Results 131 to 140 of about 28,247 (296)

Methyl 9H-carbazole-9-acetate

open access: yes, 2009
The title compound, C15H13NO2, was synthesized by N-alkylation of methyl bromoacetate with 9H-carbazole. The carbazole ring system is essentially planar (mean atomic deviation = 0.0346 Å) and makes a dihedral angle of 86.5 (7)
Yong-Jun He   +4 more
core   +1 more source

Synthesis and Properties of Conjugated Poly(1,8-carbazole)s

open access: yes, 2016
During our search of novel conjugated carbazole polymers, we succeeded in the efficient synthesis of conjugated poly(1,8-carbazole) derivatives. The synthetic route to the 1,8-difunctionalized carbazole monomers and the polymerization methods under the ...
Tsuyoshi Michinobu (1579453)   +2 more
core   +1 more source

Cyclopropylamine‐Derived Distonic Iminium Radicals: Photoinduced Strategies in Chemo‐ and Stereo‐Selective Synthesis

open access: yesChemistry – A European Journal, EarlyView.
Cyclopropylamines have emerged as powerful photocatalytic building blocks. Upon light‐induced single‐electron oxidation, they undergo strain‐release ring opening to generate distonic iminium radicals that enable diverse transformations, including ring‐opening functionalization, formal [3 + 2] cycloadditions, radical cascades, and asymmetric bond ...
Maria Chiara Cabua   +3 more
wiley   +1 more source

Synthesis of Tris(indol‐3‐yl)methanes From Indoles, CO2, and Dimethylphenylsilane With BPh3: Two‐Step Construction of π‐Conjugated Systems

open access: yesChemistry – A European Journal, EarlyView.
Tris(indol‐3‐yl)methanes were synthesized from indoles, CO2, and PhMe2SiH in the presence of BPh3 in acetonitrile at 50°C. One product, tris(4‐bromo‐1‐methylindol‐3‐yl)methane, underwent a palladium‐catalyzed cascade reaction for the formation of a novel polycyclic heteroaromatic compound, where the methine C(sp3) atom originating from CO2 was ...
Sha Li   +5 more
wiley   +1 more source

Hydrogen Release From Silicon─Hydrogen Systems: From Surface Chemistry to Higher‐Coordinate Molecular Mechanisms

open access: yesChemistry – A European Journal, EarlyView.
Hydrogen‐release processes in silicon chemistry occur across a broad spectrum of systems, including crystalline silicon surfaces, nanoporous materials, Zintl phases, and molecular hydrides. This Review highlights how Si─H activation and H2 evolution are governed by structure, coordination environment, and dynamic access to reactive geometries, with ...
Robin Rothfelder, Jonathan O. Bauer
wiley   +1 more source

Impacts of refining Canadian partially upgraded bitumen: Fluid catalytic cracking

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract In this study, we examine the fluid catalytic cracking (FCC) performance of vacuum gas oil (VGO) from partially upgraded bitumen (PUB), a novel refinery feedstock from Canadian bitumen. FCC experiments were conducted in a lab‐scale FCC unit with VGOs from two different PUBs prepared using thermal cracking and solvent deasphalting, along with ...
Yi Zhang   +3 more
wiley   +1 more source

A Co‐Deposition Approach for Self‐Assembled Molecules and Perovskites Achieving > 20% Efficiency in Wide‐Bandgap Perovskite Solar Cells

open access: yesEcoEnergy, EarlyView.
Developing the π‐conjugation extended carbazole self‐assembled molecule, written as XS22, for efficient co‐deposited wide‐bandgap perovskite solar cells. ABSTRACT Co‐deposited strategy of self‐assembled molecule (SAM) and perovskite could simplify the fabrication process as well as achieving the high‐performance solar cells.
Yuxiao Guo   +8 more
wiley   +1 more source

Polycarbazole–NiOOH Interfacial Engineering of BiVO4 Photoanodes for Efficient and Stable Solar Water Splitting

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A π‐conjugated carbazole (p‐CBZ) layer is electro‐polymerized on BiVO4 to form a p–n heterojunction that enhances charge separation and suppresses surface recombination, while a NiOOH co‐catalyst accelerates oxygen evolution kinetics. The synergistic BVO/p‐CBZ/NiOOH photoanode delivers a high photocurrent density and long‐term stability for efficient ...
Lakshman Sundar Arumugam   +11 more
wiley   +1 more source

Flexible Direct‐Conversion X‐Ray Detectors: From Emerging Materials to Conformal Imaging

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This comprehensive review analyzed the performance, challenges, and future directions of four emerging material systems for next‐generation flexible direct‐conversion X‐ray detectors: organic semiconductors, perovskites, metal–organic frameworks, and inorganic metal compounds.
Haipeng Di   +11 more
wiley   +1 more source

A Co‐Self‐Assembled Monolayer With Enhanced Coverage and Defect Passivation for Efficient Inverted Perovskite Solar Cells

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This study achieved a co‐self‐assembled monolayer (Co‐SAM) with more uniform coverage on nickel oxide substrates and enhanced passivation of buried interfaces by incorporating 4PABCz into Me‐4PACz. Perovskite solar cells fabricated with this Co‐SAM achieved an efficiency of 26.33% and exhibited enhanced stability. The combination of nickel oxide (NiOx)
Zhiwei Deng   +16 more
wiley   +1 more source

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