Results 181 to 190 of about 70,737 (245)

Biosynthesis of the Fully Saturated C16 Homosesquiterpene Descartane Through Deprotonation With Cyclopropanation

open access: yesAngewandte Chemie International Edition, EarlyView.
A non‐canonical C16 sesquiterpene synthase from Morganella morganii produces the unusual scaffold descartane. Its cyclisation mechanism was rationalised by isotopic labelling experiments and DFT calculations. Site‐directed mutagenesis altered enzyme function, resulting in alternative products, including voltairene, which requires a different ...
Kexin Yang   +4 more
wiley   +1 more source

The Carbon Isotope Ratio as an Objective Biomarker of Added Sugar Intake: A Scoping Review of Current Evidence in Human Nutrition. [PDF]

open access: yesAdv Nutr
Tripicchio GL   +7 more
europepmc   +1 more source

Highly Enantio‐ and Diastereoselective Synthesis of Tetrahydrofuran Frameworks via Chiral Lewis Acid‐Catalyzed Formal [3+2] Cycloaddition of Allylsilanes

open access: yesAngewandte Chemie International Edition, EarlyView.
The first catalytic asymmetric formal [3+2] cycloaddition of allylsilanes delivers cis‐2,5‐disubstituted tetrahydrofuran‐3‐ones that serve as versatile intermediates for the synthesis of diverse bioactive scaffolds. ABSTRACT A formal [3+2] cycloaddition via cyclization/1,2‐hydride shift initiated by nucleophilic attack of allylsilanes has been ...
Hosung Lee   +5 more
wiley   +1 more source

Pulsed‐Laser Ablation for the Synthesis of High‐Entropy Alloy Aerogels Toward H2O2 Production and Water Decolorization

open access: yesAngewandte Chemie International Edition, EarlyView.
This work establishes a universal strategy for fabricating compositionally complex solid solution alloy aerogels via pulsed‐laser ablation and the sol‐gel process. The electrocatalytic capabilities of these aerogels are subsequently evaluated for H2O2 electrosynthesis and water treatment applications.
Cui Wang   +10 more
wiley   +1 more source

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