Pd(II)-Catalyzed Heteroarylative Difunctionalization of Unactivated Alkenes via Cascade Nucleopalladation of Alkynes. [PDF]
Patra J, Shukla RK, Volla CMR.
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Trimethylaluminum Activates Zeolite-Confined Lanthanum Borohydrides to Enhance Catalytic C-H Borylation. [PDF]
Li Y +5 more
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Regioselective access to B-N Lewis pair-functionalized anthracenes: mechanistic studies and optoelectronic properties. [PDF]
Zuo J +3 more
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Frontiers in Iridium-Catalyzed C-H Borylation: Attaining Novel Reactivity and Selectivity
Matthew A. Larsen
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High-Throughput Enabled Iridium-Catalyzed C-H Borylation Platform for Late-Stage Functionalization. [PDF]
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Enantioselective Miyaura Reaction by Desymmetrizing C(sp<sup>2</sup>)-B Cross-Coupling of 1,1'-Biaryl-2,6-diyl Bis(nonaflates). [PDF]
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A radical borylation of vinyl azides with NHC-boranes in the presence of tBuSH is described, which enables the divergent synthesis of α-boryl ketones and borylated triazoles with excellent functional group tolerance and a broad substrate scope.
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Formal nucleophilic borylation and borylative cyclization of organic halides
Organic & Biomolecular Chemistry, 2017Recent advances in borylations of organic halides, including both transition-metal-catalyzed and metal-free methods are summarized. Borylative cyclization is also discussed.
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Hydrogenation of Borylated Arenes
Angewandte Chemie International Edition, 2018AbstractA cis‐selective hydrogenation of abundant aryl boronic acids and their derivatives catalyzed by rhodium cyclic (alkyl)(amino)carbene (Rh–CAAC) is reported. The reaction tolerates a variety of boron‐protecting groups and provides direct access to a broad scope of saturated, borylated carbo‐ and heterocycles with various functional groups.
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