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A Series of Mixed‐Metal Borohydrides
Angewandte Chemie - International Edition, 2009Mix and match: A novel series of alkali-metal zinc borohydrides, LiZn 2(BH 4) 5 (see picture), NaZn 2(BH 4) 5, and NaZn(BH 4) 3, with fascinating structures are presented. An interpenetrated network structure, containing a [Zn 2(BH 4) 5] -. ion, is observed for the first time for a borohydride.
Yaroslav Filinchuk +2 more
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The reaction of aluminum borohydride with tetraethylammonium borohydride
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 19701. A complex borohydridoaluminate, [(C2H5)4N][Al(BH4)4] has been prepared by the reaction of aluminium borohydride with tetraethylammonium borohydride at room temperature. Its IR spectrum and x-ray photograph have been investigated. 2. The complex decomposes with the evolution of H2, C2H6, (C2H5)3N, metallic aluminum, and boron over the ...
L. V. Titov +3 more
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Complex of aluminum borohydride with calcium borohydride
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 19751. The reaction of Al(BH4)3 with the unsolvated Ca(BH4)2 gave the complex Ca(BH4)2·Al(BH4)3, which is stable at room temperature; its density and IR spectrum are given. 2. Ca(BH4)2·Al(BH4)3 decomposes completely into the component borohydrides when heated in vacuo or when treated with donor solvents.
L. V. Titov, E. R. Eremin
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Complexes of manganese borohydride with the borohydrides of organic cations
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, 19891. Reaction of MnCBH4)2(THF)3 with tetrabutylammoniura and tetraphenylphosphonium borohydndes, and with tetraphenylphosphonium chloride, has given the compounds (Bu4N)[Mn(BH4)3], (Ph4P)[Mn(BH4)3], (Ph4P)[Mn(BH4)3(THF)], (Ph4P) [Mn(BH4)3Cl], and (Ph4P) [Mn(BH4)2Cl(THF)], which have been characterized by IR spectroscopy and thermogravimetric studies.
V. D. Makhaev +5 more
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