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Boron cluster leveraged polymeric building blocks
Chemical Society ReviewsThis review presents an insightful overview of current approaches for synthesis and application of boron cluster compounds-containing polymers.
Jianwei Li +4 more
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Elongation of Planar Boron Clusters by Hydrogenation: Boron Analogues of Polyenes
Journal of the American Chemical Society, 2012Dihydrogenated boron clusters, H(2)B(n)(-) (n = 7-12), were produced and characterized using photoelectron spectroscopy and computational chemistry to have ladderlike structures terminated by a hydrogen atom on each end. The two rows of boron atoms in the dihydrides are bonded by delocalized three-, four-, or five-center σ and π bonds.
Wei-Li, Li +3 more
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Ruthenium boron cluster chemistry
2018This thesis was digitised by the British Library from microfilm. You can acquire a single copy of this thesis for research purposes by clicking on the padlock icon on the thesis file. Please be aware that the text in the supplied thesis pdf file may not be as clear as text in a thesis that was born digital or digitised directly from paper due to the ...
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The σ delocalization in planar boron clusters
Dalton Transactions, 2009The sigma delocalization plays an important role in the stability of small boron clusters; therefore, it is important to establish under which circumstances this delocalization contributes to the aromaticity of these molecules. In this work, using electron localization function (ELF) calculations, we show that sigma and pi electrons follow different ...
Luis, Rincon +5 more
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Stealth Amphiphiles: Self-Assembly of Polyhedral Boron Clusters
Langmuir, 2016This is the first experimental evidence that both self-assembly and surface activity are common features of all water-soluble boron cluster compounds. The solution behavior of anionic polyhedral boranes (sodium decaborate, sodium dodecaborate, and sodium mercaptododecaborate), carboranes (potassium 1-carba-dodecaborate), and metallacarboranes {sodium ...
Ďorďovič, Vladimír +11 more
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Atomistic Study of Boron Clustering in Silicon
Solid State Phenomena, 2001We present the results of our theoretical investigation on the energetics of boron-interstitial clusters in silicon. In particular, we discuss the results obtained within a Density Functional derived Tight Binding (DFTB) scheme and further analyzed by Density Functional Theory calculations performed in the Local Density Approximation (DFT-LDA). We show
ALIPPI P. +2 more
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Structural transformations in boron clusters induced by metal doping
Chemical Society Reviews, 2022Jorge Barroso, Sudip Pan, Gabriel Merino
exaly