Results 151 to 160 of about 237,106 (303)

Beyond Presumptions: Toward Mechanistic Clarity in Metal‐Free Carbon Catalysts for Electrochemical H2O2 Production via Data Science

Advanced Materials, EarlyView.
Metal‐free carbon catalysts enable the sustainable synthesis of hydrogen peroxide via two‐electron oxygen reduction; however, active site complexity continues to hinder reliable interpretation. This review critiques correlation‐based approaches and highlights the importance of orthogonal experimental designs, standardized catalyst passports ...
Dayu Zhu, Hsi‐wen Wu, Xiao Wang, Jie Zhang   +3 more
wiley   +1 more source

Crystal Engineering of Reticular Materials for Gas‐ and Liquid‐Phase Hydrocarbon Separation

Advanced Materials, EarlyView.
Crystal engineering enables systematic study of structure/function relationships as exemplified by pore engineering of reticular sorbents, including porous coordination networks and covalent organic frameworks. This review assesses such studies applied across the full scope of industrially relevant hydrocarbon separations to provide insight into how ...
Xia Li, Soumya Mukherjee, Michael J. Zaworotko   +2 more
wiley   +1 more source

Archeo‐Inspiration from the Cultural History of Glass: Historic Accounts, Anecdotes and Hard Facts as Challenges to Modern Material Science

Advanced Materials, EarlyView.
Glass, historically valued for its purity and durability, has long inspired artists and societies. This article introduces the concept of “Archeo‐Inspiration”, drawing on cultural and historical contexts of glass to guide future material innovations.
Eva von Contzen, Julia von Ditfurth, Fabian Stroth, Bastian E. Rapp   +3 more
wiley   +1 more source

Structural Exploration of Zirconium Metal–Organic Frameworks Through Linker Desymmetrization and Modulator Compensation

Advanced Materials, EarlyView.
A linker‐desymmetrization‐modulator‐compensation (LDMC) strategy for constructing structurally diverse Zr‐MOFs is reported. This approach reduces linker symmetry to create defects in Zr‐clusters, which can be compensated for by modulator coordination. Using this approach, we synthesized PCN‐1005 and PCN‐1006, featuring unprecedented Zr‐clusters. In PCN‐
Rong‐Ran Liang, Kun‐Yu Wang, Zongsu Han, Kui Tan, Yihao Yang, Zhaoyi Liu, Joshua Rushlow, Jiatong Huo, Hong‐Cai Zhou   +8 more
wiley   +1 more source

Natural ocean alkalinization through erosion of glacial till and weathering at the seafloor

Communications Earth & Environment
The ocean absorbs about 25% of anthropogenic carbon dioxide emissions, with this uptake regulated by acid-neutralizing anions collectively termed alkalinity.
Florian Scholz, Janine Börker, Christoph Vogt, Jens Hartmann, Klaus Wallmann   +4 more
doaj   +1 more source

BILP-19-An Ultramicroporous Organic Network with Exceptional Carbon Dioxide Uptake. [PDF]

Molecules, 2017
Klumpen C, Radakovitsch F, Jess A, Senker J.   +3 more
europepmc   +1 more source

Porous Iridium Oxide Inverse Opal Catalysts Enable Efficient PEM Water Electrolysis

Advanced Materials, EarlyView.
Porous iridium‐based inverse opal (IrOx‐IO) structures are introduced as high‐performance, unsupported PEM‐WE anode catalysts. Their electrochemical behavior is analyzed through porosity/surface area tuning, voltage breakdown, and circuit modeling.
Sebastian Möhle, Kerolus Nasser Nagi Nasralla, Jakub Drnec, William Chèvremont, Peter Strasser   +4 more
wiley   +1 more source

High‐Performance Zero‐Gap Glycerol‐Fed Electrolyzer for C3 Chemicals and Hydrogen Production

Advanced Materials, EarlyView.
This work presents a dynamic, self‐regulating operation strategy that enables selective glycerol electrooxidation in the OER‐free regime, co‐producing C3 chemicals and hydrogen at cell voltages below 1.25 V. Voltage‐ and temperature‐resolved analyses define optimal operating conditions, achieving a sustained current density of 500 mA cm−2 at ∼1.21 V ...
Shayan Angizi, Inder Sangha, Mahsa Khoshnam, Mahdis Nankali, Ashkan Irannezhad, Amirhossein Rakhsha, Zahra Teimouri, Amir Foroozan, Mengnan Zhu, Navid Noor, Reza Eslami, Drew Higgins   +11 more
wiley   +1 more source

Operando X‐ray Spectroscopy Study of Pd and Pd–Au Laterally Condensed Catalysts during Selective Acetylene Hydrogenation: The Role of Carbon

Advanced Materials, EarlyView.
The selective hydrogenation of acetylene over laterally condensed Pd and Pd–Au catalysts (LCCs) was investigated using operando X‐ray absorption and photoelectron spectroscopy in combination with density functional theory. Pd‐LCCs were found to incorporate significantly more carbon into the metal lattice than Pd–Au LCCs, where the carbon uptake governs
Eylül Öztuna, Thomas Götsch, Daniel Cruz, Patrick Zeller, Olga V. Vinogradova, Zehua Li, Christian Rohner, Franz‐Philipp Schmidt, Zahra Gheisari, Alexander Steigert, Martin Muske, Michael Hävecker, Eugen Stotz, Iryna Antonyshyn, Frank Girgsdies, Olaf Timpe, Thomas Lunkenbein, Vanessa J. Bukas, Karsten Reuter, Robert Schlögl, Katarzyna Skorupska, Axel Knop‐Gericke, Beatriz Roldán Cuenya   +22 more
wiley   +1 more source

Report of the SNOMS Project 2006 to 2012, SNOMS SWIRE NOCS Ocean Monitoring System. Part 1: Narrative description

, 2013
The ocean plays a major role in controlling the concentration of carbon dioxide (CO2) in the atmosphere. Increasing concentrations of CO2 in the atmosphere are a threat to the stability of the earth’s climate.
Campbell, J.M., Donahoe, J., Hartman, M.C., Hartman, S.E., Hydes, D.J., Jiang, Z-P., Kelly-Gerreyn, B.A., Pagnani, M.   +7 more
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