Results 141 to 150 of about 31,221 (252)

Electro-Oxidation of Glycerol on Core–Shell M@Pt/C (M = Co, Ni, Sn) Catalysts in Alkaline Medium

open access: yesEnergies
This study explores the development of core–shell electrocatalysts for efficient glycerol oxidation in alkaline media. Carbon-supported M@Pt/C (M = Co, Ni, Sn) catalysts with a 1:1 atomic ratio of metal (M) to platinum (Pt) were synthesized using a ...
Rudyere Nascimento Silva   +3 more
doaj   +1 more source

Desymmetrization of Pseudo‐para Diformyl[2.2]Paracyclophane via Brønsted Acid‐Catalyzed Reductive Amination

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.
A highly stereoselective desymmetrization of pseudo‐para diformyl[2.2]paracyclophanes is developed via chiral Brønsted acid‐catalyzed reductive amination. This protocol provides efficient access to enantiopure planar chiral paracyclophanes with broad substrate scope, excellent enantioselectivity, and versatile postsynthetic functionalization. Access to
Sandip Baban Shinde   +4 more
wiley   +1 more source

Highly Lewis Acidic In Situ‐Generated Boronic Acid Ester: A Practical Catalyst for Hosomi–Sakurai Conjugate Addition, Carbonyl‐Ene Reaction, and Silane‐Mediated Amide Reduction

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.
An exceptionally Lewis acidic boronic acid ester, generated in situ from pentafluorophenylboronic acid and tetrabromonaphthalenediol, catalyzes three important chemical transformations at 1–10 mol% loading: the Hosomi–Sakurai allylation of α,β‐unsaturated ketones, intermolecular carbonyl‐ene reactions, and the reductions of tertiary amides to amines ...
Ava Bousselat   +5 more
wiley   +1 more source

Highly Stable and Minimally Pt‐Loaded Multiporous Bimetallic Matryoshka Heterostructures for Efficient Hydrogen Evolution Reaction via pH‐Dependent Mechanistic Decoupling

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.
Highly uniform, multi‐porous Au–Pt Matryoshka heterostructures were synthesized via a facile galvanic replacement reaction using Au@Ag coreshells as sacrificial templates. By precisely tuning the Au/Pt composition, the catalysts were optimized for the hydrogen evolution reaction (HER), exhibiting outstanding efficiency and ultra‐high stability in both ...
Dun Chan Cha   +8 more
wiley   +1 more source

Chemical reduction of hematite by sodium borohydride [PDF]

open access: yes, 2005
DA COSTA, GM   +3 more
core   +1 more source

Experimental High‐Throughput Electrochemistry

open access: yesChemElectroChem, Volume 13, Issue 9, 5 May 2026.
This review highlights experimental high‐throughput electrochemistry as a powerful approach to accelerate electrochemical research. Key technologies such as automated platforms, microelectrode arrays, and machine learning‐based optimization are discussed, with a focus on applications in electrocatalysis, battery research, and electrosynthesis ...
Jens Noack
wiley   +1 more source

Synthesis of a π‐Extended Phenazine Diimide Derivative and Characterization of Its Closed‐Shell Reduced States

open access: yesChemistry – A European Journal, Volume 32, Issue 17, 5 May 2026.
In this work, the synthesis and characterization of novel π‐extended phenazine diimides is reported. The derivatives undergo differential reduction to a dihydrophenazine or Meisenheimer form depending on the reaction conditions employed. The outcome of this work highlights the paramount importance of structural design in determining the nature of the ...
Francesco Rigodanza   +7 more
wiley   +1 more source

Using Additives to Control the Decomposition Temperature of Sodium Borohydride [PDF]

open access: yes, 2020
Jubert Tomasso, Camille   +3 more
core  

Boosting Photo‐Pyroelectric Effect via Tunable Polarization and Interfacial Defect Engineering

open access: yesAdvanced Science, Volume 13, Issue 25, 4 May 2026.
This study reports Ba(Ti0.85Zr0.15)O3 nanocatalysts with enhanced polarization and oxygen‐vacancy‐rich interfaces for efficient NIR‐II photo‐pyroelectric therapy. Zr doping boosts the pyroelectric coefficient and accelerates polarization switching, while oxygen vacancies improve photothermal conversion and surface reactivity.
Yanli Huang   +13 more
wiley   +1 more source

Dual‐Phosphorus, Dual‐Nitrogen‐Embedded Corannulene: Synthesis, Structure, and Electronic Coupling

open access: yesChemistryEurope, Volume 4, Issue 5, May 2026.
P2N2‐TBC, a corannulene‐based bowl structure incorporating two phosphorus and two nitrogen atoms, represents the first P2N2‐embedded heterobuckybowl. The cis and trans stereoisomers of this compound display distinct packing motifs, leading to markedly different electronic coupling patterns.
Marina Nagai   +6 more
wiley   +1 more source

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