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The 2007 Spring meeting of the Swiss Chemical Society was held at the University of Geneva on Friday March 9th. The general theme was catalysis and the different speakers covered various aspects of the field.
Alan F. Williams
doaj +1 more source
Engineering and Sizing Nanoreactors To Confine Metal Complexes for Enhanced Catalytic Performance [PDF]
Homogeneous metal complexes often display superior activity and selectivity in catalysis of chemical transformations. Heterogenization of these complexes by immobilization on solid supports has been used to facilitate recovery, but this is often ...
Klein Gebbink, Bert +10 more
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Calpain small subunit homodimerization is robust and calcium‐independent
Calpains dimerize via penta‐EF‐hand (PEF) domains. Using single‐molecule force spectroscopy, we measured the strength and kinetics of PEF–PEF homodimer binding. The interaction is robust, shows a transient conformational step before dissociation, and remains largely insensitive to Ca2+.
Nesha May O. Andoy +4 more
wiley +1 more source
Cobalt particle size effects in catalysis [PDF]
Aim of the work described in this thesis was first to investigate cobalt particle size effects in heterogeneous catalysis. The main focus was to provide a deeper understanding of the origin of the cobalt particle size effects in Fischer-Tropsch (FT ...
Inorganic Chemistry and Catalysis +2 more
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New frontiers in X-ray spectroscopy in heterogeneous catalysis: Using Fe/ZSM-5 as test-system [PDF]
We have applied a number of novel X-ray spectroscopic tools to Fe/ZSM-5 systems. Fe/ZSM-5 can be considered as an ideal test-system for the characterization techniques in heterogeneous catalysis.
Inorganic Chemistry and Catalysis 1 +6 more
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Comparison of the HDS DBT reaction using bulk and supported catalysts
The paper describes in detail the procedure for the preparation of a granular bulk NiMoW catalyst and a supported reference NiMo/Al2O3 catalyst. Mention is made of investigations of the supported and bulk catalysts by various physico-chemical methods ...
Polina P. Mukhacheva +9 more
doaj +1 more source
Structural insights into an engineered feruloyl esterase with improved MHET degrading properties
A feruloyl esterase was engineered to mimic key features of MHETase, enhancing the degradation of PET oligomers. Structural and computational analysis reveal how a point mutation stabilizes the active site and reshapes the binding cleft, expading substrate scope.
Panagiota Karampa +5 more
wiley +1 more source
The cluster approach to molecular heterogeneous catalysis [PDF]
Density functional theory enables quantitative computational analysis of reaction intermediates. The cluster approach makes application to heterogeneous catalysis possible.
R.A van Santen +3 more
core +2 more sources
Biomolecular condensates formed by fused in sarcoma (FUS) are dissolved by high ATP concentrations yet persist in cells. Using a reconstituted system, we demonstrate that valosin‐containing protein (VCP), an AAA+ ATPase, counteracts ATP‐driven dissolution of FUS condensates through its D2 ATPase activity.
Hitomi Kimura +2 more
wiley +1 more source
Lewis Acidity in Cracking and Polymerization Catalysis [PDF]
The aim of this PhD thesis was to provide insight into the nature and variety of Lewis acidity in solid acid catalysts and to clarify the role of Lewis acid sites in fluid catalytic cracking (FCC) and metallocene-based olefin polymerization catalysis ...
Sub Inorganic Chemistry and Catalysis +2 more
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