Results 11 to 20 of about 6,068,014 (260)
DABCO-promoted photocatalytic C–H functionalization of aldehydes
Beilstein Journal of Organic Chemistry, 2021 Herein we present a direct application of DABCO, an inexpensive and broadly accessible organic base, as a hydrogen atom transfer (HAT) abstractor in a photocatalytic strategy for aldehyde C–H activation.
Bruno Maia da Silva Santos +4 more
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Functionalization of Porphyrins Using Metal-Catalyzed C–H Activation
Inorganics, 2022 The review is devoted to the C–H functionalization of porphyrins. Porphyrins exhibit the properties of organic semiconductors, light energy converters, chemical and electrochemical catalysts, and photocatalysts.
Aleksey N. Kiselev +3 more
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Recent Advances in C–H Functionalization of Pyrenes
Chemistry, 2023 In recent years, transition metal-catalyzed C–H activation and site-selective functionalization have been considered to be valuable synthetic tactics to functionalize organic compounds containing multiple C–H bonds.
Srinivasarao Arulananda Babu +2 more
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Regioselective aliphatic C–H functionalization using frustrated radical pairs
Nature, 2023 Frustrated Lewis pairs (FLPs) are well documented for the activation of small molecules such as dihydrogen and carbon dioxide^ 1 – 4 . Although canonical FLP chemistry is heterolytic in nature, recent work has shown that certain FLPs can undergo single ...
Zhipeng Lu +7 more
semanticscholar +1 more source
Frontiers in Chemistry, 2022 The C-H functionalization of nitrogen-containing heterocycles has emerged as a powerful strategy for the construction of carbon-carbon (C-C) and carbon-heteroatom (C-X) bonds.
Ya-Nan Li +4 more
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Transannular C–H Functionalization of Cycloalkane Carboxylic Acids
Nature, 2023 Cyclic organic molecules are common among natural products and pharmaceuticals^ 1 , 2 . In fact, the overwhelming majority of small-molecule pharmaceuticals contain at least one ring system, as they provide control over molecular shape, often increasing ...
Guowei Kang +4 more
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C–H bond functionalization reactions enabled by photobiocatalytic cascades
Green Synthesis and Catalysis, 2021 Light may participate in biocatalytic processes either by direct light-induced biocatalysis or by cascading light-induced chemical reactions with biocatalytic ones, which are acknowledged as photocatalysis.
Yuanying Li +3 more
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Tuning Benzylic C−H Functionalization of (Thio)xanthenes with Electrochemistry
Molecules, 2023 Here, we report a tunable electrochemical benzylic C−H functionalization of (thio)xanthenes with terminal alkynes and nitriles in the absence of any catalyst or external chemical oxidant.
Changji Wang +4 more
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Recent advances in transition-metal-free C–H functionalization of imidazo[1,2-a]pyridines
Green Synthesis and Catalysis, 2022 Imidazo[1,2-a]pyridines are unique nitrogen-containing organic compounds with wide applications in pharmaceuticals, natural products, material science and organometallics.
Linlin Shi, Tiantian Li, Guang-Jian Mei
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Weak Coordination as a Powerful Means for Developing Broadly Useful C–H Functionalization Reactions
Accounts of Chemical Research, 2011 Conspectus Reactions that convert carbon–hydrogen (C–H) bonds into carbon–carbon (C–C) or carbon–heteroatom (C–Y) bonds are attractive tools for organic chemists, potentially expediting the synthesis of target molecules through new disconnections in ...
K. Engle, T. Mei, M. Wasa, jin-quan yu
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