Enhancement of Dissymmetry Factors Through Axial Elongation of Hetero[n]helicenes
A benzofuran scaffolding strategy enables the synthesis of hetero[9]‐, [12]‐, and [15]helicenes. Structural and chiroptical analyses demonstrate that systematic axial elongation increases helical distortion and significantly amplifies luminescence dissymmetry.
Jeppe S. Mogensen +7 more
wiley +2 more sources
Efficient synthesis of complex supramolecular topologies via coordination angle modulation. [PDF]
Dang LL +7 more
europepmc +1 more source
Mechanistic Diversity in Photoexcited Radical Redox Chemistry: A Critical Evaluation
Many high‐profile examples of photoredox catalysis are proposed to proceed via excitation of an open‐shell intermediate form of the catalyst. However, there is much debate over whether such mechanisms are realistic and, if so, exactly how they can occur.
Samuel J. Horsewill +3 more
wiley +1 more source
Molecularly Templated Buried Interfaces for Inverted Perovskite Solar Cells
We demonstrate a molecularly matched buried interface between SAM and perovskite, enhancing adhesion and passivating defects. This optimized interface achieves 26.58% power conversion efficiency and 86.72% fill factor with exceptional operational stability in both large‐area and wide‐bandgap devices, thereby increasing efficiency and prolonging ...
Songyang Yuan +19 more
wiley +2 more sources
Suppressing Interfacial-Accelerated Degradation in Perovskite Solar Cells via Supramolecular Co-Assembly. [PDF]
Lu B +15 more
europepmc +1 more source
Improving xylitol production by semi-rational engineering of xylitol dehydrogenase and optimizing cofactor regeneration in Gluconobacter oxydans. [PDF]
Su JH, Guo JC, Liu L, Zhang HL, Liu D.
europepmc +1 more source
Divergent Synthesis of Möbius and Hückel N-Heterocycloarenes From a Common Macrocyclic Backbone. [PDF]
Chen H +6 more
europepmc +1 more source
Solvent Polarity as a Selective Modulator of the First Hyperpolarizability in Para-Substituted Azo-Carbazole Dyes. [PDF]
Ferreira MBM +3 more
europepmc +1 more source
Regioisomeric carbazole-dicyano-dioxin AIDF emitters for efficient triplet harvesting, two-photon absorption and bioimaging. [PDF]
Bera A +5 more
europepmc +1 more source

