Results 111 to 120 of about 2,741 (258)

Weak‐Solvent‐Coordination Inducing MnNCN Preferential Orientation Toward High‐Capacity and Fast‐Charge Lithium‐Ion Storage

open access: yesCarbon Energy, EarlyView.
Preferentially oriented MnNCN nanosheets with high active (003) facets were synthesized by an aqueous weak solvent‐coordination strategy, and highly integrated MnNCN/CNT composite was in‐situ constructed as a high‐capacity fast‐charging anode. NCM811//MnNCN/CNT pouch cell exhibits a high energy density of 325 Wh kg−1 with a long cycle‐life over 200 ...
Penghui Guo   +11 more
wiley   +1 more source

Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth‐Ligand Cooperation

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Over the past twenty years, main group chemistry has significantly expanded its scope to include reactivities once considered the exclusive domain of transition metals. Among the emerging concepts, element‐ligand cooperation has proven to be a powerful strategy for enabling bond activation reactions but remains relatively unexplored for ...
Lennart Hensle, Viktoria H. Gessner
wiley   +1 more source

A Novel Method for the Synthesis of Carbodiimide

open access: yesNippon kagaku zassi, 1971
N, N'-ニ置換チオ尿素と2, 3-ジクロル-5, 6-ジシアン-p-ベンゾキノン(DDQ)およびp-ベンゾキノンとの反応について研究を行なった。無水ニ塩化メチレン中,室温でN, N'-ニ置換チオ尿素とDDQとの反応を行なって黄色の生成物〔A〕を得た。この生成物〔A〕を過剰の2N水酸化ナトリウムで処理すると,対応するN, N'-ニ置換カルボジイミドを約70%の収率で与え,同時に2, 3-ジクロル-5, 6-ジシアンヒドロキノンおよび遊離イオウが得られた。一方, N, N'-ニ置換チオ尿素とp-ベンゾキノンとの反応を上記の条件で試みたが24時間後も反応は認められなかった。しかし2N塩酸の存在ではただちに反応が起こり油状または結晶性物質〔B〕が得られた。生成物〔B ...
openaire   +3 more sources

Design of Fuel‐Dependent, Complex‐Coacervate‐Based Synthetic Cells

open access: yesChemistry – A European Journal, EarlyView.
Fuel‐dependent synthetic cells form and persist only in the presence of chemical fuel, decaying under starvation. We establish design rules for hexapeptide‐based coacervates, showing that tryptophan enhances polyanion binding, extends lifetime, and reduces waste sensitivity.
Anna‐Lena Holtmannspötter   +9 more
wiley   +1 more source

Bioinspired Design and Synthesis of Polyphenolic Star‐Like and Hyperbranched Polyester Models

open access: yesChemistry – A European Journal, EarlyView.
Gallotannin‐inspired star‐like and hyperbranched aromatic polyesters were synthesized from D‐glucose and ABn‐type phenolic acid monomers, such as protocatechuic acid. This bioinspired approach afforded polyphenolic polymeric nanoparticles able to encapsulate hydrophobic dyes, opening new perspectives for biobased encapsulation and delivery systems ...
Guanfei Shen   +4 more
wiley   +1 more source

Revisiting the synthesis of dimethyl carbonate from methanol and carbon dioxide

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract The process for producing dimethyl carbonate (DMC) from carbon dioxide (CO2) and methanol is explored in this article. It provides an overview of the thermodynamics involved in DMC synthesis, discussing the challenges and potential solutions. The article highlights the reported use of catalysts and dehydrating agents to improve DMC yield and ...
Diego Alexander Santos Araque   +3 more
wiley   +1 more source

Spectral, Semi‐Spectral, and Bandwidth Flow Cytometric Implementation of Multiplex Cytokine Bead Assays

open access: yesCytometry Part A, EarlyView.
ABSTRACT Multiplex cytokine bead assays (MCBA) have previously been carried out on conventional (aka classical, or bandwidth) flow cytometers, and issues involving unmixing distortions were encountered when using the manufacturer's set‐up beads for unmixing full‐spectrum data.
Jacob Laster   +3 more
wiley   +1 more source

Molecular Modification Strategies for CO2 Electroreduction to C2+ Products: Classifications, Mechanisms, Advances, and Perspectives

open access: yesEcoEnergy, EarlyView.
This review comprehensively outlines molecular modification strategies for steering CO2 electroreduction toward C2+ products, including the classification of diverse molecular structures, elucidation of their roles in microenvironment regulation, dissection of C–C coupling pathway engineering, and forward‐looking perspectives on machine learning and ...
Lingling Peng, Hanwen Liu, Tianyou Peng
wiley   +1 more source

Advances in protein–polyphenol complexation: Unraveling mechanisms, modulation, and functional outcomes

open access: yesFood Biomacromolecules, EarlyView.
Abstract Polyphenolic compounds have attracted increasing market demand and extensive attention due to their potential health benefits and bioactivities. Meanwhile, proteins are widely used in the food industry for their nutritional and functional properties. However, the application of proteins in the food industry is often limited by challenges, such
Fang Li   +7 more
wiley   +1 more source

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