gabriela T. Quadros   +5 more
wiley   +1 more source

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