Results 81 to 90 of about 86,895 (336)

Crystal structures of 4-chlorophenyl N-(3,5-dinitrophenyl)carbamate and phenyl N-(3,5-dinitrophenyl)carbamate

Acta Crystallographica Section E: Crystallographic Communications, 2015
The title compounds, C13H8ClN3O6, (I), and C13H9N3O6, (II), differ in the orientation of the two aromatic rings. In (I), they are essentially coplanar, making a dihedral angle of 8.2 (1)°, while in (II), they are inclined to one another by 76.2 (1)°. The
Rajamani Raja, Subramaniyan Sathiyaraj, B. Mohamad Ali, A. Sultan Nasar   +3 more
doaj   +1 more source

Engineering of Multi‐Dynamic Bonds Toward Room‐Temperature Self‐Healing Epoxy/MXene Adaptable Network with Record‐High Toughness

Advanced Science, EarlyView.
Inspired by mussel nacre and byssus, a multi‐type dynamic chemically bonded epoxy/MXene adaptable network is fabricated through a hierarchical assembly strategy, establishing the toughest (210.75 MJ m−3) room‐temperature self‐healing (90.04% recovery within 2 h at 25 °C) epoxy resin to date, challenging the limitations of conventional thermosetting ...
Xiaobo Zhu, Yu Hao, Liang‐Feng Huang, Haichao Zhao, Liping Wang   +4 more
wiley   +1 more source

Total Synthesis of Isodaphlongamine H by Iridium‐Catalyzed Reductive [3 + 2] Cycloaddition of N‐Hydroxylactam

Angewandte Chemie, EarlyView.
The total synthesis of isodaphlongamine H was accomplished by a lactam strategy. This strategy started with alkylation and N‐oxidation of a readily available chiral lactam. For the key functionalization of the amide carbonyl, an iridium‐catalyzed reductive [3 + 2] cycloaddition of the N‐hydroxylactam afforded the tricyclic isoxazolidine, which was ...
Sora Iwamoto, Reki Nakano, Keiji Sasaki, Shoichiro Kobayashi, Yuki Taira, Koya Takei, Reiji Kawakita, Ayako Tokuyama, Haruto Nakamura, Manato Tomoike, Ryota Kawahara, Akari Murase, Siro Simizu, Noritaka Chida, Toshitaka Okamura, Takaaki Sato   +15 more
wiley   +2 more sources

Dibasic Derivatives of Phenylcarbamic Acid as Prospective Antibacterial Agents Interacting with Cytoplasmic Membrane

Antibiotics, 2020
1-[2-[({[2-/3-(Alkoxy)phenyl]amino}carbonyl)oxy]-3-(dipropylammonio)propyl]pyrrolidinium/azepan- ium oxalates or dichlorides (alkoxy = butoxy to heptyloxy) were recently described as very promising antimycobacterial agents. These compounds were tested in
Šárka Pospíšilová, Ivan Malík, Kristyna Bezouskova, Tereza Kauerova, Peter Kollar, Jozef Csöllei, Michal Oravec, Alois Cizek, Josef Jampilek   +8 more
doaj   +1 more source

In Situ Study of the Photodegradation of Carbofuran Deposited on TiO\u3csub\u3e2\u3c/sub\u3e Film under UV Light, Using ATR-FTIR Coupled to HS-MCR-ALS [PDF]

, 2013
The in situ study of the photodegradation of carbofuran deposited on a TiO2 catalyst film under UV light was carried out using the ATR-FTIR technique. The data were analyzed using a Hard–Soft Multivariate Curve Resolution-Alternating Least Squares (HS ...
Atifi, Abderrahman, Czarnecki, Kazimierz, Mountacer, Hafida, Ryan, Michael D.   +3 more
core   +1 more source

Insertion of carbon dioxide and isocyanide into tantalum-amide and tantalum-methyl bonds [PDF]

, 2001
The methyl–amide complex [TaCp*(NtBu)Me(NMe2)] (1a) was isolated by reaction of the chloro–methyl [TaCp*(NtBu)MeCl] complex with LiNMe2. Reaction of the mono-amide compounds [TaCp*(NtBu)XY] (X=NMe2, Y=Me (1a); X=NHtBu, Y=Me (1b), Cl (1c)) with CO2 gives ...
Royo Gracia, Pascual, Sánchez-Nieves Fernández, Javier   +1 more
core   +3 more sources

A Smart Ru‐Locked Chemiluminescence Probe via Bioorthogonal Activation for Highly Selective, Real‐Time and Noninvasive In Vivo Imaging of Thiol Dysregulation

Aggregate, EarlyView.
A smart Ru‐catalyzed chemiluminescence probe based on phenoxy‐adamantyl‐1,2‐dioxetane (PAD) scaffolds is developed for highly sensitive, real‐time in vivo imaging. Featuring a Ru‐locked activation mechanism and a chemiluminophore synthesized via an optimized route, this noninvasive probe enables selective, light‐independent detection of H₂S and thiol ...
Dongnan Guo, Dan Xu, Xiaofeng Wei, Chunying Fan, Bobo Wang, Laifu Li, Haixia Song, Wenguang Yang, Yujie Wang, Zhaojia Wang, Xiaofang Hou, Sicen Wang   +11 more
wiley   +1 more source

Automated Iterative N─C and C─C Bond Formation

Angewandte Chemie, EarlyView.
Automated iterative assembly of MIDA or TIDA boronate building blocks enables generalized and automated preparation of many different types of small functional molecules in a modular fashion. However, until now, this engine could not leverage nitrogen atoms as iteration handles, excluding molecules rich in N─C and C─C bonds.
Theodore Tyrikos‐Ergas, Sevasti Agiakloglou, Antonio J. LaPorte, Wesley Wang, Chieh‐Kai Chan, Clare E. Wells, Christopher K. Rakowski, Rachel I. Hammond, Jia Qiu, Jonathan D. Raymond, Tiago Vieira, John Limanto, Marc N. Feiglin, Daniel J. Blair, Martin D. Burke   +14 more
wiley   +2 more sources

Molecular characterization of ethyl carbamate toxicity in Caenorhabditis elegans

Toxicology Reports, 2022
Ethyl carbamate is a common contaminant prevalent in fermented food with probable carcinogenic effects in animals. To date, other toxicological properties of ethyl carbamate are not well characterized.
Jordan J. Comfort, Samantha C. Chomyshen, Brandon M. Waddell, Hadi Tabarraei, Cheng-Wei Wu   +4 more
doaj  

Diagnosis of Intoxication by the Organophosphate VX: Comparison Between an Electrochemical Sensor and Ellman´s Photometric Method

Sensors, 2008
An electrochemical sensor is introduced as a tool applicable for diagnosis of intoxication by cholinesterase inhibitors caused by the well-known nerve agent VX.
Kamil Kuca, Martina Hrabinova, Miroslav Pohanka   +2 more
doaj   +1 more source