Steuerung der Rotation eines Guanidiniumkations durch Kation‐π‐Wechselwirkungen
Ein Lanthanid‐π‐Container wurde für die Bindung eines Guanidiniumkations in dessen aromatischer Kavität mittels Kation‐π‐Wechselwirkungen verwendet. Röntgenkristallographie und Festkörper‐NMR‐Spektroskopie bei schneller Rotation um den magischen Winkel wurden verwendet, um die zugrundeliegenden Wirt‐Gast‐Interaktionen zu untersuchen.
Hannah Busch +12 more
wiley +1 more source
Controlling the Guanidinium Cation Rotation by Cation–π Interactions
A lanthanide π‐container has been employed to trap a guanidinium cation inside the aromatic cavity by cation–π interactions. X‐ray crystallography and solid‐state nuclear magnetic resonance (NMR) spectroscopy at fast magic‐angle spinning (MAS) frequencies have been utilized to probe the underlying host–guest interactions.
Hannah Busch +12 more
wiley +1 more source
A single‐molecule cascade supramolecular system comprising L/D‐FPy, CB[8], and SC4AD serves as an efficient light‐harvesting platform. It facilitates cascade energy transfer and chiral transfer to acceptor dyes. Co‐assembly with a PVA matrix produces a multicolor solid film that exhibits enhanced luminescence dissymmetry factors (glum), enabling ...
Yongxue Li +5 more
wiley +1 more source
Synthesis of Flavin–Calix[4]arene Conjugate Derivatives
AbstractThe synthesis of two new flavin substituted calix[4]arene derivatives, 9 and 10, is described. The first flavin substituted calix[4]arene derivative 9 was synthesized by the reaction of 3‐methylalloxazine (5) with 25,27‐bis(3‐bromopropoxy)‐26,28‐dihydroxy‐5,11,17,23‐tetra(tert‐butyl)calix[4]arene (4) in high yield (92%). The other derivative 10
Sayin, Serkan +4 more
openaire +3 more sources
New Carboxytriazolyl Amphiphilic Derivatives of Calix[4]arenes: Aggregation and Use in CuAAC Catalysis. [PDF]
Mironova D +8 more
europepmc +1 more source
The Use of Anhydrous Barium Hydroxide for Selective Alkylation of Dialkyloxy-tert-butyl-calix[4]arenes. [PDF]
Yesypenko OA, Trybrat OO, Kalchenko VI.
europepmc +1 more source
Synthesis of Imidazolium Cations Linked to Para-t-Butylcalix[4]arene Frameworks and Their Use as Synthons for Nickel-NHC Complexes Tethered to Calix[4]arenes. [PDF]
Chetcuti MJ +3 more
europepmc +1 more source
Synthesis of Ionizable Calix[4]arenes for Chelation of Selected Divalent Cations. [PDF]
Blumberg M +4 more
europepmc +1 more source
Electronic Tuning of Host-Guest Interactions within the Cavities of Fluorophore-Appended Calix[4]arenes. [PDF]
Rawat V, Vigalok A.
europepmc +1 more source
Synthesis of Ultrastable and Bioconjugable Ag, Au, and Bimetallic Ag_Au Nanoparticles Coated with Calix[4]arenes. [PDF]
Retout M, Jabin I, Bruylants G.
europepmc +1 more source

