Emerging progress in ruthenium-catalyzed transfer and asymmetric transfer hydrogenation [PDF]
Ruthenium-catalysed transfer hydrogenation (TH) and asymmetric transfer hydrogenation (ATH) are well recognised as efficient and environmentally benign methods for synthesising chiral alcohols, amines, and key intermediates used in the pharmaceutical and
S. M. Wahidur Rahaman
doaj +3 more sources
Effect of Solvents on Electrogenerated Base-Driven Transfer Hydrogenation Reactions [PDF]
Transfer hydrogenation is a crucial technology for synthesizing fine chemicals and pharmaceuticals, offering improved safety and convenience over traditional hydrogen methods, although it typically requires external bases.
Jing-Wei Zhu +5 more
doaj +2 more sources
Decatungstate-photocatalyzed transfer hydrogenation of unsaturated compounds using alcohol as the hydrogen source [PDF]
We present a simple and efficient photocatalytic method for the transfer hydrogenation of unsaturated compounds using alcohol as the hydrogen source and low-cost decatungstate as the photocatalyst.
Teng Zhang +7 more
doaj +2 more sources
Selective hydrogenation of α,β[alpha,beta]-unsaturated aldehydes towards clean synthesis over noble metal catalysts in mass transfer efficient three phase reactors [PDF]
The hydrodynamics and mass transfer characteristics of a concurrent downflow contactor (CDC) are studied in this work in order to investigate the viability of this bubble column as a catalytic reactor for the hydrogenation of α,β-unsaturated aldehydes ...
Zhang, Laiqi
core +7 more sources
Tetrahydroxydiboron-Mediated Palladium-Catalyzed Deoxygenative Transfer Hydrogenation of Aryl Ketones [PDF]
We describe a palladium-catalyzed deoxygenative transfer hydrogenation of ketones using B2(OH)4 as the sole additive. Deuterium labeling experiments using B2(OD)4 show that the incorporated protons originate exclusively from the diboron reagent ...
William, Spaller +2 more
core +2 more sources
Ruthenacycles and Iridacycles as Catalysts for Asymmetric Transfer Hydrogenation and Racemisation [PDF]
Ruthenacycles, which are easily prepared in a single step by reaction between enantiopure aromatic amines and [Ru(arene)Cl2]2 in the presence of NaOH and KPF6, are very good asymmetric transfer hydrogenation catalysts.
Ben L. Feringa +53 more
core +1 more source
Developments in the hydrogenation of challenging substrates utilising transition metal complexes [PDF]
This thesis describes the developments of new protocols for the hydrogenation of challenging substrates. Three specific substrates were highlighted for study after an initial review of the literature; benzofurans, esters and bulky ketones.
Carpenter, Ian
core +2 more sources
Selective hydrogenation in trickle-bed reactor. Experimental and modelling including partial wetting. [PDF]
A steady state model of a trickle bed reactor is developed for the consecutive hydrogenation of 1,5,9-cyclododecatriene on a Pd/Al2O3 catalyst. Various experiments have shown that the selectivity of this reaction towards the product of interest is much ...
Wilhelm, Anne-Marie +3 more
core +1 more source
Catalyst-Free Transfer Hydrogenation of Activated Alkenes Exploit-ing Isopropanol as the Sole and Traceless Reductant [PDF]
Both metal-catalyzed and organocatalytic transfer hydrogenation reactions are widely employed for the reduction of C=C, C=O and C=N bonds. Described herein is an unconventional catalyst-free transfer hydrogenation reaction of activated al-kenes using ...
Juha, Siitonen +7 more
core +2 more sources
Characterization of Hydrogenated Natural Rubber Synthesized by Diimide Transfer Hydrogenation
Oxidation resistance and thermal stability of natural rubber (NR) can be improved by diimide transfer hydrogenation in the latex phase. In this research, non-catalytic diimide transfer hydrogenation of concentrated NR latex was accomplished at various ...
Adi Cifriadi +2 more
doaj +1 more source

