Results 131 to 140 of about 1,147 (212)

Synthesis of Aromatic Aldehydes by CH Formylation of Aromatics with Silyl Formates Prepared from CO2 and Hydrosilanes

Advanced Synthesis &Catalysis, Volume 368, Issue 12, 17 June 2026.
A new method has been developed for the C–H formylation of aromatic compounds using silyl formates synthesized from CO2 and hydrosilanes. This is the first report on the direct C–H formylation of aromatics with silyl formates. The formylation reactions were promoted by BBr3 or BCl3. The reaction mechanism has been clarified by DFT calculations. Despite
Natsumi Nitta, Kei Hirokawa, So Saibara, Bikash Dev Nath, Kazuto Takaishi, Tadashi Ema   +5 more
wiley   +1 more source

Synthesis of β‐Enamino Sulfoxides via Cine‐Substitution of 1‐Chlorovinyl p‐Tolyl Sulfoxides with Lithium Amides

Advanced Synthesis &Catalysis, Volume 368, Issue 12, 17 June 2026.
The cine‐substitution of 2‐aryl‐1‐chlorovinyl p‐tolyl sulfoxides with lithium amides yields β‐enamino sulfoxides with high efficiency. β‐Enamino sulfoxides are desulfinylated via the sulfoxide/magnesium exchange reaction with isopropylmagnesium chloride to yield enamines.
Tsutomu Kimura, Rio Dohira, Masataka Ogasawara, Takahiro Tsuru, Tsuyoshi Satoh   +4 more
wiley   +1 more source

Mild N‑Arylation of Sulfoximines With (Hetero)aryl Chlorides Enabled by α‐Methylnaphthyl‐tBuBrettPhos Palladium Triflate

Chemistry – A European Journal, Volume 32, Issue 23, 16 June 2026.
A readily accessible, air‐ and moisture‐stable palladium precatalyst, [Pd(1‐MeNAP)(tBuBrettPhos)]OTf, enables the direct N‐arylation of NH‐sulfoximines with (hetero)aryl chlorides under exceptionally mild conditions ideal for late‐stage diversification of drug‐like scaffolds.
Sourav Manna, Mahima Pilania, Kumarjit Sen, Nikolaos V. Tzouras, Angelino Doppiu, Lukas J. Gooßen   +5 more
wiley   +1 more source

Luminescent Donor‐Acceptor Radical With Propeller Chirality: Bright and Photostable Red Circularly Polarized Luminescence and Whispering Gallery Mode Resonance

Angewandte Chemie, Volume 138, Issue 24, 8 June 2026.
A series of donor‐attached brominated chiral luminescent radicals (CzTTBrM, 2CzTTBrM, and 3CzTTBrM) was synthesized, showing red to near‐infrared (NIR) circularly polarized luminescence (CPL) with exceptionally high PLQY of up to 76% and markedly enhanced CPL brightness (BCPL). Doping into polystyrene microspheres further yields whispering gallery mode
Kazuhiro Nakamura, Kenshiro Matsuda, Kosuke Anraku, Keiko Yamaoka, Taisuke Matsumoto, Fumitaka Ishiwari, Takeaki Zaima, Wataru Ota, Emiko Fujiwara, Tohru Sato, Yoshitaka Inoue, Soh Kushida, Yohei Yamamoto, Takuya Hosokai, Ken Albrecht   +14 more
wiley   +2 more sources

1,1‐Disubstituted Vinylbromides: Versatile Building Blocks for the Synthesis of Nitrogen‐Containing Heterocycles

European Journal of Organic Chemistry, Volume 29, Issue 23, 16 June 2026.
1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer, Jun Fang, Chonghuo Liu, Guillaume Lefèvre, Gérard Guillamot, Phannarath Phansavath, Virginie Ratovelomanana‐Vidal   +6 more
wiley   +1 more source

A Green and Highly Selective Approach to Copper‐Catalyzed Transfer Hydrodeuteration of Alkenes and Alkynes Using D2O

ChemSusChem, Volume 19, Issue 11, 15 June 2026.
Highly selective deuteration is now possible with a green and more environmentally benign reaction protocol for Cu‐catalyzed transfer hydrodeuteration of alkenes and alkynes. This was applied to the synthesis of precisely deuterated alkanes, including deuterated complex molecules and high enantiopurity isotopomers. Precisely labeled small molecules are
Aniel J. Rivera Arzola, Raffaele Senatore, Shashank P. Sancheti, Nazanin Farmanbordar‐Ghadikolaei, Brooks H. Pate, Joseph R. Clark   +5 more
wiley   +1 more source

Electrophilic Iodination of Heterocyclic Compounds. Recent Advances 2008–2025: Part II

European Journal of Organic Chemistry, Volume 29, Issue 22, 9 June 2026.
Electrophilic iodination using molecular iodine and iodide sources represents an efficient approach for accessing valuable iodinated organic compounds. This review highlights recent advances in the iodination of heterocyclic compounds from 2008 to 2025, emphasizing the role of heteroaryl iodides as important synthetic intermediates for biologically ...
Njomza Ajvazi, Stojan Stavber
wiley   +1 more source

Emerging Trends in Organic Photoreactions Utilizing Disulfides

European Journal of Organic Chemistry, Volume 29, Issue 21, 4 June 2026.
Disulfides are versatile, nontoxic alternatives to metal photocatalysts. This review explores their role as photoactivated thiyl‐radical precursors and bifunctional catalysts (HAT/electron shuttling) in diverse transformations. Strategies for electronic tuning and development into recyclable heterogeneous materials are highlighted for sustainable ...
Sunil Kumar, Bolormaa Bayarkhuu, Hong Y. Cho, Jeehye Byun   +3 more
wiley   +1 more source

Multi‐Dielectric Metasurfaces for Ultrabright, Tunable Structural Color and Reconfigurable Optical Filtering with Extraordinarily Large Color Span

Advanced Optical Materials, Volume 14, Issue 23, 19 June 2026.
Structural color generation is an emerging field for digital display and printing applications. This report presents a novel truncated‐cone design and the first use of GaP sandwiched between two layers of TiO2, demonstrating ultra‐bright, tunable colors with a record color gamut.
Md Rumon Miah, Yavuz Selim Aydın, Hilmi Volkan Demir   +2 more
wiley   +1 more source

Intermolecular Aggregation‐Induced Delayed Fluorescence Scintillators for Ultrahigh‐Resolution X‐Ray Imaging

Advanced Science, Volume 13, Issue 34, 19 June 2026.
An intermolecular AIDF strategy enables an organic X‐ray scintillator (OXST) that resists concentration quenching and efficiently utilizes singlet and triplet excitons. The AIDF emitter, embedded in a polysulfone matrix, yields bright, flexible, and transparent scintillation screens with ultralow detection limits and high spatial resolution, offering a
Jie Yuan, Ying Liu, Botao Zheng, Xu Zhao, Yongrong Wang, Peng Zhang, Yifei Liu, Jingxia Zheng, Ping Li, Jianwei Li, Shen Xu, Runfeng Chen, Ye Tao   +12 more
wiley   +1 more source