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One-step construction of indolo[2,1-a]isoquinolines using solid calcium carbide as an alternative to gaseous acetylene

Synthetic Communications
An efficient method for the synthesis of indolo[2,1-a]isoquinolines using calcium carbide as an alkyne source, 2-(2-bromophenyl)-1H-indoles as starting materials, and copper as a catalyst is described.
Xinjie You   +3 more
semanticscholar   +1 more source

Modelling of a Plasma Reactor for the Synthesis of Calcium Carbide

Canadian Metallurgical Quarterly, 1998
Abstract Plasma synthesis of calcium carbide was investigated using calcium oxide and graphite powders. A semi-batch spout-fluid bed reactor with a DC plasma torch was used for the study. Argon was used to initiate the plasma and hydrogen gas was then added to increase power and raise the plasma jet enthalpy.
M. H. El-Naas   +5 more
openaire   +2 more sources

One‐Pot Three‐Component Construction of (Z)‐3‐Benzylidene‐2‐(quinolin‐8‐yl)isoindolin‐1‐ones Through C(sp2)−H Bond Activation Using Calcium Carbide as a Solid Alkyne Source

ChemistrySelect
A simple method for the synthesis of (Z)‐3‐benzylidene‐2‐(quinolin‐8‐yl)isoindolin‐1‐ones through C(sp2)−H bond activation, Sonogashira cross‐coupling and annulation tandem reactions using calcium carbide as a solid alkyne source, and benzamides as ...
Fei Wen   +8 more
semanticscholar   +1 more source

Phase Relationships in the Calcium Chloride – Calcium Carbide System

Canadian Journal of Chemistry, 1972
The system calcium chloride – calcium carbide has been examined by thermal analysis. The depression of the freezing point of CaCl2 by CaC2 is ideal. The system is a eutectic one, with a eutectic point at 90 mol% CaCl2 at 740 °C. Carbon is believed to be present in the electrolyte as the so called acetylide ion [Formula: see text] The melting point of ...
D. R. Morris, J. F. Maillot
openaire   +2 more sources

Calcium carbide poisoning via food in childhood

The Journal of Emergency Medicine, 2007
The fast ripening of fruits means they may contain various harmful properties. A commonly used agent in the ripening process is calcium carbide, a material most commonly used for welding purposes. Calcium carbide treatment of food is extremely hazardous because it contains traces of arsenic and phosphorous. Once dissolved in water, the carbide produces
Yağmur, Fatih   +5 more
openaire   +4 more sources

Thermodynamic Analysis of Calcium Carbide Production

Industrial & Engineering Chemistry Research, 2014
CaC2 production is studied from the viewpoint of thermodynamics using an equilibrium composition model with total Gibbs free energy minimization. It is found that CaC2 is formed directly from the reaction of C and CaO without an intermediate step under the conditions of industrial practice.
Leiming Ji, Zhenyu Liu, Qingya Liu
openaire   +2 more sources

Global Exploration of the Enthalpy Landscape of Calcium Carbide

The Journal of Physical Chemistry B, 2010
The enthalpy landscape of CaC(2) was investigated on the ab initio level, and possible (meta)stable structures are predicted. Simulated annealing was used as a global exploration method for the determination of the local minima on the enthalpy landscapes, where the only information supplied was the number of atoms per unit cell.
Martin Jansen   +3 more
openaire   +3 more sources

Preparation and curing method of red mud-calcium carbide slag synergistically activated fly ash-ground granulated blast furnace slag based eco-friendly geopolymer

Cement & Concrete Composites, 2023
Yuxuan Shi   +6 more
semanticscholar   +1 more source

Vinylation of Selected Terpenols with Calcium Carbide

Russian Journal of General Chemistry, 2017
A method for the synthesis of vinyl derivatives of the terpenols verbenol and fenchol by their reaction with calcium carbide was developed. It was found that addition of potassium fluoride affects the yield of nucleophilic addition of the corresponding alcoholate ions to acetylene.
openaire   +2 more sources

Preparation and carbonation hardening of low calcium CO2 sequestration materials from waste concrete powder and calcium carbide slag

Cement & Concrete Composites, 2023
Songhui Liu   +6 more
semanticscholar   +1 more source

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