Organocatalytic C–H activation reactions
Beilstein Journal of Organic Chemistry, 2012 Organocatalytic C–H activation reactions have recently been developed besides the traditional metal-catalysed C–H activation reactions. The recent non-asymmetric and asymmetric C–H activation reactions mediated by organocatalysts are discussed in this ...
Subhas Chandra Pan
doaj +2 more sources
Gold(I)-Mediated C−H Activation of Arenes
, 2016 Gold(I)-Mediated C−H Activation of ...
Pengfei Lu (549353) +3 more
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Tandem C–O and C–H Activation at Palladium Enables Catalytic Direct C–H Alkenylation with Enol Pivalates [PDF]
, 2021 The use of oxygen-based electrophiles in cross-coupling remains challenging for substrates with strong C–O bonds, with few examples that can combine C–O activation with an-other strong-bond activation in tandem.
Nahiane, Pipaon Fernandez +4 more
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δ-C(sp3)H Activation of Free Alcohols Enabled by Rationally Designed H-Bond-Acceptor Ligands [PDF]
, 2023 The ability to employ a wide range of native substrates is essential for the broad application of transition-metal-catalyzed C–H activation. Recent advances have made native carboxylic acids, ketones, and amines amenable to C(sp3)–H activation, but ...
Jin-Quan, Yu +9 more
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C—H Activation of Unbiased C(sp3)—H Bonds [PDF]
, 2022 The selective functionalization of non-activated C(sp3)—H bonds is a major challenge in chemistry. Here, we have developed an [Au]-catalyzed C(sp3)-H activation of common 1 bromoalkynes into a library of diverse 3D-scaffolds.
Pablo, Barrio +6 more
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Transition Metal-catalyzed C-H /C-C Activation and Coupling with 1, 3-diyne [PDF]
, 2022 This review focuses on providing a broad overview of the recent developments in the field of transition metal-catalyzed C-H bond activation and coupling with 1,3-diyne for assembling alkynylated heterocycles and bis-heterocycles.
Tanmayee, Nanda +4 more
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Twofold C-H Activation-Based Enantio- and Diastereoselective C-H Arylation Using Diarylacetylenes as Rare Arylating Reagents [PDF]
, 2021 C-H bond activation has been established as an attractive strategy to access axially chiral biaryls, and the most straightforward method is direct C-H arylation of arenes.
Xingwei, Li +4 more
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Dual Catalytic C(sp2)–H Activation of Azaheterocycles towards C–N Atropisomers [PDF]
, 2023 We describe a PdII-catalyzed enantioselective C(heteroaryl)–H activation method enabled by a chiral transient directing group (cTDG) to gain access to C–N atropisomers.
Quynh, Wong +5 more
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Direct Light Activation of Hypervalent Iodine Reagents: Substrate-Controlled C-C or C-H Alkynylation of Cyclopropanes [PDF]
, 2022 We report the direct light activation of ethynylbenziodoxolone (EBX) reagents for the oxyalkynylation of aryl- and amino-cyclopropanes as well as styrenes. Irradiation with visible light at 440 nm promoted the reaction without the need of a photocatalyst.
Tin. V. T. , Nguyen, Jerome, Waser
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Multiple C–H Activation Enabled Modular Construction of Densely Functionalized Sulfur-Contained Arenes [PDF]
, 2021 Modular construction of multiple functionalized arenes from abundant feedstocks, stands as an unremitting pursue goal in synthetic chemistry, which would accelerate the discovery of new drugs an advanced materials.
Jianhang, Rao +6 more
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