Star polymers rupture induced by constant forces [PDF]
In this work, we study the breakage process of an unknotted three-arm star-shaped polymer when it is pulled from its free ends by a constant force. The star polymer configuration is described through an array of monomers coupled by anharmonic bonds ...
Febbo, Mariano +3 more
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Ion-Molecule Reactions in Unsaturated Hydrocarbons: Allene, Propyne, Diacetylene, and Vinylacetylene [PDF]
Ion-molecule reactions in allene, propyne, diacetylene, and vinylacetylene (1-buten-3-yne) have been studied at near-thermal energies by the technique of ion cyclotron resonance mass spectrometry.
Anicich, Vincent G. +4 more
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Nucleic Acid Carriers Based on Precise Polymer Conjugates [PDF]
Polymer polydispersity, random conjugation of functional groups, and poorly understood structure–activity relationships have constantly hampered progress in the development of nucleic acid carriers.
Troiber, Christina, Wagner, Ernst
core +1 more source
Beneficial influence of nanocarbon on the aryliminopyridylnickel chloride catalyzed ethylene polymerization [PDF]
A series of 1-aryliminoethylpyridine ligands (L1―L3) was synthesized by condensation of 2-acetylpyridine with 1-aminonaphthalene, 2-aminoanthracene or 1-aminopyrene, respectively.
Durand, Jérôme +6 more
core +4 more sources
Influence of polymerisation conditions on the properties of polymer/clay nanocomposite hydrogels [PDF]
Free-radical polymerisation of acrylamide derivatives in the presence of exfoliated clay platelets has recently emerged as a new technique for the synthesis of strong and tough nanocomposite hydrogels (NCHs) with a unique hybrid organic/inorganic network
Abdurrahmanoglu +36 more
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Influence of pH on mechanical relaxations in high solids lm-pectin preparations [PDF]
The influence of pH on the mechanical relaxation of LM-pectin in the presence of co-solute has been investigated by means of differential scanning calorimetry, ζ-potential measurements and small deformation dynamic oscillation in shear.
Al-Ruqaie +42 more
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Charged solitons in branched conducting polymers
We consider dynamics of charged solitons in branched conducting polymers. An effective model based on the sine-Gordon equation on metric graphs is used for computing the charge transport and scattering of charge carriers at the polymer branching points ...
Babajanov, D. +2 more
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Molecular flexibility of citrus pectins by combined sedimentation and viscosity analysis [PDF]
The flexibility/rigidity of pectins plays an important part in their structure-function relationship and therefore on their commercial applications in the food and biomedical industries.
Alan Smith +47 more
core +1 more source
Density fields for branching, stiff networks in rigid confining regions
We develop a formalism to describe the equilibrium distributions for segments of confined branched networks consisting of stiff filaments. This is applicable to certain situations of cytoskeleton in cells, such as for example actin filaments with ...
Azote, Somiéalo +1 more
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Perspectives on the viscoelasticity and flow behavior of entangled linear and branched polymers
We briefly review the recent advances in the rheology of entangled polymers and identify emerging research trends and outstanding challenges, especially with respect to branched polymers. Emphasis is placed on the role of well-characterized model systems,
Olmsted, P. D. +3 more
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