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Enantioseparations in counter-current chromatography and centrifugal partition chromatography
Journal of Chromatography A, 2001Examples of chiral separations in counter-current chromatography (CCC) and centrifugal partition chromatography (CPC) are not numerous, due to the difficulty of finding chiral selectors highly selective in the liquid phase as well as a combination of solvents that does not destroy the selectivity and retains the capacity to elute chiral isomers of ...
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Deep eutectic solvents in countercurrent and centrifugal partition chromatography
Journal of Chromatography A, 2016Deep eutectic solvents (DESs) were evaluated as solvents in centrifugal partition chromatography, a liquid-liquid chromatography separation technology. To this end, the partition coefficients of ten natural compounds of different hydrophobicity were determined in non-aqueous biphasic systems containing DES.
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Anion-Exchange Displacement Centrifugal Partition Chromatography
Analytical Chemistry, 2004Ion-exchange displacement chromatography has been adapted to centrifugal partition chromatography. The use of an ionic liquid, benzalkonium chloride, as a strong anion-exchanger has proven to be efficient for the preparative separation of phenolic acid regioisomers.
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Multiphase flow modeling in centrifugal partition chromatography
Journal of Chromatography A, 2011The separation efficiency in Centrifugal Partition Chromatography (CPC) depends on selection of a suitable biphasic solvent system (distribution ratio, selectivity factor, sample solubility) and is influenced by hydrodynamics in the chambers. Especially the stationary phase retention, the interfacial area for mass transfer and the flow pattern ...
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Centrifugal Partition Chromatography. II. Selectivity Efficiency
Journal of Liquid Chromatography, 1988Abstract Centrifugal Partition Chromatography (CPC) is a technique that uses two immiscible liquids. One liquid is used as a stationary phase, the second one as the mobile phase. Using the liquid systems methanol-hexane and octanol-water, the selectivity and efficiency of CPC apparatus were tested.
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