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Chemical Synthesis of Phosphatidylglucoside
20231-stearoyl (18:0)-2-arachidoyl (20:0)-sn-glycero-3-phospho-ß-D-glucoside (Phosphatidylglucoside or PtdGlc) was synthesized by direct coupling of D-glucose with the phosphate group of phosphatidic acid (18:0, 20:0). Selective in situ activation of the anomeric center of D-glucose by 2-chloro-1,3-dimethylimidazolinium chloride (DMC) in aqueous media ...
Koki, Kano +3 more
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Enzymes for chemical synthesis
Nature, 2001New catalytic synthetic methods in organic chemistry that satisfy increasingly stringent environmental constraints are in great demand by the pharmaceutical and chemical industries. In addition, novel catalytic procedures are necessary to produce the emerging classes of organic compounds that are becoming the targets of molecular and biomedical ...
K M, Koeller, C H, Wong
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Biochimica et Biophysica Acta (BBA) - Nucleic Acids and Protein Synthesis, 1974
Abstract The chemical synthesis of ppGpp (guanosine 3′,5′-dipyrophosphate) is described. The synthesis started from guanosine 3′,5′-diphosphate. The acidlabile ethoxyethyl group was used to protect the 2′-OH functional group. The pyrophosphate linkages were built up simultaneously according to the anionexchange method and the protecting group was ...
A, Simoncsits, J, Tomasz
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Abstract The chemical synthesis of ppGpp (guanosine 3′,5′-dipyrophosphate) is described. The synthesis started from guanosine 3′,5′-diphosphate. The acidlabile ethoxyethyl group was used to protect the 2′-OH functional group. The pyrophosphate linkages were built up simultaneously according to the anionexchange method and the protecting group was ...
A, Simoncsits, J, Tomasz
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Chemical synthesis of proteins
Trends in Biotechnology, 2000The manipulation of protein structure enables a better understanding of the principles of protein folding, as well as the development of novel therapeutics and drug-delivery vehicles. Chemical synthesis is the most powerful approach for constructing proteins of novel design and structure, allowing for variation of covalent structure without limitations.
J A, Borgia, G B, Fields
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Light-driven chemical synthesis
Trends in Plant Science, 2012Depletion of the fossil fuel reserves of the Earth has prompted research into sources of renewable and sustainable energy, and feedstock for the chemical and pharmaceutical industries to support the transition towards a bio-based society. Photosynthesis efficiently captures solar energy, but its subsequent conversion into chemical energy in the form of
Jensen, Kenneth +2 more
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Chemical Synthesis of Polysaccharides
1967Publisher Summary This chapter discusses the chemical synthesis of polysaccharides. The present concepts of the chemical constitution of such important biopolymers ascellulose, amylose, and chitin can be confirmed by their adequate chemical synthesis.
I J, Goldstein, T L, Hullar
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Chemical Synthesis of Polynucleotides
Angewandte Chemie International Edition in English, 1972AbstractCurrent methodology for the chemical synthesis of short chains (up to about twenty nucleotide units) of deoxyribopolynucleotides is reviewed.
K L, Agarwal +3 more
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Methods for chemical synthesis of colloidal gold
Russian Chemical Reviews, 2019Published data on the chemical synthesis of colloidal gold are summarized and systematized. Attention is focused on the state-of-the-art concepts behind the mechanisms of citrate synthesis and its control parameters, methods for fabrication of ultrafine ...
L. Dykman, N. Khlebtsov
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Chemical Synthesis of Endotoxin
1990Total synthesis of lipid A’s of Escherichia coli and many other bacterial species achieved in our laboratory (6, 7, 8) contributed not only to confirm their proposed chemical structures but also to establish unequivocally that these phosphorylated polyacyl glucosamine disaccharide with definite structures are responsible for most of the endotoxic ...
S, Kusumoto +4 more
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Chemical Synthesis in Microreactors
2009To develop a new generation of drugs, pharmaceutical companies need to be able to synthesise and screen novel chemicals with enhanced speed. New technology that would enable a cost neutral step change in the number of potential drug candidates would provide a distinct competitive advantage.
Paul, Watts, Stephen J, Haswell
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