Ir Complexes With Mixed‐Valent Bidentate Ligands: From Complex Synthesis to Catalytic Application
ABSTRACT The bidentate ligands Ph2P(E)NHPPh2 (E = S, Se) feature phosphorous atoms in two different oxidation states and provide the potential to tune chemical reactivity through the choice of donor E. The mononuclear complexes [Ir(COD){κ2‐P,E‐Ph2P(E)NPPh2}] (E = S 1a, Se 1b) were prepared from the dimer [IrClCOD]2 (COD = 1,5‐cyclooctadiene) and the ...
C. Gabriela Morales Salas +4 more
wiley +1 more source
Charge Transport and Thermoelectric Performance of Bornite Controlled by Cu Non-Stoichiometry. [PDF]
Kim H, Oh H, Kim IH.
europepmc +1 more source
Achievement of Transition Metal Chalcogenides/Oxides in Hydrogen Production by Seawater Electrolysis
Transition metal chalcogenides (TMCs)/oxides have shown great application potential in seawater splitting for hydrogen generation due to their adjustable electronic properties, abundant active sites, and excellent catalytic performance. ABSTRACT Under the impetus of global “dual carbon” goals, green hydrogen has become a key component of the future ...
Xiaohui Du, Xinyu Li, Jianna Li, Tao Sun
wiley +1 more source
This Review highlights how metal halide perovskites enable coupled selective organic oxidation and hydrogen evolution under visible light. It summarizes halide‐dependent design principles, surface engineering strategies, reaction mechanisms, and stability challenges, providing guidance for developing efficient and durable photocatalytic systems ...
Jutarat Jitrada +4 more
wiley +1 more source
Compositional Tuning of Barium Titanium Trisulphide-Based Perovskite Chalcogenides: Manganese and Selenium Substitution Effects on Electronic and Transport Properties. [PDF]
Alruqi AB.
europepmc +1 more source
Niobium‐Based Chalcogenides as Emerging Electrode Materials for Rechargeable Batteries
This review highlights recent advances in Nb‐based TMCs, covering their structure‐property relationships, synthesis strategies, electrochemical mechanisms, and energy‐storage applications. Emerging approaches including defect engineering, operando characterization, DFT modeling, and AI‐assisted design are discussed to accelerate the development of high‐
Narasimharao Kitchamsetti +3 more
wiley +1 more source
K<sup>+</sup>-free mica-assisted epitaxy of Bi-based chalcogenide and oxychalcogenide single-crystals. [PDF]
Zhao T +13 more
europepmc +1 more source
Ag incorporation emerges as a unifying strategy for optimizing chalcogenide thin‐film solar cells by tailoring crystallization, defect energetics, and junction quality. This review bridges fundamental mechanisms with practical strategies for next‐generation high‐efficiency photovoltaic technologies.
Van‐Quy Hoang +10 more
wiley +1 more source
Cluster-based DFT modeling of Raman vibrations in tetrahedral GeS<sub>2</sub> and GeSe<sub>2</sub> amorphous chalcogenides. [PDF]
Halenkovič T, Němec P, Nazabal V.
europepmc +1 more source
Anode Materials Requirements for Potassium Ion Batteries: Challenges and Future Possibilities
This work identifies a critical scale‐up gap between laboratory battery research and industrial targets, driven by low active‐mass loadings and the omission of full‐cell metrics. We outline concrete strategies to bridge this divide, shifting focus toward high‐loading electrodes (> 3 mg cm−2) to ensure practical commercial viability of potassium ion ...
Md. Robiul Alam +9 more
wiley +1 more source

