Results 91 to 100 of about 2,271 (214)

Redox Complexity in Sodium Manganese Hexacyanomanganate and Its Influence on Sodium‐Ion Storage Performance

open access: yesAdvanced Energy Materials, EarlyView.
The role of each Mn site in the Na3‐xMn[Mn(CN)6]·zH2O compounds’ redox activity was investigated using a combined experimental–computational approach, which shows that only the low‐spin Mn‐C site undergoes redox changes (Mn1+ to Mn4+), while high‐spin Mn‐N remains unchanged. The study confirms the presence of the Mn1+ intermediate and newly reveals its
Zhenying Li   +11 more
wiley   +1 more source

Accelerated carbonation test data for concretes with varying slag content. [PDF]

open access: yesData Brief
Haavisto J   +5 more
europepmc   +1 more source

Unveiling the High‐Voltage Reactivity and Gas Evolution With Aluminum‐Based Chloride and Oxychloride Catholytes in Solid‐State Sodium Batteries

open access: yesAdvanced Energy Materials, EarlyView.
The work examines the electrochemical and interfacial behaviors of crystalline NaAlCl4 and amorphous Na–Al–oxychloride solid electrolytes with NaNi0.5Mn0.5O2 cathodes. Operando gas evolution and ToF‐SIMS analyses highlight that pure chloride solid electrolytes offer greater interfacial stability and safety compared to the oxychloride solid electrolytes
Erick Ruoff   +2 more
wiley   +1 more source

Synergistic Regulation of Interfacial Potential and Anionic Covalency for High‐Voltage Cobalt‐Free All‐Solid‐State Batteries

open access: yesAngewandte Chemie, EarlyView.
A synergistic interface regulation strategy using high‐dielectric BaTiO3 and sulfate‐derived S─O bonds is developed to unlock high‐voltage LiNi0.5Mn1.5O4 all‐solid‐state batteries. By mitigating space‐charge layer effects and stabilizing lattice oxygen, the system achieves high‐rate (3 C) and durable operation in 5 V‐class cobalt‐free solid‐state ...
Yue Wang   +5 more
wiley   +2 more sources

Image-Based Classification of Concrete Carbonation Using YOLO Models. [PDF]

open access: yesMaterials (Basel)
Aydın Y   +4 more
europepmc   +1 more source

Investigation Into the Electrochemical Performance of Micron‐ and Nanosized Tin in Diglyme and Carbonate Electrolytes in Sodium Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
This study compares Sn particles of different sizes in NIBs using carbonate‐ and diglyme‐based electrolytes. Diglyme electrolytes enable stable cycling despite large volume changes, while carbonate electrolytes degrade rapidly, especially with nanoparticles.
Chinnasamy Murugesan   +4 more
wiley   +1 more source

Design Guidelines for Anode Modifications to Eliminate Soft Short Circuits in Anode‐Free Na Batteries Under High Current Density With Large‐Capacity Plating, Demonstrated via Initiated Chemical Vapor Deposition (iCVD)

open access: yesAngewandte Chemie, EarlyView.
This work establishes a laterally homogeneous organic–inorganic hybrid interphase for soft‐short‐free anode‐free sodium metal batteries under extended cycling at high current density and high plating capacity. In contrast to conventional strategies that evolve into laterally heterogeneous interphases and induce localized Na filament growth, the pDFHA ...
Yeongjun Oh   +7 more
wiley   +2 more sources

In Situ Evolution of Artificial Interphase Enabling Stable, High‐Performance Lithium Metal Batteries

open access: yesAdvanced Energy Materials, EarlyView.
An evolutionary artificial interphase is presented for stable lithium metal batteries. A Mg3N2‐based layer spontaneously evolves into a hybrid interphase enriched with superionic Li3N and lithiophilic Mg‐Li alloy during cycling. This dynamic, self‐reinforcing mechanism effectively suppresses dendrite growth and enables exceptional long‐term cycling ...
Sangcheol Lee   +4 more
wiley   +1 more source

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