Results 31 to 40 of about 92,115 (282)

Synthesis and Characterization of Side-Chain Liquid-Crystalline Block Copolymers Containing Cyano-Terminated Phenyl Benzoate Moieties

open access: yesMolecules, 2023
Block copolymers, known for their capacity to undergo microphase separation, spontaneously yield various periodic nanostructures. These precisely controlled nanostructures have attracted considerable interest due to their potential applications in ...
Kaito Takahashi   +5 more
doaj   +1 more source

Synthesis of tri-block copolymers through reverse atom transfer radical polymerization of methyl methacrylate using polyurethane macroiniferter

open access: yeseXPRESS Polymer Letters, 2008
Reverse atom transfer radical polymerization was successfully used for the first time to synthesis tri-block copolymers. Poly (methyl methacrylate)-block-polyurethane-block-poly (methyl methacrylate) tri-block copolymers were synthesized using ...
doaj   +1 more source

Dissipative Particle Dynamics Study on Interfacial Properties of Ternary H-Shaped Copolymer–Homopolymer Blends

open access: yesMolecules
Dissipative particle dynamics (DPD) simulations is used to study the effect of Am/2BmAm/2 and H-shaped (Am/4)2Bm(Am/4)2 block copolymers on the interfacial properties of ternary blends.
Ye Lin, Yongchao Jin, Xiyin Wang
doaj   +1 more source

Ring-opening polymerization-induced crystallization-driven self-assembly of poly-L-lactide-block-polyethylene glycol block copolymers (ROPI-CDSA)

open access: yesNature Communications, 2020
A key challenge in the self-assembly of block copolymers is obtaining independent control over molecular structure and hierarchical structure in all dimensions using scalable one-pot chemistry.
Paul J. Hurst   +2 more
doaj   +1 more source

The Living ROMP of trans-Cyclooctene [PDF]

open access: yes, 2009
The living ring-opening metathesis polymerization (ROMP) of trans-cyclooctene (tCO) was investigated. ROMP of tCO in the presence of PPh_3 in THF leads to the formation of narrowly dispersed polycyclooctene (PCO).
Conrad, Rosemary M.   +2 more
core   +2 more sources

Rethinking plastic waste: innovations in enzymatic breakdown of oil‐based polyesters and bioplastics

open access: yesFEBS Open Bio, EarlyView.
Plastic pollution remains a critical environmental challenge, and current mechanical and chemical recycling methods are insufficient to achieve a fully circular economy. This review highlights recent breakthroughs in the enzymatic depolymerization of both oil‐derived polyesters and bioplastics, including high‐throughput protein engineering, de novo ...
Elena Rosini   +2 more
wiley   +1 more source

Novel multi-responsive P2VP-block-PNIPAAm block copolymers via nitroxide-mediated radical polymerization

open access: yesBeilstein Journal of Organic Chemistry, 2010
Linear soluble multi-responsive block copolymers are able to form so called schizophrenic micelles in aqueous solution. Here, such polymers are prepared via nitroxide-mediated radical polymerization (NMRP).
Cathrin Corten   +2 more
doaj   +1 more source

Synthesis and properties of Poly(L-lactide)-b-poly (L-phenylalanine) hybrid copolymers [PDF]

open access: yes, 2014
Hybrid materials constituted by peptides and synthetic polymers have nowadays a great interest since they can combine the properties and functions of each constitutive block, being also possible to modify the final characteristics by using different ...
Planellas Oates, Marc   +1 more
core   +3 more sources

Enzymatic degradation of biopolymers in amorphous and molten states: mechanisms and applications

open access: yesFEBS Open Bio, EarlyView.
This review explains how polymer morphology and thermal state shape enzymatic degradation pathways, comparing amorphous and molten biopolymer structures. By integrating structure–reactivity principles with insights from thermodynamics and enzyme engineering, it highlights mechanisms that enable efficient polymer breakdown.
Anđela Pustak, Aleksandra Maršavelski
wiley   +1 more source

Impact of Block Length and Temperature over Self-Assembling Behavior of Block Copolymers

open access: yesInternational Journal of Polymer Science, 2016
Self-assembling behavior of block copolymers having water-soluble portion as one of the blocks plays key role in the properties and applications of the copolymers. Therefore, we have synthesized block copolymers of different block length and investigated
Samia A. Kosa   +4 more
doaj   +1 more source

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