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Exploring Hydrogen Sources in Catalytic Transfer Hydrogenation: A Review of Unsaturated Compound Reduction

open access: yesMolecules, 2023
Catalytic transfer hydrogenation has emerged as a pivotal chemical process with transformative potential in various industries. This review highlights the significance of catalytic transfer hydrogenation, a reaction that facilitates the transfer of ...
Batoul Taleb   +7 more
doaj   +1 more source

Metal oxides and their roles in heterogeneous catalysis: special emphasis on synthesis protocols, intrinsic properties, and their influence in transfer hydrogenation reactions

open access: yesSN Applied Sciences, 2023
This review emphasizes La-based metal oxides of the perovskite form and their application in heterogeneous catalytic transfer hydrogenation (CTH) reactions from year 2013. Perovskites are potential alternatives to noble metals. The possibility of induced-
Tafadzwa Precious Mabate   +4 more
doaj   +1 more source

Chemoselective Transfer Hydrogenation of α,β-Unsaturated Ketones Catalyzed by Iridium Complexes

open access: yesSynOpen, 2021
Efficient chemoselective transfer hydrogenation of the C=C bond of α,β-unsaturated ketones has been developed, using the iridium complexes containing pyridine-imidazolidinyl ligands as catalysts and formic acid as a hydrogen source.
Yanping Xia   +4 more
doaj   +1 more source

Transfer Hydrogenation in Water [PDF]

open access: yesThe Chemical Record, 2016
AbstractThis article provides an account of our group's efforts in developing aqueous‐phase transfer hydrogenation reactions. It is comprised of mainly two parts. The first part concentrates on asymmetric transfer hydrogenation in water, enabled by Noyori–Ikariya catalysts, while the second part is concerned with the achiral version of the reaction ...
Wu, Xiaofeng   +2 more
openaire   +2 more sources

Construction of N-Doped Carbon-Modified Ni/SiO2 Catalyst Promoting Cinnamaldehyde Selective Hydrogenation

open access: yesMolecules, 2023
At present, the selective hydrogenation of α, β-unsaturated aldehydes remains a challenge due to competition between unsaturated functional groups (C=C and C=O).
Yongwang Ren   +3 more
doaj   +1 more source

Construction of ionic liquid-Pd/C based bifunction catalysts for the synthesis of UV-P

open access: yesJournal of Saudi Chemical Society, 2023
Adding light stabilizers to polymeric materials can inhibit or delay the light aging effect and improve the light resistance of materials. 2-(2′-Hydroxy-5′-methylphenyl) benzotriazole (UV-P), as a typical benzotriazole ultraviolet absorber, is widely ...
Lingling Guo   +9 more
doaj   +1 more source

Deoxydehydration and Catalytic Transfer Hydrogenation: New Strategy to Valorize Tartaric Acid and Succinic Acid to γ-Butyrolactone and Tetrahydrofuran

open access: yesEnergies, 2020
Hydrogenation of succinic acid and maleic acid produces C4 value-added chemicals such as γ-butyrolactone and tetrahydrofuran. Here, unsupported ReOx nanoparticles transform succinic acid to γ-butyrolactone and tetrahydrofuran via catalytic transfer ...
Jun Hee Jang, Mahdi M. Abu-Omar
doaj   +1 more source

Ultrasonic-assisted catalytic transfer hydrogenation for upgrading pyrolysis-oil

open access: yesUltrasonics Sonochemistry, 2021
Recent interest in biomass-based fuel blendstocks and chemical compounds has stimulated research efforts on conversion and upgrading pathways, which are considered as critical commercialization drivers.
Ethan Struhs   +6 more
doaj   +1 more source

Silane- and peroxide-free hydrogen atom transfer hydrogenation using ascorbic acid and cobalt-photoredox dual catalysis

open access: yesNature Communications, 2021
Hydrogen atom transfer (HAT) hydrogenation of alkenes usually requires stoichiometric silanes and peroxides. Here, the authors report a silane- and peroxide-free HAT hydrogenation method using a combined cobalt/photoredox catalysis and vitamin C as a ...
Yuji Kamei   +6 more
doaj   +1 more source

Palladium-catalyzed transfer hydrogenation of terminal alkynes using ethanol as the hydrogen donor

open access: yesJournal of Chemical Research, 2022
A ligand-promoted, palladium-catalyzed transfer hydrogenation of terminal alkynes using ethanol as the hydrogen donor is developed. The chemical selectivity control is achieved based on ligand regulation. The use of triethanolamine and tetrahydrofuran at
Jie Hui, Feng Wang
doaj   +1 more source

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