Modulation of internuclear communication in multinuclear Ruthenium(II) polypyridyl complexes [PDF]
The syntheses and characterisation of a series of mononuclear and dinuclear ruthenium polypyridyl complexes based on the bridging ligands 1,3-bis-[5-(2-pyridyl)-1H-1,2,4-triazol-3-yl]benzene, 1,4-bis-[5-(2-pyridyl)-1H-1,2,4-triazol-3-yl]benzene, 2,5-bis-[
Adrian Guckian +4 more
core +2 more sources
Dangling and hydrolyzed ligand arms in [Mn3] and [Mn6] coordination assemblies: synthesis, characterization, and functional activity [PDF]
Two flexible, branched, and sterically constrained di- and tripodal side arms around a phenol backbone were utilized in ligands H3L1 and H5L2 to isolate {Mn6} and {Mn3} coordination aggregates.
Chattopadhyay, Krishna +8 more
core +3 more sources
1,4-Bis(4-nitrosophenyl)piperazine: novel bridging ligand in dinuclear complexes of rhodium(III) and iridium(III). [PDF]
The synthesis, spectroscopic characterization and crystal structures of the first 1,4-bis(4-nitrosophenyl)piperazine (BNPP) (4) bridged dinuclear complexes of rhodium(III) and iridium(III) are presented. The reaction of the μ2-halogenido-bridged dimers [(
Barth, Florian +2 more
core +1 more source
Competitive formation of spiro and ansa derivatives in the reactions of tetrafluorobutane-1,4-diol with hexachlorocyclotriphosphazene: a comparison with butane-1,4-diol [PDF]
Reaction of hexachlorocyclotriphosphazene, N3P3Cl6 (1), in two stoichiometries (1:1.2 and 1:3) with the sodium derivative of the fluorinated diol, 2,2,3,3-tetrafluorobutane-1,4-diol, (2), in THF solution at room temperature afforded six products, whose ...
Beşli, S. +5 more
core +1 more source
Rigid Macrocycle Metal Complexes as CXCR4 Chemokine Receptor Antagonists: Influence of Ring Size
Understanding the role of chemokine receptors in health and disease has been of increasing interest in recent years. Chemokine receptor CXCR4 has been extensively studied because of its defined role in immune cell trafficking, HIV infection, inflammatory
Isaline Renard +17 more
doaj +1 more source
Intrazeolite phototopotaxy. EXAFS analysis of precursor 8{W(CO)6}-Na56Y and photooxidation products 16(WO3)-Na56Y and 28(WO3)-Na56Y [PDF]
The intrazeolite photooxidation chemistry of alpha-cage encapsulated hexacarbonyltungsten(0) in Na56Y with O2, denoted n{W(CO)6}-Na56Y/O2/hv, which has previously been shown to provide a novel synthetic pathway to alpha-cage located tungsten(VI) oxide ...
Bein, Thomas +3 more
core +1 more source
Bridged chiral biaryls are axially chiral compounds with a medium-sized ring connecting the two arenes. Compared with plentiful methods for the enantioselective synthesis of biaryl compounds, synthetic approaches for this subclass of bridged atropisomers
Shuang-Hu Wang +8 more
doaj +1 more source
Trinuclear nickel coordination complexes of phenanthrene-9,10-dione dioxime
A trinuclear nickel complex of phenanthrene-9,10-dione dioxime (H2pqd), namely bis[μ2-9,10-bis(oxidoimino)phenanthrene]bis[μ2-10-(oxidoimino)phenanthrene-9-one oxime](phenanthrene-9,10-dione dioxime)trinickel(II) toluene disolvate, [Ni3(C14H8N2O2)2 ...
Owen M. Williams, Alan H. Cowley
doaj +1 more source
Building on Cram's legacy: stimulated gating in hemicarcerands. [PDF]
CONSPECTUS: Donald Cram's pioneering Nobel Prize-winning work on host-guest molecules led eventually to his creation of the field of container molecules. Cram defined two types of container molecules: carcerands and hemicarcerands.
Helgeson, Roger C, Houk, KN, Liu, Fang
core +2 more sources
Synthesis, Spectroscopy and Magnetism of Alkoxobridged Dinuclear Copper(II) Complexes with 2 Amino Picolines as the Ligands [PDF]
The synthesis, spectroscopic and magnetic characterization of a series of new alkoxo-bridged binuclear copper (II) compounds are described. All complexes have the general formula [Cu (m-OR)(L)2]2(ClO4)2 · x H2O, in which m-OR = CH3O-, C2H5O- or C3H7O-, L
Mehran Dadpu +2 more
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