Results 41 to 50 of about 76,906 (304)

Phase-vanishing halolactonization of neat substrates

open access: yesBeilstein Journal of Organic Chemistry, 2008
Phase-vanishing reactions are triphasic reactions which involve a reagent, a liquid perfluoroalkane as a phase screen and a substrate. The perfluoroalkane does not dissolve any of the reactants and is used to separate them.
Nicole Windmon, Veljko Dragojlovic
doaj   +1 more source

rac-(E,trans)-4-Bromo-10,10-dimethyl-9,11-dioxabicyclo[6.3.0]undec-4-ene

open access: yesIUCrData, 2020
In the title compound, a cyclooctene ring in a twist-boat conformation and a dioxolane ring with a distorted envelope conformation are annulated in a trans configuration. Alternating strands of single enantiomers build up the crystal. Within the strands,
Dieter Schollmeyer   +2 more
doaj   +1 more source

Bromine Incorporation and Suppressed Cation Rotation in Mixed-Halide Perovskites.

open access: yesACS Nano, 2020
Engineering the composition of perovskite active layers has been critical in increasing the efficiency of perovskite solar cells (PSCs) to more than 25% in the latest reports.
Andrew K. Johnston   +6 more
semanticscholar   +1 more source

Receptor‐Free Identification of Toxic Gases Enabled by Hygroscopic Aqueous Salt Films

open access: yesAdvanced Functional Materials, EarlyView.
Water as a gas sensor coating sounds impossible—until it stops evaporating. Here, hygroscopic salt solutions (LiCl, LiBr, H3PO4) form non‐drying aqueous films on CNT chemiresistors under ambient air. Gases partition into these liquid layers, sometimes transforming into water, and generate salt‐specific resistance fingerprints across a four‐channel ...
Seongwoo Lee   +5 more
wiley   +1 more source

Bromine mass balance calculation for dairy cows fed bromoform-based feed additives

open access: yesJournal of Agriculture and Food Research
Bromoform-based feed additives exhibit strong antimethanogenic potential. It is hypothesized that bromoform is dehalogenated in the rumen into multiple end products, including methane and bromine, yet little is known about bromine distribution and ...
Renata Tognelli   +5 more
doaj   +1 more source

Regioselective Synthesis of 5-Propyl-2-((trityloxy)methyl)thiophene-3-carbaldehyde

open access: yesMolbank, 2021
5-propyl-2-((trityloxy)methyl)thiophene-3-carbaldehyde was synthesized by using the concept of chemo- and regioselective Br/Li exchange reaction from 3-bromo-5-propyl-2-((trityloxy)methyl)thiophene.
Sukanta Bar
doaj   +1 more source

X‐Functionality–Driven Photocatalytic Hydrogen Evolution in 2D 4‐X‐PEA2SnI4 Perovskites

open access: yesAdvanced Functional Materials, EarlyView.
We report a water‐based synthesis of 2D 4‐X‐PEA2SnI4 perovskite microcrystals with prominent photocatalytic (PC) activity for H2 production. The synergy between organic functionalization and HI‐derived iodide scavenges holes suppress octahedral distortion, and favor electron accumulation, enabling a PC H2 evolution ∼20 µmol·g−1 and long‐term stability ...
Taeyeon Kim   +21 more
wiley   +1 more source

Asparagopsis taxiformis supplementation to mitigate enteric methane emissions in dairy cows—Effects on performance and metabolism

open access: yesJournal of Dairy Science
: Methane emissions from ruminant digestion contribute significantly to global anthropogenic greenhouse gas emissions. Members of the phylum Rhodophyta (red algae), particularly Asparagopsis sp., have shown promising results in reducing methane emissions
M. Angellotti   +4 more
doaj   +1 more source

Modelling future changes to the stratospheric source gas injection of biogenic bromocarbons

open access: yesGeophysical Research Letters, 2012
Simulations with a chemistry‐climate model (CCM) show a future increase in the stratospheric source gas injection (SGI) of biogenic very short‐lived substances (VSLS).
R. Hossaini   +11 more
doaj   +1 more source

Water‐Compatible SuFEx‐Active Diazonium Linchpin Platform for Rapid Modular Diversification and On‐DNA Functionalization

open access: yesAdvanced Functional Materials, EarlyView.
Sulfur fluoride exchange (SuFEx) is a powerful click platform, yet water‐compatible multifunctional linchpins remain elusive. Here, we report decagram‐scalable diazonium linchpins that enable rapid Pd‐catalyzed diversification and direct, catalyst‐free on‐DNA ligation in aqueous media.
Seok Ju Hong   +5 more
wiley   +1 more source

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