Results 31 to 40 of about 1,828 (197)

Strain‐Release Pentafluorosulfanylation of Carbonyl‐Containing Disubstituted Bicyclobutanes: A Fortuitous Path to SF5‐Containing Oxa[2.1.1]bicyclohexanes

open access: yesAngewandte Chemie, EarlyView.
A regio‐ and diastereoselective method for strain‐release pentafluorosulfanylation of carbonyl‐containing 1,3‐disubstituted [1.1.0]bicyclobutanes (BCBs) was developed that led to several fortuitous discoveries. For instance, the resultant SF5‐cyclobutanes (SF5‐CBs) exhibit close SF5⋯C═X contacts (X = C, N, O) and provide synthetic access to a new class
Alexander M. Stephens   +9 more
wiley   +2 more sources

Alkali Metal Borides

open access: yes, 1977
The first studies relevant to alkali metal borides were carried out in the nineteenh century as an incidental part of the effort to isolate element boron by reduction of several boron compounds...
Naslain, Roger   +2 more
openaire   +2 more sources

Impact of MgO Additions on the Oxidation Resistance and Compression Behavior of Vanadium Alloys

open access: yesAdvanced Engineering Materials, EarlyView.
An increase in oxidation resistance at 600 °C is achieved for alloys containing more than 2.5 wt.% MgO. It has been established that, along with V2O5, MgO6V2, and Mg2O7V2 are formed, which are presumed to enhance oxidative stability. Furthermore, the possible transformation of Mg‐vanadates through reaction with CO2, which presumably occurs in this ...
Ievgen Solodkyi   +5 more
wiley   +1 more source

Short-Term Oxidation of HfB2-SiC Based UHTC in Supersonic Flow of Carbon Dioxide Plasma

open access: yesPlasma
The short-term (5 min) exposure to the supersonic flow of carbon dioxide plasma on ultrahigh-temperature ceramics of HfB2-30vol.%SiC composition has been studied.
Aleksey V. Chaplygin   +14 more
doaj   +1 more source

Characterizations and boron diffusion modelling on the AISI H13 steel [PDF]

open access: yesJournal of Mining and Metallurgy. Section B: Metallurgy
A kinetic approach accounting for the linearity of boron profiles through the boronized layers on AISI H13 steel was developed. It aims to track the temporal evolution of the thicknesses of the FeB and (FeB + Fe2B) layers by considering new expressions ...
Ortiz-Domínguez M.   +2 more
doaj   +1 more source

Current Functional Materials for Wear-Resistant Casting: from Multicomponent Cast Irons to Hybrid High-Boron Alloys

open access: yesУспехи физики металлов, 2022
The results obtained in the last two decades in the development of functional tribological alloys for the castings working under severe abrasion, erosion, and erosion–corrosion conditions are reviewed.
Yu. G. Chabak, V. I. Zurnadzhy, M. A. Golinskyi, V. G. Efremenko, N. P. Zaichuk, I. Petryshynets, and S. P. Shymchuk
doaj   +1 more source

The Influence of Field‐Assisted Sintering Technology (FAST) Temperature and Cooling Rate on the Microstructural Evolution in Gamma‐Titanium Aluminide Alloy GE4822

open access: yesAdvanced Engineering Materials, EarlyView.
Controlling the Field Assisted Sintering Technology (FAST) parameters, dwell temperature and cooling rate, significantly influences the microstructural evolution in titanium aluminide GE4822. Significant γ‐lamellar colonies develop only upon cooling through the α‐transus.
Jack Krohn, James Pepper, Martin Jackson
wiley   +1 more source

High-T c 2D ambient BCS superconductors in hydrogenated transition-metal borides

open access: yesnpj 2D Materials and Applications
The discovery of MgB2, with T c of 39 K, has inspired intensive studies on various metal (di)-borides to identify other potential conventional high-temperature superconductors.
Jakkapat Seeyangnok   +2 more
doaj   +1 more source

HRXRD study of the theoretical densities of novel reactive sintered boride candidate neutron shielding materials

open access: yesNuclear Materials and Energy, 2020
Reactive Sintered Borides (RSBs) are novel borocarbide materials derived from FeCr-based cemented tungsten (FeCr-cWCs) show considerable promise as compact radiation armour for proposed spherical tokamak (Humphry-Baker, 2007 [1], [2], [3], [4], [5].
J.M. Marshall, D. Walker, P.A. Thomas
doaj   +1 more source

Fundamentals of Thermal Transport and Energy Conversion in Ultra‐High Temperature Ceramics: From Microscale Mechanisms to Macroscopic Properties

open access: yesAdvanced Science, EarlyView.
This review critically examines thermal transport and radiative properties of ultra‐high temperature ceramics for hypersonic flight, advanced nuclear systems, and next‐generation energy conversion devices. It explores phonon–photon–electron interactions, microstructural engineering, thermoelectric conversion, and machine learning‐accelerated multiscale
Zhipeng Pei   +8 more
wiley   +1 more source

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