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Silicon‐Based Azo Compound‐Mediated CO Activation and N2 Release

open access: yesAngewandte Chemie, EarlyView.
A rare silicon(IV)‐based azo compound featuring a Si─N═N─Si linkage was synthesized via the direct reaction of an organoazide with a silaiminyl–silylene precursor. This compound undergoes an unusual CO activation process, resulting in N2 release and complete cleavage of the C≡O bond, forming a Si(II)/Si(IV) product bridged by an oxygen atom and an ...
Da Jin   +3 more
wiley   +2 more sources

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