Sunlight‐driven synthesis offers a green and energy‐efficient route to metallic nanoparticles. Here, double‐vacancy halide perovskites (Cs2PtX6, X = Cl, Br) act as photoactive precursors for the in‐situ formation of ultrasmall (< 3 nm) platinum nanoparticles under simulated sunlight at room temperature.
Kevin Mego +4 more
wiley +1 more source
Azidophosphonamido Rhodium(I) and Iridium(I) Complexes: Synthesis, Properties, and Linkage Isomerism
A family of azidophosphonamido ligands and their corresponding rhodium(I) and iridium(I) complexes were synthesized. The rich reaction chemistry of these species revealed unusual linkage isomerization processes and bonding motifs. M = Rh, Ir; Mes = 2,4,6‐Me3C6H2. ABSTRACT A series of azidophosphonamido rhodium(I) and iridium(I) complexes ([iPr2P(N3R)NR]
Emily L. Trew +3 more
wiley +1 more source
Biodegradation of Triphenyl Phosphate by a Novel Marine Bacterium <i>Pseudomonas abyssi</i> RL-WG04: Characterization, Metabolic Pathway, Bioremediation and Synergistic Metabolism. [PDF]
Shi M +6 more
europepmc +1 more source
The first example of a simple alkylated phosphinidene‐adduct (“phospha‐Wittig”) is reported. The synthesis of Me3PPC2F5 was enabled through reaction of the cyclotetraphosphane (PC2F5)4 with PMe3. The phosphanyl‐functionalized Wittig reagent Me3PC(CF3)P(C2F5)F was prepared by treating the diphosphane P2(C2F5)4 with PMe3.
Lukas Hartmann +7 more
wiley +1 more source
Hydrogen-rich water irrigation enhances fruit quality in 'Flame Seedless' grapes by regulating chlorophyll fluorescence parameters and antioxidant activities. [PDF]
Ali HSM +6 more
europepmc +1 more source
The article describes the synthesis and molecular transformations of a silica‐supported bis(phosphine)methylplatinum(II) complex under reactive (H2, CO) and inert gas atmospheres. The focus lies on the stabilizing effect of the sterically non‐demanding trimethylphosphine ligand, which alters the reactivity of the surface sites, compared to other ...
Lea S. Kopietz +6 more
wiley +1 more source
Challenges and adaptation strategies for improving quality and biochemical changes of Flame Seedless grapevines in Mediterranean environment under increasing climate variability. [PDF]
Alebidi A +5 more
europepmc +1 more source
Five heteroleptic iridium(III) complexes bearing cyclometalated 2,4‐diphenylpyridinato ligands were synthesized and their electrochemiluminescence (ECL) investigated. Two different coreactants were evaluated: tri‐n‐propylamine and benzoyl peroxide under anodic and cathodic potentials, respectively.
Ovini Jayawardana +6 more
wiley +1 more source
Boron-based fire retardancy for natural polymeric materials. [PDF]
Wang X, Shi SQ.
europepmc +1 more source
Global and Detailed Calculation of Tube Wall Temperature in a Process Furnace Steam Superheater
This study presents a comparison between an iterative global model and multiple approaches to a new non‐iterative model with the purpose of predicting tube wall temperature of a superheater. The results show that the non‐iterative method achieves sufficient accuracy while improving the prediction of local temperature distribution and better ...
Anežka Michálková, Zdeněk Jegla
wiley +1 more source

