Tetrazine Ligation in Living Systems: Beyond Fast Kinetics to Effective Bioorthogonality
Chemistry – A European Journal, EarlyView.Rapid reaction kinetics (k2) alone do not ensure successful tetrazine ligation in living systems. This review introduces ‘effective orthogonality’—focusing on chemical survival, availability, and encounter—as a practical framework. We highlight how bottlenecks shift from cellular sinks to in vivo delivery limits, offering design strategies for reliable
Junhyeong Yim +3 more
wiley +1 more source
Influence of Mediterranean shrublands management on soil carbon sequestration. [PDF]
iScienceGonzález-Morales M +3 more
europepmc +1 more source
A Low‐Symmetry FeII Tetrahedron From a Flexible Tritopic Ligand
Chemistry – A European Journal, EarlyView.A highly symmetric and flexible tris‐bidentate tritopic ligand forms an S4 meso homoleptic face‐capped FeII tetrahedron near‐quantitatively in acetonitrile. The addition of nitromethane solvent causes partial isomerization of this meso cage to the racemic homochiral tetrahedron, with the complexity of the system being moderated through solvophobic ...
Rosemary J. Goodwin +5 more
wiley +1 more source
Co-benefits of reduced carbon and water footprints and enhanced carbon sequestration with integrated organic-inorganic fertilization and cover cropping in hilly citrus orchards. [PDF]
Front Plant SciNing W +13 more
europepmc +1 more source
Precision Chemistry for Protein Lysine Modification
Chemistry – A European Journal, EarlyView.Selective modification of lysine residues is challenging due to their similar intrinsic reactivity. Inspired by enzymatic recognition, ligand‐guided electrophiles enable site‐selective labeling and functionalization, while ligand‐guided catalyses achieve regioselective installation of bio‐relevant post‐translational modifications.
Mayu Onoda, Motomu Kanai
wiley +1 more source
Carbon sequestration potential of community forests in Bhutan: a possible forest carbon pathway, trade-offs, and stakeholder perceptions. [PDF]
Carbon Balance ManagDelma S +6 more
europepmc +1 more source
Organelle‐Resolved Tetrazine‐trans‐Cyclooctene Click Chemistry for Cargo Delivery and Release
Chemistry – A European Journal, EarlyView.Bioorthogonal click chemistry tools provide a means for specific intracellular conjugation of molecules. In this study, we used reactive tetrazine (Tz) and TCO moieties for labeling of organelles and organelle‐specific delivery and activation of doxorubicin prodrugs.
Oleh Durydivka +6 more
wiley +1 more source
Earthworm breeding techniques and their roles in microbial regulation and soil carbon sequestration. [PDF]
Front MicrobiolWu J +6 more
europepmc +1 more source
Spatially resolved 23Na magnetic resonance dispersion measurement in porous media
The Canadian Journal of Chemical Engineering, EarlyView.Quantitative 23Na MRI was employed to analyze dispersion in realistic core plug samples and was compared with the conventional breakthrough curve. 23Na MRI provided a more effective aassessment of core plug heterogeneity than the conventional method. Abstract Tracer tests are widely used in the petroleum industry to assess reservoir core plugs, relying
Rheya Rajeev +5 more
wiley +1 more source
Dendrometric traits for developing biomass equations of tree and shrub species in carbon sequestration projects. [PDF]
Biodivers Data JWang CJ +5 more
europepmc +1 more source