Results 51 to 60 of about 15,586 (258)

Catalytic combustion of methane

Fuel Processing Technology, 1995
Abstract Palladium-based catalysts have been found to be the most efficient catalysts for the catalytic oxidation of methane to carbon dioxide and water. The catalytic oxidation is dependent on factors such as the oxygen: methane feed ratio, the loading of precious metal on the support, the nature of the support, the particle size of the precious ...
Joo H. Lee, David L. Trimm
openaire   +1 more source

Hypergolic Copper Cluster‐Based Covalent Organic Frameworks

Advanced Science, EarlyView.
Hpergolic cluster‐based covalent organic framework (Cu3‐CB‐COF), assembled from aldehyde‐functionalized carborane monomers and trinuclear copper clusters, demonstrates a strong synergy between its catalytic copper nodes and energetic carborane backbones.
Yu‐Zhou Qiao, Cai Li, Wen‐Yang Jiao, Guoqiang Sun, Xiao‐Fei Liu, Shuang‐Quan Zang   +5 more
wiley   +1 more source

Probing Electrocatalyst Design for Product Selectivity in CO2 Reduction

Advanced Science, EarlyView.
Selective CO2 electroreduction is controlled by catalyst structure, dynamic surface reconstruction, adsorbate interactions, and reaction microenvironment. This review summarizes Cu‐ and non‐Cu‐based catalysts, single‐atom and molecular systems, degradation pathways, and operando/computational strategies for steering CO2RR toward hydrocarbons ...
Suvodeep Sen, Bapan Biswas, Apinya Ngoipala, Julia Wiktor, Ujjwal Pal, Shalini Singh   +5 more
wiley   +1 more source

Thermally Assisted Photocatalytic Dehydrogenation of Methanol in Continuous Steady‐State Operation

Advanced Science, EarlyView.
Thermally assisted photocatalytic methanol dehydrogenation on Pt/TiO2 enables formaldehyde and hydrogen production far beyond thermodynamic limits. Continuous operation delivers up to 95% selectivity over 70 h, and oxygen microdosing strongly boosts conversion by regenerating surface oxygen sites.
Florian Stubenrauch, Phillip Nathrath, Markus Schörner, Yazan Mahayni, Birk Fritsch, Andreas Hutzler, Peter Wasserscheid, Andreas Bösmann, Patrick Schühle   +8 more
wiley   +1 more source

Hole‐Activated Lattice Oxygen Enables Pt‐Free Propane Dehydrogenation by Eliminating the Hydrogen Recombination Bottleneck

Angewandte Chemie, EarlyView.
Trace Mg doping into gallia–alumina generates hole‐type oxygen species that accelerate hydrogen recombination, eliminating the need for Pt promotion. The fully oxide‐based catalyst resists sintering under repeated regeneration, outperforming benchmark PtSn and CrOx catalysts with exceptional stability over 30 dehydrogenation–regeneration cycles ...
DongHwan Oh, Jaewoo Jeong, Susung Lee, Younghwan Park, Seunghyuck Chi, Yaejun Baik, Hyungjun Kim, Hyeyoung Shin, Minkee Choi   +8 more
wiley   +2 more sources

Nitraminepyrazole ligand boosting ignition and catalytic performance of energetic complexes

Energetic Materials Frontiers
The development of energetic combustion catalysts as combustion catalysts for ammonium perchlorate (AP) has aroused increasing interest in recent years. In this work, five energetic complexes (1–5) were prepared via the coordination of the 3-nitramine-4 ...
Bo Wu, Ya-lin Yang, Xu-wen Duan, Qian-gui Zeng, Guo-jie Zhang, Cong-ming Ma, Chong-hua Pei   +6 more
doaj   +1 more source

Decoupling Electronic–Ionic Transport and Catalysis Enables High‐Performance, Chemically Stable Sr‐Free Air Electrodes for High‐Temperature Solid Oxide Cells

Advanced Science, EarlyView.
A Sr‐free air electrode for high‐temperature solid oxide cells is designed by independently tailoring electronic conduction, ionic transport, and surface catalysis using complementary Sr‐free phases and infiltrated nanocatalysts. It delivers performance comparable to state‐of‐the‐art Sr‐containing electrodes while completely suppressing Cr‐induced ...
Ji‐eun Won, Wooseok Lee, Jaehyun Seo, Dogeun Yoon, Ho‐Il Ji, HeeChan Kang, Jun Hyuk Kim, Hwitae Kim, Ji Wan Kim, Jongsup Hong, Kyung Joong Yoon   +10 more
wiley   +1 more source

Modulating Local Coordination in Single‐Atom Catalysts: From Fundamental Concepts to Emerging Breakthroughs in Electrocatalysis

Angewandte Chemie, EarlyView.
This review summarizes atomic‐level design strategies for single‐atom catalysts, emphasizing modulation of the local coordination environment, active‐site geometry, and metal‐support interactions to optimize catalytic activity and stability in electrocatalytic energy conversion applications.
Ashwani Kumar, Harun Tüysüz
wiley   +2 more sources

Bio‐Based Polyurethanes for Sustainable and Multifunctional Applications

Advanced Science, EarlyView.
Bio‐based polyurethanes prepared from vegetable oils, lignin, and polysaccharides have attracted increasing interest as alternatives to fossil‐derived polyurethanes. This review summarizes recent progress in their chemistry, structural engineering, and advanced applications, highlighting the roles of feedstocks, chain‐segment design, dynamic covalent ...
Xin Li, Henghui Deng, Shiwei Yu, Jiawei Huang, Zehong Chen, Dawei Zhao, Chaoqun Zhang   +6 more
wiley   +1 more source

Titanium‐Catalyzed Defluorination of Poly(Vinyl Fluoride) and Poly(Vinylidene Fluoride) Under Friedel–Crafts Conditions

Angewandte Chemie, EarlyView.
Cationic titanium sandwich catalysts display exceptional activity in the hydrodefluorination of Csp3─F bonds, in the presence of silanes and aromatic solvents (turnover numbers up to 3000). As a result, they can be used to defluorinate challenging fluoropolymers, such as poly(vinyl fluoride) (PVF) or poly(vinylidene fluoride) (PVDF).
Louis Le Moigne, Marie Sircoglou, Quentin Bonnin, Marie‐José Penouilh, Joan Vignolle, Etienne Grau, Cédric Le Coz, Mélanie Bousquet, Paul Fleurat‐Lessard, Adrien T. Normand   +9 more
wiley   +2 more sources