European Journal of Inorganic Chemistry, Volume 29, Issue 15, 20 May 2026.The concept of scorpionate ligands has evolved significantly since the introduction of tris(pyrazolyl)borate. By integrating a biological supramolecular ligand scaffold with the classic scorpionate architecture, researchers have made notable strides in mimicking the active sites of nitrogenase and advancing homogeneous catalysis.
Austin Winfield Medley +1 more
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Combustion Resistant Borohydrides and Their Chemical Interactions with Li-Metal Surfaces: An Experimental and Theoretical Study. [PDF]
ACS Cent SciTomich AW +10 more
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Stereoselective Synthesis of Glycomimetic Amines From Biomass‐Derived Cyrene
European Journal of Organic Chemistry, Volume 29, Issue 18, 14 May 2026.2,3,4‐Trideoxy‐2‐mannosamines, including the unsubstituted one, are accessible as the only endo diastereoisomers by reductive amination of the green solvent Cyrene, derived from pyrolysis of cellulose containing waste biomass. The products are useful chiral synthetic intermediate to nitrogenated glycomimetics.
Debora Pratesi +4 more
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Molecular Dynamics in Tetrafluoridoborate Salts of Divalent Metals Studied by Nuclear Magnetic Resonance Spectroscopy. [PDF]
ChemphyschemGradišek A, Radan K, Lozinšek M.
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A focus on anionic boron anthracenes and triptycenes as entry point toward B-doped polyaromatic materials and Lewis acids. [PDF]
Chem Sci, 2023 Berionni G.
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Surface‐Engineered Dual‐Emission of Carbon Dots for Ratiometric Detection of Hydroxyl Radicals
Nanophotonics, Volume 15, Issue 9, 13 May 2026.Oxidation‐engineered CDs with tunable dual emission (450/590 nm) exhibit oxidation state‐driven electron redistribution and core‐to‐surface transfer within 5 ps, achieving 59 nM ·OH detection via ratiometric sensing and enabling dual‐channel ·OH monitoring in onion cells.
Yatao Pan +6 more
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Chemical Bonds Containing Hydrogen: Choices for Hydrogen Carriers and Catalysts. [PDF]
Angew Chem Int Ed EnglCashel J +9 more
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Advanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.A highly stereoselective desymmetrization of pseudo‐para diformyl[2.2]paracyclophanes is developed via chiral Brønsted acid‐catalyzed reductive amination. This protocol provides efficient access to enantiopure planar chiral paracyclophanes with broad substrate scope, excellent enantioselectivity, and versatile postsynthetic functionalization. Access to
Sandip Baban Shinde +4 more
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Direct measurement of covalent three-center, two-electron M-H-B bonding in Zr and Hf borohydrides using B K-edge XAS. [PDF]
Chem SciHansen HM +9 more
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Advanced Synthesis &Catalysis, Volume 368, Issue 9, 5 May 2026.An exceptionally Lewis acidic boronic acid ester, generated in situ from pentafluorophenylboronic acid and tetrabromonaphthalenediol, catalyzes three important chemical transformations at 1–10 mol% loading: the Hosomi–Sakurai allylation of α,β‐unsaturated ketones, intermolecular carbonyl‐ene reactions, and the reductions of tertiary amides to amines ...
Ava Bousselat +5 more
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