Alkali‐Metal Base Catalyzed Electrocyclization of Isoprene Derivatives
Simple and abundant alkali‐metal base catalysis in combination with Lewis basic polyamines enables the electrocyclization of isoprene‐derived trienes to cycloheptadienes under neat conditions. Mechanistic insight supported by DFT guides a scalable route to seven‐membered carbocycles which, after reduction, give saturated cycloalkanes relevant as ...
Mikaël Le Roch +3 more
wiley +1 more source
Environmental endocrine disruptors at the synapse: mechanisms linking chemical exposure to cognitive and behavioral dysfunction. [PDF]
Jocsak G +6 more
europepmc +1 more source
Azidophosphonamido Rhodium(I) and Iridium(I) Complexes: Synthesis, Properties, and Linkage Isomerism
A family of azidophosphonamido ligands and their corresponding rhodium(I) and iridium(I) complexes were synthesized. The rich reaction chemistry of these species revealed unusual linkage isomerization processes and bonding motifs. M = Rh, Ir; Mes = 2,4,6‐Me3C6H2. ABSTRACT A series of azidophosphonamido rhodium(I) and iridium(I) complexes ([iPr2P(N3R)NR]
Emily L. Trew +3 more
wiley +1 more source
Selective cytotoxicity of zinc peroxide and tetrapodal zinc oxide micro-nanoparticles against breast cancer cells: synthesis, characterization, and therapeutic potential. [PDF]
Riaz T +13 more
europepmc +1 more source
The first example of a simple alkylated phosphinidene‐adduct (“phospha‐Wittig”) is reported. The synthesis of Me3PPC2F5 was enabled through reaction of the cyclotetraphosphane (PC2F5)4 with PMe3. The phosphanyl‐functionalized Wittig reagent Me3PC(CF3)P(C2F5)F was prepared by treating the diphosphane P2(C2F5)4 with PMe3.
Lukas Hartmann +7 more
wiley +1 more source
Silicone Wristbands for Measuring Human Exposure to Organic Chemicals: Uses and Benefits for Human Biological Research. [PDF]
Howe ME +3 more
europepmc +1 more source
Global and Detailed Calculation of Tube Wall Temperature in a Process Furnace Steam Superheater
This study presents a comparison between an iterative global model and multiple approaches to a new non‐iterative model with the purpose of predicting tube wall temperature of a superheater. The results show that the non‐iterative method achieves sufficient accuracy while improving the prediction of local temperature distribution and better ...
Anežka Michálková, Zdeněk Jegla
wiley +1 more source
Comparative Thermal and Fire Behavior of Rigid Polyurethane (PUR) and Polyisocyanurate (PIR) Foams Formulated with Recycled Poly(ethylene terephthalate) (PET) Polyols-Part 1. [PDF]
Skowron M +2 more
europepmc +1 more source
Abstract The objective of this work is to demonstrate that the inclusion of an up‐flow anaerobic sludge bed (UASB reactor) within an industrial wastewater treatment plant reduces the plant's investment and operating costs compared to a system based solely on conventional complete‐mix activated sludge (CMAS), operating under the same design principles ...
Juan Manuel Morgan‐Sagastume +1 more
wiley +1 more source
Structural and Chemical Modification of Cellular Wood Composite for Enhanced Strength, Fire, and Biological Resistance. [PDF]
Koo MS +4 more
europepmc +1 more source

