Results 131 to 140 of about 12,778 (258)

Sub‐Nanometer Cobalt on Tungsten Titanium Carbide MXene (W2TiC2Tx): An Electrocatalyst for Highly Efficient and Stable Alkaline Hydrogen Evolution at Industrial‐Scale Current Density

Advanced Materials, EarlyView.
A novel W2TiC2Tx MXene prepared through a MAX‐phase route supports sub‐nanometer Co for highly efficient alkaline hydrogen evolution. Strong Co–W interfacial interactions optimize hydrogen adsorption and catalytic activity, enabling low overpotentials of 63 mV at 10 mA cm−2, small Tafel slope of 44.3 mV dec−1, and exceptional durability at industrially
Xiaopeng Liu, Fan Yang, Deep M. Patel, Mohammad Albloushi, Qiqi Mao, Shan Jiang, Christian J. Breckner, Connor W. Schroeder, Ruoyu Cui, Tao Ma, Dapeng Jing, Wenyu Huang, Jeffrey T. Miller, Wenzhen Li, Luke T. Roling, Yue Wu   +15 more
wiley   +1 more source

Liquid Phase Catalytic Transfer Hydrogenation of Crotonaldehyde over ReO_x-Supported Catalysts Using Formic Acid as In Situ Hydrogen Donor. [PDF]

Molecules
Aristizábal-Alzate CE, Naharro-Ovejero V, Romero-Sáez M, Dongil AB.   +3 more
europepmc   +1 more source

Efficient Hydroxyl Diffusion Triggers Surface Hydronium Enrichment and Bulk Proton Participation to Boost Alkaline Hydrogen‐Evolving Reaction

Advanced Materials, EarlyView.
For the first time, we shed light on the surface‐to‐bulk diffusion, induction, and reaction behaviors of OH−, H+, and H2O species on model oxides for alkaline hydrogen‐evolving reaction (HER). We first demonstrate that bulk OH− diffusion significantly affects the generation of proton sources and the diffusion/reaction behaviors of protons, thus ...
Daqin Guan, Hengyue Xu, Xiao Sun, Leqi Zhao, Chun‐Kuo Peng, Chao Jing, Yu‐Cheng Huang, Jiayi Tang, Nai Shi, Zezhou Lin, Xiaomin Xu, Zhiwei Hu, Zongping Shao   +12 more
wiley   +1 more source

Entropy engineering activation of UiO-66 for boosting catalytic transfer hydrogenation. [PDF]

Nat Commun
Ma M, Chen E, Yue H, Tian G, Feng S.
europepmc   +1 more source

Engineering Metal‐Pocket Cooperativity in Single‐Atom COF Nanozymes for Selective Cascade Catalysis

Advanced Materials, EarlyView.
A multilevel programming strategy is developed to engineer single‐atom COF nanozymes with tunable metal centers and chiral pockets inspired by heme–pocket cooperativity. This approach enables controlled metal–pocket interplay for asymmetric cascade catalysis, delivering high activity, selectivity, and recyclability in an asymmetric oxidation–aldol ...
Ziping Li, Qijun Sun, Yawen Hao, Haotian Wen, Shery Chang, Fengwang Li, Jiangtao Xu, Kang Liang   +7 more
wiley   +1 more source

Advances in Sustainable γ-Valerolactone (GVL) Production via Catalytic Transfer Hydrogenation of Levulinic Acid and Its Esters. [PDF]

ACS Sustain Chem Eng
Khalid M, Granollers Mesa M, Scapens D, Osatiashtiani A.   +3 more
europepmc   +1 more source

2D Abrupt Nano‐Junctions Blending sp–sp2 Bonds on Atomically Precise Heterostructures

Advanced Materials, EarlyView.
A lateral heterostructure between atomically precise sp–sp2$^2$ metalated graphdiyne and sp2$^2$ graphene nanoribbons is realized by on‐surface synthesis and investigated by STM and DFT. The impact of on‐surface synthesis byproducts on covalent junction formation yield is unveiled.
Alice Cartoceti, Simona Achilli, Masoumeh Alihosseini, Adriana E. Candia, Enrico Beltrami, Paolo D'Agosta, Alessio Orbelli Biroli, Francesco Sedona, Andrea Li Bassi, Jorge Lobo‐Checa, Carlo S. Casari   +10 more
wiley   +1 more source

Side‐Chain‐Induced Interlayer Slipping in Metalloporphyrin COFs Enables Microenvironment and Spin‐State Regulation for Photocatalytic CO2 Reduction

Advanced Materials, EarlyView.
Alkoxy chain length drives a continuous transition from eclipsed AA to a serrated, slipped AA* configuration over Co‐porphyrin COFs. A moderate slip both contracts the pore channel to enrich CO2 and suppress hydrogen evolution, and enhances collective high‐spin of Co sites, which delivers a record CO production rate with high selectivity.
Jie He, Qingxuan Chen, Minxian Zhang, Wenhao Zhao, Aoni Xu, Jinqiang Zhang, Hongqi Sun, Shaobin Wang, Xiaoguang Duan   +8 more
wiley   +1 more source

Zirconium Phosphate-Pillared Zeolite MCM-36 for Green Production of γ-Valerolactone from Levulinic Acid via Catalytic Transfer Hydrogenation. [PDF]

Molecules
Hou P, Su H, Jin K, Li Q, Yan W.
europepmc   +1 more source

Effective hydrogen transfer in catalytic cracking

Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute, 2010
Maeda, Kenta, Nakamura, Tomofumi, Takahashi, Nobuhide, Fukunaga, Hiroshi, Takatsuka, Toru   +4 more
openaire   +1 more source