Clean 1H NMR Spectra of Products Directly from Batch and Flow Reaction Mixtures
Time‐resolved diffusion nuclear magnetic resonance (NMR) is a valuable tool in reaction monitoring. and multiway analysis of such data can provide access to the individual spectraof reaction components. Herein, batch and flow reactions are analysed using flow NMR to obtain the spectrum of newly‐formed products.
Yuliia Horbenko+8 more
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Patrilocality and hunter-gatherer-related ancestry of populations in East-Central Europe during the Middle Bronze Age. [PDF]
Chyleński M+31 more
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Synthesis and Aggregation of Amphiphilic Porphyrin‐Perylenebisimide Dyads
We report the straightforward synthesis of a family of amphiphilic zinc‐porphyrin‐perylenebisimide dyads containing sterically demanding substituents at the porphyrin meso‐position, as well as at the PBI bay position. The hydrophilic head group consists of oligo‐carboxylic acid G2‐Newkome dendrons attached to the porphyrin, whereas lipophilic pentyl ...
Erik Schulze+4 more
wiley +1 more source
Topographic thresholds for gully head formation in badlands
Gully topographic threshold model was extended to badlands, on the basis of data collected in the Mediterranean environment in Italy and Spain, characterized by diversified climatic, lithological, geological and anthropogenic settings. Criteria for the attribution of curve number values has been more objectively defined in order to reduce arbitrariness
Mauro Rossi+4 more
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La Sassa cave: Isotopic evidence for Copper Age and Bronze Age population dynamics in Central Italy. [PDF]
Romboni M+10 more
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Oxidation‐Deformylation Cascade Catalyzed By a Mononuclear Copper Complex
A bioinspired copper complex is able to catalyze two successive oxidative steps of alcohol conversion in the presence of hydrogen peroxide under mild conditions: (i) alcohol oxidation to aldehyde and (ii) aldehyde deformylation. Isotopic effects on the reaction rates indicate that hydrogen atom abstraction is rate limiting for both steps.
Yongxing Wang+8 more
wiley +1 more source
Ethnogenetic analysis reveals the Bronze Age genetic affiliation of Yashkuns with West Eurasians. [PDF]
Khan MU+6 more
europepmc +1 more source
Resilience, innovation and collapse of settlement networks in later Bronze Age Europe: New survey data from the southern Carpathian Basin. [PDF]
Molloy B+9 more
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Endohedral Coordination of Bulky Substrates in Metalloenzyme‐like Organometallic Nanotubes
Artificial receptors inspired by metalloenzymes share three key properties: a structurally flexible cavity, substrate binding via metal–ligand coordination, and metal‐based redox activity. Herein, we report an organometallic nanotube with such features based on our supramolecular pillarplex platform, with eight CuI centers integrated in its cavitand ...
Thomas Pickl+7 more
wiley +1 more source
The dynamics of Bovini exploitation strategies on the Central Plains of China from the Middle Neolithic to the Bronze Age. [PDF]
Pei X, Liang F, Cao Y, Zhang Y.
europepmc +1 more source