Results 131 to 140 of about 267,561 (310)

Modeling the hydrolysis of perfluorinated compounds containing carboxylic and phosphoric acid ester functions, alkyl iodides, and sulfonamide groups [PDF]

open access: yes, 2009
Temperature dependent rate constants were estimated for the acid- and base-catalyzed and neutral hydrolysis reactions of perfluorinated telomer acrylates (FTAcrs) and phosphate esters (FTPEs), and the SN1 and SN2 hydrolysis reactions of fluorotelomer ...
Kaya Forest, Sierra Rayne
core   +1 more source

Enhancing and Stabilizing Hydrogen Catalysis Through [NiFe]‐Hydrogenase Immobilization Within Macroporous Covalent Organic Frameworks

open access: yesAdvanced Functional Materials, EarlyView.
[NiFe]‐hydrogenases efficiently catalyze hydrogen conversion, but their instability limits biotechnological applications. Here it is shown that encapsulating hydrogenase into hierarchical COFs with macro‐ and micropores and functionalized with sulfonic or carboxylic acid groups improves enzyme stability and electron transfer to electrodes.
Islam E. Khalil   +12 more
wiley   +1 more source

Hydration of Carboxyl Groups: A Route toward Molecular Recognition? [PDF]

open access: yesJ Phys Chem B, 2020
Di Gioacchino M   +3 more
europepmc   +1 more source

The Effect of Amino Acids on the Formation of Amorphous Calcium Carbonate Nanoparticles

open access: yesAdvanced Functional Materials, EarlyView.
Biomineral formation often proceeds via the assembly of amorphous calcium carbonate (ACC) nanoparticles with narrow size distributions. Using in situ SAXS coupled to a stopped‐flow device, we follow synthetic ACC formation with a 10 ms time resolution and show that amino acids narrow the size distribution at low supersaturation, highlighting their key ...
Lucas Kuhrts   +10 more
wiley   +1 more source

Impact of Surface Functionalization on NV Quantum Properties: Implications for Biosensing with Fluorescent Nanodiamonds

open access: yesAdvanced Functional Materials, EarlyView.
Fluorescent nanodiamonds (fNDs) have emerged as an invaluable quantum sensing platform for biological and biochemical systems. This paper investigates the influence of common surface functionalization strategies for bioconjugation on the quantum properties of nitrogen vacancy (NV) centers in nanodiamonds.
Anja Sadžak   +6 more
wiley   +1 more source

Controlled Movement of Soft Actuators using Multi‐Responsive Microgel Arrays and Microcirculatory Systems

open access: yesAdvanced Functional Materials, EarlyView.
Microscale hydrogels (microgels) feature improved mass transport characteristics supportive of fast actuation and chemical tunability amenable to programmed stimuli response. A unique soft actuator architecture is realized by encapsulating microgels in soft microcirculatory systems which enable the convenient delivery of liquid stimuli for powering and
Nengjian Huang   +2 more
wiley   +1 more source

Reaction pathways and functional group transformation in CO/CO2 generation from low-rank coal at low temperature oxidation

open access: yesCase Studies in Thermal Engineering
Carbon monoxide (CO) and carbon dioxide (CO2) are the primary gases generated during the low-temperature oxidation (LTO) of coal. This study explores their generation mechanisms in low-rank coal through a combination of LTO experiments, in-situ Fourier ...
Liangzhou Chen   +5 more
doaj   +1 more source

Dental Composition Modified with Aryloxyphosphazene Containing Carboxyl Groups. [PDF]

open access: yesPolymers (Basel), 2020
Chistyakov EM   +3 more
europepmc   +1 more source

Living Liquid Metal Composites Embedded with Electrogenic Endospores for Next‐Generation Bioelectronics

open access: yesAdvanced Functional Materials, EarlyView.
A new class of living liquid metal composites is introduced, embedding Bacillus subtilis endospores into eutectic gallium–indium (EGaIn). The spores enhance droplet coalescence, strengthen interfacial conductivity, and provide on‐demand electrogenic functionality after germination. The composites exhibit high conductivity, self‐healing, patternability,
Maryam Rezaie, Yang Gao, Seokheun Choi
wiley   +1 more source

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