Results 81 to 90 of about 68,370 (267)

Water Permeates and Plasticizes Amorphous Carbon Dots: Unraveling the Inner Accessibility of the Nanoparticles by Glass Transition Studies

open access: yesAdvanced Materials, EarlyView.
The water permeability of amorphous carbon dots (CDs) is demonstrated by investigating their plasticization. Novel polyamide‐based and amorphous nanoparticles are synthesized by controlling their inner packing density. Water plasticization is evidenced by the decrease of the CDs glass transition temperature with increasing the hydration degree.
Elisa Sturabotti   +8 more
wiley   +1 more source

Opportunities of Semiconducting Oxide Nanostructures as Advanced Luminescent Materials in Photonics

open access: yesAdvanced Materials, EarlyView.
The review discusses the challenges of wide and ultrawide bandgap semiconducting oxides as a suitable material platform for photonics. They offer great versatility in terms of tuning microstructure, native defects, doping, anisotropy, and micro‐ and nano‐structuring. The review focuses on their light emission, light‐confinement in optical cavities, and
Ana Cremades   +7 more
wiley   +1 more source

National Revival in the Works of Taras Shevchenko and Ján Kollár: Overlaps and Controversies [PDF]

open access: yesSlovenska Literatura, 2019
The paper sets a goal to find out whether Taras Shevchenko knew particular works of Ján Kollár, to point out possible contacts as well as typological overlaps between the both writers in terms of reflecting on national revival and also to draw attention ...
Oleksandr Boroň
doaj  

КОНТАКТИ І ТИПОЛОГІЧНІ ЗБІГИ МІЖ "СЕЛЯНСЬКИМИ ПОВІСТЯМИ" ЮЗЕФА КРАШЕВСЬКОГО І ПРОЗОЮ ТАРАСА ШЕВЧЕНКА

open access: yesВісник Київського національного університету імені Тараса Шевченка. Літературознавство. Мовознавство. Фольклористика, 2023
Прозова спадщина Тараса Шевченка, у якій із певною часткою умовності можна відстежити сліди творчого опрацювання інонаціональних літературних зразків, становить найбільш удячний матеріал для порівняльних студій.
Oleksandr Boron
doaj  

Azaporphyrinoid‐Based Photo‐ and Electroactive Architectures for Advanced Functional Materials

open access: yesAdvanced Materials, EarlyView.
A long‐standing collaboration between the Torres and Guldi groups has yielded diverse azaporphyrinoid‐based donor‐acceptor nanohybrids with promising applications in solar energy conversion. This conspectus highlights key molecular platforms and structure‐function relationships that govern light and charge management, supporting the rational design of ...
Jorge Labella   +3 more
wiley   +1 more source

In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts

open access: yesAdvanced Materials, EarlyView.
An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea   +9 more
wiley   +1 more source

Boron beats nitrogen: strained boron–boron bonds as (molecular) proton sponges

open access: yesPhysical Chemistry Chemical Physics
The basicity and the hydrogen bond (HB) acceptor capability of diborane derivatives of dipyrazole 1 with a B–B bond have been studied theoretically using M06-2x and CCSD(T) methods. The proton affinities of 1b reach 1096 kJ mol −1 .
Ibon Alkorta   +4 more
openaire   +4 more sources

High Charge Carrier Mobility in Non‐Conjugated 3D Covalent Organic Frameworks

open access: yesAdvanced Materials, EarlyView.
A non‐conjugated 3D COF constructed via boronate ester linkages from tetraphenylene and pyrene‐based monomers is reported, which exhibits a high charge carrier mobility of 14 ± 1 cm2 V−1 s−1. ABSTRACT π‐Conjugation, π–π stacking, and long‐range order play a central role in determining charge transport efficiency in organic materials.
Joaquín Almarza   +11 more
wiley   +1 more source

Sub‐Nanometer Curvature Unlocks Quantum Orbital Flexoelectricity in Graphene

open access: yesAdvanced Materials, EarlyView.
In self‐assembled, reproducible, large‐area, quasi‐pristine graphene nanowrinkles, extreme curvature forces out‐of‐plane π‐electrons toward hybridization, driving a transition from classical to quantum orbital flexoelectricity. As curvature approaches the fundamental physical limit set by the C─C bond length, the resulting polarization increases by ...
Sathvik Ajay Iyengar   +8 more
wiley   +1 more source

Latinoamérica en la hora de los hornos

open access: yesRaigal, 2017
Son muchos los analistas y observadores de la escena internacional que expresan su aprehensión ante un mundo que se acerca temerariamente a una tercera guerra mundial.
Atilio Borón
doaj  

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