Results 251 to 260 of about 3,897,550 (347)

A heterometallic σ-silane adduct from cooperative reactivity of an iron-aluminium complex.

Chem Commun (Camb)
Stadler B, Crimmin MR.
europepmc   +1 more source

Dipolar Molecular Motor Candidates with Planar Chirality

Chemistry – A European Journal, EarlyView.
Two prototypes of molecular motors with simultaneous implementation of planar chirality and a permanent dipole have been designed and synthesized in 7 steps with overall yields of 2.8 to 5.5%. Abstract Two molecular motor candidates built around ruthenium(II) centers featuring both planar chirality and a permanent dipole have been synthesized in seven ...
Thomas A. Hector, Shohei Katao, Nathalie Saffon‐Merceron, Valentin Magné, Claire Kammerer, Gwénaël Rapenne   +5 more
wiley   +1 more source

Unfreezing structural biology for drug discovery. [PDF]

Nat Chem Biol
Stachowski TR, Fischer M.
europepmc   +1 more source

A [3]Rotaxane Containing {Ti7Ga} Rings Linking CuII: Synthesis, Structure, and Spectroscopic Studies

Chemistry – A European Journal, EarlyView.
Extended hybrid inorganic‐organic [2]‐ and [3]‐rotaxanes are reported based on heterometallic rings with threads that link CuII complexes; the crystal structures are reported, and the solution behavior is investigated by double electron electron resonance spectroscopy methods.
Selena J. Lockyer, Lubomir Loci, George F. S. Whitehead, Inigo J. Vitorica‐Yrezabal, Grigore A. Timco, Alice M. Bowen, Eric J. L. McInnes, Richard E. P. Winpenny   +7 more
wiley   +1 more source

Linear-scaling aspherical crystallographic refinement of proteins: a case study for crambin and rubredoxin. [PDF]

IUCrJ
Bergmann J, Kleemiss F, Creutzberg J, Oksanen E, Ryde U.   +4 more
europepmc   +1 more source

Multiple Dimerization Modes in Thiocarboxylate Paddlewheel Complexes: A Comprehensive View of Energy Landscapes from DFT Calculations and Statistics

Chemistry – A European Journal, EarlyView.
Staggered, square, and heavily bent dimers occur in the five known solvatomorphs of paddlewheel (PW) complex [PtVO(SOCPh)4]. These and other structural motifs are well within energetic reach due to the shallow potential energy surface that guides dimerization and are included in a revised classification of available structural data on heterobimetallic ...
Olga Mironova, Giacomo Bellini, Alessio Nicolini, Andrea Cornia   +3 more
wiley   +1 more source

One‐Pot Transition‐Metal‐Free Methods for the Synthesis of All Three Bonds of the Alkyne's Triple Bond

Chemistry – A European Journal, EarlyView.
One‐pot transition‐metal‐free methods for the synthesis of all three bonds of the alkyne's triple bond are reviewed. After analysis of several named reactions and discussion of improvements, recent advances in the synthesis of alkynes are discussed. Each section contains a proposed reaction mechanism and analysis of the strengths and weaknesses of the ...
Eugene Kim, Yu Wu, Judith N. Currano, Jianyou Mao, Patrick J. Walsh   +4 more
wiley   +1 more source

Twisted 1‐ and 2‐Azaperopyrenes: Synthesis, Structure, and Properties

Chemistry – A European Journal, EarlyView.
ABSTRACT A synthesis of hitherto unknown 1‐ and 2‐azaperopyrenes, twisted nitrogen‐doped peropyrenes, is reported. The synthesis is based on a Brønsted acid‐mediated benzannulation of alkynes. Key alkyne intermediates are synthesized via two complementary routes, including a Pd/C‐catalyzed, copper‐ and amine‐free Sonogashira‐type coupling of (hetero ...
Ricardo Molenda, Arpine Vardanyan, Alexander Villinger, Peter Ehlers, Peter Langer   +4 more
wiley   +1 more source