Radical Advances in C(sp3)−H Functionalization: Foundations for C–H Cross-Coupling [PDF]
, 2022 C−H functionalization reactions are playing an increasing role in the preparation and modification of complex organic molecules, including pharmaceuticals, agrochemicals, and polymer precursors.
Dung, Golden +2 more
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Arenes and Heteroarenes C–H Functionalization Under Enabling Conditions: Electrochemistry, Photoelectrochemistry & Flow Technology [PDF]
, 2023 C-H bond functionalization generates molecular complexity in single-step transformation. However, the activation of C-H bonds requires expensive metals or stoichiometric amounts of oxidizing/reducing species.
Ayesha , Murtaza +6 more
core +1 more source
Isodesmic C–H Functionalization: Carboxyl-Assisted Remote meta- and ortho-C–H Iodination of Arenes via Shuttle Catalysis [PDF]
, 2021 Isodesmic C–H functionalization reactions are extremely rare. Herein we report the first Pd(II)-catalyzed isodesmic C–H iodination of arenes using 2-nitrophenyl iodides as the mild iodinating reagents.
Lei, Cai +7 more
core +2 more sources
Organophotoredox-Catalyzed Direct C-H Functionalization of “Drug Prejudice” at Room Temperature [PDF]
, 2020 Organophotocatalytic C─H bond functionalization has attracted lot of attention in the past several years due to the possibility of catalysing reactions in a metal-free environment.
Narendra, Chaubey +2 more
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Remote C-H Functionalization of Aliphatic Amines [PDF]
This thesis summarizes our efforts in the development of methodologies aimed at remote C(sp3)–H functionalization of aliphatic amines. Amines are an important functional group present in a variety of biologically relevant molecules; however, examples of ...
Lee, Melissa
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Catalytic Intermolecular Functionalization of Benzimidazoles [PDF]
, 2019 This chapter describes contemporary strategies for selective catalytic intermolecular functionalization of the benzimidazole scaffold. Functionalization at nitrogen and position C-2 is well developed employing copper, palladium, rhodium, nickel, and ...
Fjellaksel, Richard +3 more
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Catalyst-Controlled C–H Functionalization of Adamantanes Using Selective H‑Atom Transfer [PDF]
, 2018 A method for the direct functionalization of diamondoids has been developed using photoredox and H atom transfer catalysis. This C–H alkylation reaction has excellent chemoselectivity for the strong 3° C–H bonds of adamantanes in polyfunctional molecules.
Abigail Feceu (5237030) +11 more
core +1 more source
Green Solvents for C-H Functionalization
, 2023 Organic solvents are ubiquitous in most of the synthetic processes and play a crucial role in influencing the chemical behavior of catalytic system and/or reactive species. Modern chemistry inevitably includes an evaluation of the chemical efficiency and
Rossini, Gabriele +3 more
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Ligand control of hydrocarbon C-H bond functionalization by uranyl photocatalysts [PDF]
, 2023 The aqueous uranyl dication has long been known to facilitate the UV light-induced decomposition of aqueous VOCs (volatile organic compounds), via the long-lived highly efficient, uranyl excited state.
Polly, Arnold +8 more
core +1 more source
Ru-Catalyzed Selective C–H Functionalization of Pyridotriazoles with Acrylates
SynOpen, 2021 Ruthenium-catalyzed efficient and selective C–H alkenylation of pyridotriazoles with acrylates is described. The combination of metals (Ru and Fe) plays a crucial role in achieving quantitative yields of the desired products.
Abhisek Joshi +2 more
doaj +1 more source