Results 191 to 200 of about 2,223,295 (291)

Structural and Functional Siderophore Remodeling by Enzymatic Delipidation

open access: yesAngewandte Chemie, EarlyView.
A surprising functional switch in bacterial siderophores was discovered through genome mining and the analysis of environmental and pathogenic Pandoraea species. Pandorachelin B, a lipocyclopeptide that promotes swarming motility, is cleaved by a specialized acylase, yielding a ring‐contracted, homodetic cyclopeptide, pandorachelin A, which exhibits ...
Elena Herzog   +5 more
wiley   +1 more source

Key Drivers of Activity and Selectivity in Cu‐Based Catalysts for Methanol Synthesis From CO2: Insights From Atomically Dispersed Promoters

open access: yesAngewandte Chemie, EarlyView.
Mechanistic studies on model Cu─M/SiO2 catalysts (M = Zn, Ga, and In) reveal that promoters enable a formate spillover pathway from Cu to Mn+ (n = 2 or 3) sites. The promoter's electronic effect on formate bond strengths serves as a quantitative descriptor for activity and selectivity, balancing spillover dynamics with intermediate stabilization to ...
Nat Phongprueksathat   +6 more
wiley   +1 more source

The carbon isotope ratio of alanine is a biomarker of added sugar and sugar-sweetened beverage intakes: a pooled analysis of 4 studies. [PDF]

open access: yesAm J Clin Nutr
Johnson JJ   +14 more
europepmc   +1 more source

Modulating Local Coordination in Single‐Atom Catalysts: From Fundamental Concepts to Emerging Breakthroughs in Electrocatalysis

open access: yesAngewandte Chemie, EarlyView.
This review summarizes atomic‐level design strategies for single‐atom catalysts, emphasizing modulation of the local coordination environment, active‐site geometry, and metal‐support interactions to optimize catalytic activity and stability in electrocatalytic energy conversion applications.
Ashwani Kumar, Harun Tüysüz
wiley   +1 more source

Direct Solar Power‐Driven Durable Ammonia Electrosynthesis From Nitrate Under Fluctuating Voltage Conditions

open access: yesAngewandte Chemie, EarlyView.
Isolated Sn sites on Cu(111) induce a highly asymmetric charge distribution, which promotes water dissociation, accelerates key intermediate hydrogenation, and suppresses competing hydrogen evolution. As a result, SnCu111 delivers NH3 Faradaic efficiencies above 90% over an 800 mV potential window and enables stable direct solar power‐driven NH3 ...
Xiaokang Wang   +8 more
wiley   +1 more source

Stable carbon isotope evolution of formaldehyde on early Mars. [PDF]

open access: yesSci Rep
Koyama S   +8 more
europepmc   +1 more source

Exclusive Hydroformylation of Terminal Olefins: A Phosphorus‐Free Ruthenium System for the Selective Functionalization of Complex Mixtures

open access: yesAngewandte Chemie, EarlyView.
Development of a phosphorus‐free Ru/DBU catalyst enabling highly chemo‐ and regioselective hydroformylation of terminal olefins, sparing internal double bonds. Optimization of reaction parameters, ligand effects, and substrate scope including industrial feedstocks was realized.
Mohamed Niyaz Vellala Syed Ali   +6 more
wiley   +1 more source

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