Electrochemical Borylation of Carboxylic Acids [PDF]
A simple electrochemically mediated method for the conversion of alkyl carboxylic acids to their borylated congeners is presented. This protocol features an undivided cell setup with inexpensive carbon-based electrodes and exhibits a broad substrate scope and scalability in both flow and batch reactors. The use of this method in challenging contexts is
Lisa M. Barton +3 more
openaire +3 more sources
Geometry and conformation of benzenecarboxylic acids [PDF]
The geometry, conformations and energy of mono-, di-, and tri-carboxylic derivatives of benzene were studied by means of the AM1 molecular-orbital method.
Marković Zoran +2 more
doaj +1 more source
Unravelling the surface chemistry of metal oxide nanocrystals, the role of acids and bases [PDF]
We synthesized HfO2 nanocrystals from HfCl4 using a surfactant-free solvothermal process in benzyl alcohol and found that the resulting nanocrystals could be transferred to nonpolar media using a mixture of carboxylic acids and amines.
De Keukeleere, Katrien +5 more
core +1 more source
Protonation and ring closure of stereoisomeric alpha-substituted cinnamic acids in superacidic media studied by 13C NMR spectroscopy and computations [PDF]
Five alpha-substituted cinnamic acids [(E)- and (Z)-2,3-diphenyl-, (E)- and (Z)-3-(2-methoxyphenyl)-2-phenyl- and (E)-2-(2-methoxyphenyl)-3-phenyl-propenoic acids] have been protonated in fluorosulfonic acid at -78 degrees C, Protonation of the ...
Burrichter, Arwed +5 more
core +1 more source
Valorization of Lignin by Partial Wet Oxidation Using Sustainable Heteropoly Acid Catalysts
The production of carboxylic acids by partial wet oxidation of alkali lignin at elevated temperatures and pressures was studied experimentally. Two different heteropoly acids, phosphotungstic acid (H3PW12O40) and phosphomolybdic acid (H3PMo12O40), were ...
Abayneh Getachew Demesa +3 more
doaj +1 more source
This study aimed to synthesize quinolinone derivatives and investigate their cytotoxic activity. The compound 1-azacoumarin-3-carboxylic acid (2-oxo-1H-quinoline-3-carboxylic acid) was obtained via the cyclocondensation of 2-hydroxybenzaldehyde with ...
Ahmed Gaber +5 more
doaj +1 more source
Addition of dianions of carboxylic acids to imines. Influence of the acid in the outcome of the reaction [PDF]
The addition of different carboxylic acids dianions to N-benzylidenebenzeneamine have been studied. The outcome of the reaction depends on the acid. Saturated ones lead to β-aminoacids with good yields and syn-selectivity whereas α,β-unsaturated ones ...
Gil Grau, Salvador +2 more
core +1 more source
Effectiveness of synthetic versus natural human volatiles as attractants for Anopheles gambiae (Diptera: Culicidae) sensu stricto [PDF]
Females of the African malaria vector, Anopheles gambiae Giles sensu stricto, use human volatiles to find their blood-host. Previous work has shown that ammonia, lactic acid, and aliphatic carboxylic acids significantly affect host orientation and ...
Knols, B.G.J. +2 more
core +2 more sources
The photoinduced decarboxylative radical addition of aryl carboxylic acids, including heteroaromatic carboxylic acids, to electron‐deficient alkenes is achieved in a two‐molecule photoredox system using a combination of biphenyl (BP) and 9,10 ...
Daisuke Suzuki +5 more
doaj +1 more source
Titanium Tetrachloride-Assisted Direct Esterification of Carboxylic Acids
Ester compounds, widely found in pharmaceutical and natural products, play a crucial role in organic synthesis, prompting the development of numerous methods for their synthesis. An important chemical approach in synthesizing esters from carboxylic acids
Palmira Alessia Cavallaro +6 more
doaj +1 more source

