Results 11 to 20 of about 2,063,218 (218)

Photocatalytic C−H activation and C−C coupling of monohydric alcohols

open access: yesCatalysis Communications, 2021
Monohydric alcohols, such as methanol, ethanol, are useful chemical building blocks that can be facilely produced from various carbon resources. The direct conversion of alcohols into high-value-added chemicals, in particular diols, is attractive but ...
Limei Wang   +5 more
doaj   +1 more source

Strategies to transform remote C(sp3)-H bonds of amino acid derivatives

open access: yesTetrahedron Chem, 2022
Amino acids and peptides play an important role in nature as well as in the pharmaceutical industry. Therefore, transformation of amino acids and peptides into their unnatural derivatives via step and atom economical ways is highly demanding. Although, a
Supreeta Sen   +2 more
doaj   +1 more source

When transition-metal-catalyzed C–H activation meets allene chemistry

open access: yesTetrahedron Chem, 2023
Transition-metal-catalyzed allenes-involved C–H functionalizations demonstrate unique selectivity and undergo exceptional pathways due to the existence of elusive orthogonal cumulative CCC bonds.
Shu-Meng Deng   +2 more
doaj   +1 more source

Functionalization of Porphyrins Using Metal-Catalyzed C–H Activation

open access: yesInorganics, 2022
The review is devoted to the C–H functionalization of porphyrins. Porphyrins exhibit the properties of organic semiconductors, light energy converters, chemical and electrochemical catalysts, and photocatalysts.
Aleksey N. Kiselev   +3 more
doaj   +1 more source

Rollover Cyclometalation as a Valuable Tool for Regioselective C–H Bond Activation and Functionalization

open access: yesMolecules, 2021
Rollover cyclometalation constitutes a particular case of cyclometallation reaction. This reaction occurs when a chelated heterocyclic ligand loses its bidentate coordination mode and undergoes an internal rotation, after which a remote C–H bond is ...
Antonio Zucca, Maria I. Pilo
doaj   +1 more source

A synthetic, catalytic and theoretical investigation of an unsymmetrical SCN pincer palladacycle [PDF]

open access: yesRoyal Society Open Science, 2016
The SCN ligand 2-{3-[(methylsulfanyl)methyl]phenyl}pyridine, 1, has been synthesized starting from an initial Suzuki–Miyaura (SM) coupling between 3-((hydroxymethyl)phenyl)boronic acid and 2-bromopyridine.
Gavin W. Roffe   +10 more
doaj   +1 more source

Coumarins Synthesis and Transformation via C–H Bond Activation—A Review

open access: yesInorganics, 2022
For several decades, coumarins have attracted considerable attention due to the fact of their application in diverse fields such as medical science and biomedical research as well as several industrial branches.
Katarzyna Szwaczko
doaj   +1 more source

Direct C–H Arylation

open access: yesCHIMIA, 2022
Bonds between hydrogen and carbon atoms are the most frequent type of bonds in organic molecules. The ability to replace hydrogen atoms by making other types of bonds to carbon atoms can enable simpler access to complex organic molecules by substituting
Jyoti Dhankhar, Ilija Čorić
doaj   +1 more source

Recent Developments in C–H Activation for Materials Science in the Center for Selective C–H Activation

open access: yesMolecules, 2018
Organic electronics is a rapidly growing field driven in large part by the synthesis of π-conjugated molecules and polymers. Traditional aryl cross-coupling reactions such as the Stille and Suzuki have been used extensively in the synthesis of &pi ...
Junxiang Zhang   +5 more
doaj   +1 more source

Organocatalytic C–H activation reactions

open access: yesBeilstein Journal of Organic Chemistry, 2012
Organocatalytic C–H activation reactions have recently been developed besides the traditional metal-catalysed C–H activation reactions. The recent non-asymmetric and asymmetric C–H activation reactions mediated by organocatalysts are discussed in this ...
Subhas Chandra Pan
doaj   +1 more source

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