Results 1 to 10 of about 26,610,004 (213)

Metal-free photoanodes for C–H functionalization

open access: yesNature Communications, 2023
Organic semiconductors, such as carbon nitride, when employed as powders, show attractive photocatalytic properties, but their photoelectrochemical performance suffers from low charge transport capability, charge carrier recombination, and self-oxidation.
Junfang Zhang   +8 more
doaj   +1 more source

Photoredox catalysis in nickel-catalyzed C–H functionalization

open access: yesBeilstein Journal of Organic Chemistry, 2021
Catalytic C‒H functionalization has become a powerful strategy in organic synthesis due to the improved atom-, step- and resource economy in comparison with cross-coupling or classical organic functional group transformations.
Lusina Mantry   +3 more
doaj   +1 more source

DABCO-promoted photocatalytic C–H functionalization of aldehydes

open access: yesBeilstein Journal of Organic Chemistry, 2021
Herein we present a direct application of DABCO, an inexpensive and broadly accessible organic base, as a hydrogen atom transfer (HAT) abstractor in a photocatalytic strategy for aldehyde C–H activation.
Bruno Maia da Silva Santos   +4 more
doaj   +1 more source

Functionalization of Porphyrins Using Metal-Catalyzed C–H Activation

open access: yesInorganics, 2022
The review is devoted to the C–H functionalization of porphyrins. Porphyrins exhibit the properties of organic semiconductors, light energy converters, chemical and electrochemical catalysts, and photocatalysts.
Aleksey N. Kiselev   +3 more
doaj   +1 more source

Recent Advances in C–H Functionalization of Pyrenes

open access: yesChemistry, 2023
In recent years, transition metal-catalyzed C–H activation and site-selective functionalization have been considered to be valuable synthetic tactics to functionalize organic compounds containing multiple C–H bonds.
Srinivasarao Arulananda Babu   +2 more
doaj   +1 more source

Recent advances in metal catalyst- and oxidant-free electrochemical C-H bond functionalization of nitrogen-containing heterocycles

open access: yesFrontiers in Chemistry, 2022
The C-H functionalization of nitrogen-containing heterocycles has emerged as a powerful strategy for the construction of carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds.
Ya-Nan Li   +4 more
doaj   +1 more source

C–H bond functionalization reactions enabled by photobiocatalytic cascades

open access: yesGreen Synthesis and Catalysis, 2021
Light may participate in biocatalytic processes either by direct light-induced biocatalysis or by cascading light-induced chemical reactions with biocatalytic ones, which are acknowledged as photocatalysis.
Yuanying Li   +3 more
doaj   +1 more source

Tuning Benzylic C−H Functionalization of (Thio)xanthenes with Electrochemistry

open access: yesMolecules, 2023
Here, we report a tunable electrochemical benzylic C−H functionalization of (thio)xanthenes with terminal alkynes and nitriles in the absence of any catalyst or external chemical oxidant.
Changji Wang   +4 more
doaj   +1 more source

Recent advances in transition-metal-free C–H functionalization of imidazo[1,2-a]pyridines

open access: yesGreen Synthesis and Catalysis, 2022
Imidazo[1,2-a]pyridines are unique nitrogen-containing organic compounds with wide applications in pharmaceuticals, natural products, material science and organometallics.
Linlin Shi, Tiantian Li, Guang-Jian Mei
doaj   +1 more source

Recent Advances on Synthetic Methodology Merging C–H Functionalization and C–C Cleavage

open access: yesMolecules, 2020
The functionalization of C–H bonds has become a major thread of research in organic synthesis that can be assessed from different angles, for instance depending on the type of catalyst employed or the overall transformation that is carried out.
Hamid Azizollahi   +1 more
doaj   +1 more source

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