Dehydrogenation of Surface-Oxidized Mixtures of 2LiBH4 + Al/Additives (TiF3 or CeO2)
Inorganics, 2017 Research for suitable hydrogen storage materials is an important ongoing subject. LiBH4–Al mixtures could be attractive; however, several issues must be solved. Here, the dehydrogenation reactions of surface-oxidized 2LiBH4 + Al mixtures plus an additive
Juan Luis Carrillo-Bucio +2 more
doaj +1 more source
A Mechanistic Analysis of Phase Evolution and Hydrogen Storage Behavior in Nanocrystalline Mg(BH4)2 within Reduced Graphene Oxide. [PDF]
, 2020 Magnesium borohydride (Mg(BH4)2, abbreviated here MBH) has received tremendous attention as a promising onboard hydrogen storage medium due to its excellent gravimetric and volumetric hydrogen storage capacities.
Guo, Jinghua +15 more
core +1 more source
Design of a Nanometric AlTi Additive for MgB2-Based Reactive Hydride Composites with Superior Kinetic Properties [PDF]
, 2018 Solid-state hydride compounds are a promising option for efficient and safe hydrogen-storage systems. Lithium reactive hydride composite system 2LiBH4 + MgH2/2LiH + MgB2 (Li-RHC) has been widely investigated owing to its high theoretical hydrogen-storage
Akiba, Etsuo +17 more
core +2 more sources
Investigating the Factors Affecting the Ionic Conduction in Nanoconfined NaBH4
Inorganics, 2021 Nanoconfinement is an effective strategy to tune the properties of the metal hydrides. It has been extensively employed to modify the ionic conductivity of LiBH4 as an electrolyte for Li-ion batteries. However, the approach does not seem to be applicable
Xiaoxuan Luo +2 more
doaj +1 more source
, 2016 Aluminum borohydride (Al(BH$_4$)$_3$) is an example of a promising hydrogen storage material with exceptional hydrogen densities by weight and volume and a low hydrogen desorption temperature.
Harrison, D., Thonhauser, T.
core +1 more source
A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes [PDF]
, 2013 Frustrated Lewis pairs are compounds containing both Lewis acidic and Lewis basic moieties, where the formation of an adduct is prevented by steric hindrance.
Chernichenko, K. +2 more
core +1 more source
Tuning LiBH4 for Hydrogen Storage: Destabilization, Additive, and Nanoconfinement Approaches
Molecules, 2019 Hydrogen technology has become essential to fulfill our mobile and stationary energy needs in a global low–carbon energy system. The non-renewability of fossil fuels and the increasing environmental problems caused by our fossil fuel–running economy have
Julián Puszkiel +3 more
doaj +1 more source
Chemical Bonding Analysis on Amphoteric Hydrogen - Alkaline Earth Ammine Borohydrides
, 2017 Usually the ions in solid are in the positive oxidation states or in the negative oxidation state depending upon the chemical environment. It is highly unusual for an ion having both positive as well as negative oxidation state in a particular compound ...
Kiruthika, S, Ravindran, P
core +1 more source
Complex hydrides for hydrogen storage - New perspectives [PDF]
, 2014 Since the 1970s, hydrogen has been considered as a possible energy carrier for the storage of renewable energy. The main focus has been on addressing the ultimate challenge: eveloping an environmentally friendly successor for gasoline.
Bellosta Von Colbe, José M. +12 more
core +2 more sources
Phase Engineering of Atomically Precise Nanoclusters (APNCs) of Gold and Beyond
Advanced Materials, EarlyView.Engineering the structural phase of materials is of paramount importance for both fundamental research and practical applications. In this Review, we summarize the recent progress in controlling the phases of atomically precise nanoclusters (APNCs) of gold, silver and copper, as well as bimetallic systems. The phase‐enabled material properties of APNCs
Yitong Wang +4 more
wiley +1 more source