Results 21 to 30 of about 3,802 (275)

The Borohydride Ion in the Lithium Borohydride Lattice [PDF]

Nature, 1961
IN a recent communication in Nature, Dr. C. J. H. Schutte1 has suggested that the anomalous band occurring at about 1,250 cm.−1 in the paraffin-oil mull spectrum of lithium borohydride at room temperature2 may be assigned to the doubly degenerate frequency, ν2(E), of tne tetrahedral
openaire   +3 more sources

A Review of the MSCA ITN ECOSTORE—Novel Complex Metal Hydrides for Efficient and Compact Storage of Renewable Energy as Hydrogen and Electricity

Inorganics, 2020
Hydrogen as an energy carrier is very versatile in energy storage applications. Developments in novel, sustainable technologies towards a CO2-free society are needed and the exploration of all-solid-state batteries (ASSBs) as well as solid-state hydrogen
Efi Hadjixenophontos, Erika Michela Dematteis, Nicola Berti, Anna Roza Wołczyk, Priscilla Huen, Matteo Brighi, Thi Thu Le, Antonio Santoru, SeyedHosein Payandeh, Filippo Peru, Anh Ha Dao, Yinzhe Liu, Michael Heere   +12 more
doaj   +1 more source

Calcium Borohydride Ca(BH₄)₂: Fundamentals, Prediction and Probing for High-Capacity Energy Storage Applications, Organic Synthesis and Catalysis

Energies, 2023
Calcium borohydride (Ca(BH4)2) is a complex hydride that has been less investigated compared to its lighter counterpart, magnesium borohydride. While offering slightly lower hydrogen storage capacity (11.5 wt% theoretical maximum, 9.6 wt% under actual ...
Cezar Comanescu
doaj   +1 more source

Hydrogen Production via Hydrolysis and Alcoholysis of Light Metal-Based Materials: A Review

Nano-Micro Letters, 2021
As an environmentally friendly and high-density energy carrier, hydrogen has been recognized as one of the ideal alternatives for fossil fuels. One of the major challenges faced by “hydrogen economy” is the development of efficient, low-cost, safe and ...
Liuzhang Ouyang, Jun Jiang, Kang Chen, Min Zhu, Zongwen Liu   +4 more
doaj   +1 more source

First-principles predicted low-energy structures of NaSc(BH4)4 [PDF]

, 2014
According to previous interpretations of experimental data, sodium-scandium double-cation borohydride NaSc(BH$_4$)$_4$ crystallizes in the crystallographic space group $Cmcm$ where each sodium (scandium) atom is surrounded by six scandium (sodium) atoms.
Huan Doan Tran, Maximilian Amsler, Miguel A. L. Marques, Ostwald W., Silvana Botti, Stefan Goedecker   +5 more
core   +2 more sources

Effect of the Process Parameters on the Energy Transfer during the Synthesis of the 2LiBH4-MgH2 Reactive Hydride Composite for Hydrogen Storage

Metals, 2019
Several different milling parameters (additive content, rotation velocity, ball-to-powder ratio, degree of filling, and time) affect the hydrogen absorption and desorption properties of a reactive hydride composite (RHC).
Julian Jepsen, Giovanni Capurso, Julián Puszkiel, Nina Busch, Tobias Werner, Chiara Milanese, Alessandro Girella, José Bellosta von Colbe, Martin Dornheim, Thomas Klassen   +9 more
doaj   +1 more source

Fundamental Material Properties of the 2LiBH4-MgH2 Reactive Hydride Composite for Hydrogen Storage: (I) Thermodynamic and Heat Transfer Properties

Energies, 2018
Thermodynamic and heat transfer properties of the 2LiBH4-MgH2 composite (Li-RHC) system are experimentally determined and studied as a basis for the design and development of hydrogen storage tanks.
Julian Jepsen, Chiara Milanese, Julián Puszkiel, Alessandro Girella, Benedetto Schiavo, Gustavo A. Lozano, Giovanni Capurso, José M. Bellosta von Colbe, Amedeo Marini, Stephan Kabelac, Martin Dornheim, Thomas Klassen   +11 more
doaj   +1 more source

Hydrides as high capacity anodes in lithium cells: an Italian “Futuro in Ricerca di Base FIRB-2010” project [PDF]

, 2017
Automotive and stationary energy storage are among the most recently-proposed and still unfulfilled applications for lithium ion devices. Higher energy, power and superior safety standards, well beyond the present state of the art, are actually ...
Brutti, Sergio, Farina, Luca, Gatto, Sara, Manzi, Jessica, Meggiolaro, Daniele, Munao', David, Panero, Stefania, Paolone, Annalisa, Reale, Priscilla, Silvestri, Laura, Vitucci, FRANCESCO MARIA   +10 more
core   +4 more sources

Synthesis, Crystal Structures and Thermal Properties of Ammine Barium Borohydrides

Inorganics, 2020
Ammine metal borohydrides show large compositional and structural diversity, and have been proposed as candidates for solid-state ammonia and hydrogen storage as well as fast cationic conductors.
Jakob B. Grinderslev, Mads B. Amdisen, Torben R. Jensen   +2 more
doaj   +1 more source

Exploring structural and electronic effects in three isomers of tris{bis(trifluoromethyl)phenyl}borane: Towards the combined electrochemical-frustrated Lewis pair activation of H2 [PDF]

, 2015
Three structural isomers of tris{bis(trifluoromethyl)phenyl}borane have been studied as the acidic com- ponent of frustrated Lewis pairs. While the 3,5-substituted isomer is already known to heterolytically cleave H2 to generate a bridging-hydride; ortho-
Andrew E. Ashley, Becke, Binding, Bourhis, Chapman, Chase, Chernichenko, Clark, Coles, Cornet, Dolomanov, Elliot J. Lawrence, Farrell, Fulmer, Gregory G. Wildgoose, Hariharan, Heiden, Herrington, Katie Resner, Kolychev, Konze, Lancaster, Lawrence, Lawrence, Lawrence, Lawrence, Lee, LeSuer, Lu, Mahdi, McDaniel, Melen, Ménard, Ménard, Palatinus, Palatinus, Palatinus, Robin J. Blagg, Rokob, Scott, Scott, Sheldrick, Sheldrick, Sivaev, Stephan, Stephan, Stephan, Stephan, Stephan, Stephan, Thomas J. Herrington, Vasily S. Oganesyan, Wang, Welch, Wu, Xu   +55 more
core   +1 more source