Five adamantyl esters and ethers with alkyl substituents of increasing branching are investigated by rotational spectroscopy. From the experimental data, their accurate structures are derived. All the derivatives feature similar CC distances, regardless of the functional group, the alkyl substituent, or other effects as methyl top internal rotation ...
Nataša Burić+5 more
wiley +1 more source
Synthesis of New N,N′‐Diarylureas and Their Theoretical Study as Cannabinoid‐1 Receptor Inhibitors
A series of new pyrazolo‐ and triazolo‐based N,N′‐diarylureas is synthesized following the triphosgene protocol in the last step. Density functional theory calculations and molecular docking provide strong evidence that all new compounds bind strongly to the cannabinoid‐1 (CB‐1) receptor, showing comparable results with the known allosteric CB‐1 ...
Eirini Tsemperlidou+4 more
wiley +1 more source
Asymmetric Synthesis of 1-Heteroaryl-1-arylalkyl Tertiary Alcohols and 1-Pyridyl-1-arylethanes by Lithiation-Borylation Methodology [PDF]
Aggarwal V. K.+41 more
core +2 more sources
A sustainable valorization of chestnut wood waste is proposed through microwave‐assisted subcritical water extraction, optimized via central composite design. The extract is fractionated by membrane filtration and resin purification, enabling water recovery (up to 89%) and obtaining a tannin‐rich fraction, used to synthesize a PVA‐based biopolymer ...
Clelia Aimone+9 more
wiley +1 more source
Nitrogen‐Functionalized Lignin: Current Status, Applications, and Challenges
This Table of Contents graphic illustrates strategies for nitrogen‐functionalizing lignin via physical blending, chemical modification, and grafting copolymerization, enabling advanced applications in energy, environment, and biomedicine. The central concept highlights the synergy between lignin valorization and nitrogen chemistry for functional ...
Jiansong Chen+3 more
wiley +1 more source
Rapidly making biodegradable and recyclable paper plastic based on microwave radiation driven dynamic carbamate chemistry. [PDF]
Yang X+13 more
europepmc +1 more source
On Base-catalysed Reaction of Benzyl Carbamate with Formaldehyde
Shigeya Takeuchi+3 more
openalex +2 more sources
Trivalent Metal Lewis Acids Activate CO2 in Transfer Hydrogenations
Indium(III) triflate and other trivalent metal ions catalyst the transfer hydrogenation of CO2 to formate and a series of in situ tandem reactions to yield formamides or azoles. In contrast to previous reports, the reaction proceeds by CO2 activation instead of hydride abstraction from a transfer hydrogenation source. Using γ‐terpinene as a bio‐derived
Alexandros Paparakis+6 more
wiley +1 more source
Redirecting the Peptide Cleavage Causes Protease Inactivation. [PDF]
Breuer C+20 more
europepmc +1 more source
Analogs of Tuberin : Syntheses and Biological Activity of Some New 4-Methoxy Styryl Carbamates and 4-Methoxy Styryl Semicarbazones [PDF]
J. D. RAMANATHAN+4 more
openalex +1 more source