Results 151 to 160 of about 3,734 (241)
This study investigates the impact of various p‐block element impurities in the electrochemical reductive amination and reveals with Bi a less toxic alternative for Pb. The utilization of Bi as additive was further optimized by studying the impact of additive concentration, reaction temperature, and cathode material on amine yield, offering new ...
Justus Kümper +5 more
wiley +1 more source
The Use of H2 in Catalytic Bromate Reduction by Nanoscale Heterogeneous Catalysts. [PDF]
Nurlan N, Akmanova A, Lee W.
europepmc +1 more source
The work outlined herein covers a series of novel herbicidal lead structures that possess a pyrrolidinyl pyrazole carboxamide scaffold as a key structural feature, carrying further substituted benzyl side chains. Based on scaffold hopping approaches from known fungicidal and herbicidal compounds and utilizing an optimized synthetic approach, a broader ...
Elisabeth Asmus +24 more
wiley +1 more source
Intramolecular cyclization to quench an in situ reduction‐generated azaquinone methide is a strategy that could be used for late‐stage heterocycle synthesis. Herein, synthetically accessible 4‐nitrobenzyl alcohols with a nucleophilic handle adjacent to the benzyl alcohol group are reduced under mild conditions to afford six‐ and seven‐membered ...
Harrison M. Lewin +4 more
wiley +1 more source
Synthesis of Niraparib via Chemoenzymatic Dearomatization of Substituted Pyridines
The synthesis of the PARP inhibitor Niraparib has been achieved via a chemoenzymatic dearomatization strategy. Chemical reduction combined with a one‐pot enzymatic cascade comprising an amine oxidase (AmOx) and an ene imine reductase (EneIRED) allowed for asymmetric reduction with high enantioselectivity.
Tabea Gerlach +3 more
wiley +1 more source
Combustion Resistant Borohydrides and Their Chemical Interactions with Li-Metal Surfaces: An Experimental and Theoretical Study. [PDF]
Tomich AW +10 more
europepmc +1 more source
Metal Borohydrides beyond Groups I and II: A Review. [PDF]
Suárez-Alcántara K, Tena García JR.
europepmc +1 more source
PdPt alloys supported on reduced graphene oxide exhibit enhanced hydrogen oxidation and evolution activity in acidic media. Minimal Pt incorporation into Pd tunes the d‐band center and weakens hydrogen and CO binding, delivering superior activity and CO tolerance.
Shwetambara Jha +5 more
wiley +1 more source
Electrochemical Decarboxylative Hydroxylation for the Sustainable Synthesis of Bempedoic Acid
A sustainable synthesis of bempedoic acid is achieved using electrochemical hydroxylative decarboxylation as the key step. Starting from Meldrum's acid, mild metal‐free alkylation, hydrolysis, and decarboxylation provide the key precursor, which is electrochemically converted to the alcohol intermediate and then hydrolyzed to the final product ...
Pietro Ronco +6 more
wiley +1 more source
Chemical Bonds Containing Hydrogen: Choices for Hydrogen Carriers and Catalysts. [PDF]
Cashel J +9 more
europepmc +1 more source

